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Inside Cover Alane-Based Classical and Frustrated Lewis Pairs in Polymer Synthesis Rapid Polymerization of MMA and Naturally Renewable Methylene Butyrolactones into High-Molecular-Weight Polymers (Angew. Chem. Int. Ed. 522010)

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Frustrated
Lewis pairs …
… have been used as exceptional polymerization catalysts for the conversion of naturally
renewable monomers into sustainable polymers. In their Communication on
page 10158 ff., E. Chen and co-workers describe the use of [Al(C6F5)3], phosphines,
and N-heterocyclic carbenes as classical and frustrated Lewis pair catalysts. Similar to
the horns that prevent fighting rams from hitting their heads, the bulky ligands of the
Lewis acids and bases inhibit the quenching of their reactivity.
Inside Cover
Yuetao Zhang, Garret M. Miyake, and Eugene Y.-X. Chen*
Frustrated Lewis pairs have been used as exceptional polymerization catalysts for the
conversion of naturally renewable monomers into sustainable polymers. In their
Communication on page 10158 ff., E. Chen and co-workers describe the use of
[Al(C6F5)3], phosphines, and N-heterocyclic carbenes as classical and frustrated Lewis
pair catalysts. Similar to the horns that prevent fighting rams from hitting their heads,
the bulky ligands of the Lewis acids and bases inhibit the quenching of their
reactivity.
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methylene, butyrolactone, molecular, rapid, high, classical, 522010, renewabl, base, polymer, int, cover, angel, mma, synthesis, chem, frustrated, naturally, weight, pairs, insider, lewis, polymerization, alan
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