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Subject Index [Angew. Chem. Int. Ed. Engl

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SUBJECT INDEX [Angew. Chem. Znt. Ed. Engf. 1992, 311
(A second page number to an entry indicates an erratum to the corresponding article.)
(R)
=
Review Article
(H) = Highlights
Ab initio calculations
Ab Initio Investigations of Structure
and Stability of [f,SiAI],, R = H, Me,
tBu (C) 353
- 1,2,4-Cyclohexatriene, an Isobenzene,
and its (2 + 21 Cycloaddition with
Styrene: A Theoretical Study (C)
476
- Effect of Torsional Strain and Electrostatic Interactions on the Stereochemistry of Nucleophilic Additions to Cyclohexanone and Related Systems (C)
1019
- [Ga(C,H )]. Synthesis, Identification,
and Ab Iktio Investigations (C) 1362
“Kinetically Enhanced Metalation”How Substituents Direct ortho Lithiation (C) 755
Large Hyperconjugative and Inductive
Effects on C-C-X Bond Angles
(X = Main-Group Element): The Crystal Structure of Triethylborane and Ab
Initio Investigations (C) 314
- Origin of the Stabilization of Vinyldiazonium Ions by P-Substitution; First
Crystal Structure of an Aliphatic Diazonium Ion: P,P-Diethoxyethenediazonium Hexachloroantimonate (C)
740
Structures, Structures, and Structures
(H) 290
- Synthesis and Structure of [Ni(PfBu,)]
and [Ni,(PfBu),(CO),] and Calculations on the Electronic Structure of
[Ni(PrBu),] and (PR),, R = tBu, Me (C)
323
The Electronic Structure of [($C,H,),Co,]: Comment on the Existence
of a Complex with an Unsupported CoCo Double Bond (C) 471
The Isomers of the Acetylene Derivatives C,Li,: Transferable Structural
Units in Hyperlithiated Compounds (C)
1602
The Structure of Pentamethyltantalum
(C) 1462
The Structures of Pentamethyltantalum
and -Antimony: One Square Pyramid
and One Trigonal Bipyramid (C) 1464
- The Structures of Thiosulfuric Acid
H S 0 and Its Monoanion HS,O; (C)
5s’
Transition Structures of Hydrocarbon
Pericyclic Reactions (R) 682
Acceleration of reactions
En Route to Synthetic Phosphodiesterases: Supramolecular PhosphorylTransfer Mediated by AmidiniumPhosphate Contact Ion-Pairs (C) 207
Actinoid compounds
Synthcsis of Lanthanide and Actinide
Compounds (B) 105
Adenosine monophosphates
A Synthetic Receptor for Cyclic
Adenosine Monophosphate (C) 61
Aldol reactions
One-Pot Synthesis of Tagatose 1,6-Bisphosphate by Diastereoselective Enzymatic Aldol Addition (C) 56
Alkali metal compounds
[2,3] Wittig Rearrangements of Nonconjugated Secondary a-Lithioethers: Proof
of Stereospecificity and Inversion of the
Configuration of the Carbanion C
Atom (C) 647
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Angew. C‘iwm. I n [ . Ed. Engf 1992, 3 / , No. 12
(C) = Short Communication
(B) = Book Review (L) = Correspondence
The Enchanting Alkaloids of Yuzuriha
(R) 665
Alkene complexes
- New Route to cr-[(lE,3E)-dienyl]allenes
via Butadiene-tricdrbonyliron Complexes (C) 224
- Preparation, Ligand Exchange Reactions, and Structure of a Diene(aqua)ruthenium Complex [(cod)Ru(H,O),](OTS), (C),440
Alkyl transition-metal compounds
On the Influence of Heteroatoms in x and P-Functionalized Alkyl TransitionMetal ComDounds (R)
~, 401
Alkyne compiexes
Inhibition of the [2+ 2 + 21 Cyclization
by the Formation of Chelates: Alkyne
and Vinylidene Complexes with Cyclopentadienylcobalt(~)(C) 1066
Alkynes
- Cycloalkadiynes-From
Bent Triple
Bonds to Strained Cage Compounds (R)
27
- Intermolecular Additions and Cycloisomerizations by a Pd-Catalyzed Sequence
of an Intramolecular Redox Reaction
and an Addition (C) 1335
Synthetic Approaches toward Molecular and Polymeric Carbon Allotropes
(R) 1101
- Tetraalkynylmethanes: Synthesis of Diethynyldipropargyl- and Tetrapropargylmethane (C) 1648
- The First Hexabutadiynylbenzenes:
Synthesis and Structures (C) 1643
Allenes
- I ,2,4-Cyclohexatriene, an Isobenzene,
and Bicyclo[4.4.0]deca-l,3,5,7,8-pentaene, an Isonaphthalene: Generation and
Trapping Reactions (C) 473
1,2,4-Cyclohexatriene, an Isobenzene,
and its [2 + 21 Cycloaddition with
Styrene: A Theoretical Study (C) 476
New Route to ~-((lE,3E)-dienyl]alleiies
via Butadiene-tricarbonyliron Complexes (C) 224
N-Lithiomethyl-N,N‘,N’,N‘’-tetraSynthesis and Reactions of Isothiomethyldiethylenetriamine: The First
cyanate-Substituted Allenes and 1,3Alkyllithium Compound which is
Butadienes (C) 90
Monomeric in Hydrocarbons (C) 633
[Lithium Piperidide-Piperidine],: Crys- - Synthesis of Isocyanate-Substituted Allenes and l ,3-Butadienes by [3,3] Sigmatal Structure of an Oligomeric 1 : 1 Lithitropic Rearrangements (C) 866
um Amide-Amine Mixed Complex, an
Intermediate in the N-Lithiation of Allylations
- Allvlation of Ouinones with Allvlsilane
Amines (C) 1205
in ihe Presence of Lithium Perihlorate
Perlithiated
and
Hyperlithiated
in Ether (C) 313
Methane (H) 584
- Catalysis of the Addition of Allyl- Preparative Polar Organometallic
trimethylsilane to Aldehydes by SilylatChemistry 2 (B) 485
ing Agents. Me,SiB(OTf),, a New, ‘SuStructures of Two Highly Reactive Inpersilylating’ Reagent (C) 470
termediates upon LiAIH, Reduction
Alumiiiophosphates
in the Solid State and in Solution:
Solid-State NMR Spectroscopic and X[(Me,Si),NAIH,Li . 2Et,O], and
Ray Diffraction Studies of the Low[(Me,Si),N],AIH,Li . 2Et,0 (C) 854
- The Isomers of the Acetvlene DerivaTemperature Structural Transformation
of Hydrated Porous Aluminophosphate
tives C,Li,: Transferabie Structural
VPI-5 (C) 610
Units in Hyperlithiated Compounds (C)
- Solving the Structure of a Metal-Substi1602
tuted Aluminum Phosphate Catalyst by
The New Subnitride NaBa,N; an Extension of Alkali Metal Suboxide ChemElectron Microscopy, Computer Simulation, and X-ray Powder Diffraction
istry (C) 1519
(C) 1472
Alkaloids
A Short Diastereoselective Entry to In- Aluminum compounds
Ab Initio Investigations of Structure
dole Alkaloids of the Corynanthe Type
by the Intramolecular Ene Reaction (C)
and Stability of [E3SiA1],, R = H, Me,
1079
tBu (C) 353
A Novel Six-Center DeprotonationLithiation Reaction Mechanism Supported by the X-Ray Structure Analysis
of a Lithium Carbazolide (C) 1209
A One-Pot Synthesis of Ketones and
Aldehydes from Carbon Dioxide and
Organolithium Compounds (C) 1035
- A Remarkable Change in Framework
Cation Positions upon Lithium Exchange: the Crystal Structure of LiMnPO,(OH) (C) 1090
A Supramolecular Assembly of Two
Torands, Two Lithium Ions, and Three
Water Molecules (C) 348
- A
Water-Complexed Organolithium
Compound :
[LiCH(CN), . H,O . TMEDA], (C) 77
Conformational Preference of the
Torand Ligand in Its Complexes with
Potassium and Rubidium Picrate (C)
34s
- Control of the Reaction of rz-Butyllithiurn with Benzo[b]tellurophene by the
Solvent-Either Metalation or Tellurium-Lithium Exchange To Give an Interesting Lithiostyryllithium (C) 1339
Crystal and Solution Structures of the
Novel Complex of Sodium Ketimide
with Two Ketimine Ligands
[(tBu,C=NNa),(HN=CtBu,),]:
Stacking of Complexed and Uncomplexed (”a),
Rings to give a Highly
Distorted (”a),
Cubane (C) 93
- Diastereoselective Three-Center
Michael Addition of P-Ketoesters to
Prostereogenic x,P-Unsaturated Carbonvl ComDounds Catalvzed bv K X O ,
or &,CO,’(C) 1651
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“Kineticallv Enhanced Metalation”How Substituents Direct ortho Lithiation (C) 755
- LithiodiDhenvlmethvlisocvanide4- )sparteine bis1tetrah;drof;ran): Crystal
Structure of a Lithiated Isocyanide (C)
79
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Structures of Two Highly Reactive Intermediates upon LiAIH, Reduction
in the Solid State and in Solution:
[(Me,Si),NAIH,Li
2 Et,O], and
[(Me,Si),N],AIH,Li
2Et,O (C) 854
- Synthesis and Structure of AI(OAr*),
(Ar* = 2,6-fBuz-4-MeC,H,): The First
Three-Coordinate Homoleptic Aluminum Aryloxide (C) 921
Amidines
The Chemistry of Amidines and Imidates. Vol. 2 (B) 1395
Amines
Molecular Recognition of Primary
Amines by Three-Point Binding with
Boron-Containing Host Molecules (C)
1017
Perfluorotriethylamine: An Amine with
Unusual Structure and Reactivity (C)
1467
Amino acids
- Enzymatic Preparation of Enantiomerically Pure N-alkyl Amino Acids (C) 195
D-amino acids
Proteins from the D-Chiral World (H)
1457
Amino acids
- The Photochemistry of N-Phthaloyl M Amino Acid Esters: A New Approach
to B,y-Unsaturated cc-Amino acids and
Di hydrobenzazepinediones (C) 73
The 31P-NMR Spectroscopic Determination of the Enantiomeric Excess of
Unprotected Amino Acids (C) 1092
Amino alcohols
- Stereoselective Generation of 1-Acyloxy-2-amino Carbanions by Deprotonation; Synthesis of Enantiomerically
and Diastereomerically Pure P-Amino
Alcohols (C) 1505
Amino sugars
- Configuratively Stable Dipeptide Aldehydes from o-Glucosamine Hydrochloride (C) 1391
Ammonium compounds
- Interactions Between Acyclic and Cyclic
Peraikylammonium Compounds and
DNA (C) 1207
Analytical methods
- Atomic Spectroscopy (B) 236
- Detection of Subpicomole Levels of
Compounds Containing Hydroxyl and
Amino Groups with the Fluorogenic
Reagent, 2-Naphthoylimidazole (C) 890
- Microscopy (B) 1534
- Non-Chromatographic Continuous
Separation Techniques (B) 484
Particle Beam Microanalysis. Fundamentals, Methods and Applications (B)
108
- Salting Out Selective Extraction---A
Novel Method for the Optical Resolution of Chiral Sulfinylcarboxylic Acids
and Its Application for the Convenient
Determination of Optical Purity (C)
1631
- Synchrotron X-ray and Neutron Diffraction Studies in Solid-state Chemistry (R) 1557
- The Chemistry of GALLEX-Measurement of Solar Neutrinos with a Radiochemical Gallium Detector (R) 1283
The 31P-NMR Spectroscopic Determination of the Enantiomeric Excess of
Unprotected Amino Acids (C) 1092
Annelations
- Alkyne(carbene) Complexes: Stabilization of an Intermediate of Carbene
Annelation (C) 1236
Annulenes
Corannulene Tetraanion: A Novel Species with Concentric Anionic Rings (C)
1636
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Antibiotics
Enzymatic Preparation of Enantiomerically Pure N-alkyl Amino Acids (C) 195
Antibodies
Activation Parameters and Stereochemistry of an Antibody-Catalyzed Claisen
Rearrangement (C) 182
99mTc Labeled Biotin Conjugate in a
Tumor “Pretargeting” Approach with
Monoclonal Antibodies (C) 1507
Antidepressants
Enantioselective Synthesis of the Antidepressant Rolipram by Michael Addition to a Nitroolefin (C) 870
Antimony compounds
- [SbCI([l 5]Crown-5)](SbCI6), and [BiCI([I 8]Crown-6)(CH,CN),](SbCI6), :
Salts with Antimony(i1i) and
Bismuth(1n) Dications (C) 334
The First Stibepine: Synthesis and
Structurc of Sh-Chlorobenzo[dstibepine (C) 1642
- The Structures of Pentamethyltantalum
and -Antimony: One Square Pyramid
and One Trigonal Bipyramid (C) 1464
Antisense RNA
- Inhibition of Fruit Ripening by Antisense-RNA Technology (H) 175
Antitumor agents
- 1-0-(2-Acetoxyhexadec-l -enyl)choline
Iodide, a New Anticancer Agent (C)
64
- Chlorins Designed for Photodynamic
Tumor Therapy and as Model Systems
for Photosynthesis (C) 1592
- Crosslinking
of Adjacent Guanine
Residues in an Oligonucleotide by
~ ~ . F - [ P ~ ( N H ~ ) , ( H:~Kinetic
O ) ~ ] ~Anal+
ysis of the Two-step Reaction (C)
1483
- Synthesis and Biological Activity of D-3Deoxy-3-Fluorophosphatidylinositol--A New Direction in the Design of nonDNA Targeted Anticancer Agents (C)
1379
Aqua complexes
- Preparation, Ligand Exchange Reactions, and Structure of a Diene(aqua)ruthcnium Complex [(cod)Ru(H,O),](OTs), (C) 440
Arene complexes
- A New Approach to Bis(arene)titanium(o) and -titanium( -I) Complexes;
Structure of Bis(arene)titanates(l - ) (C)
1495
- Benzene and Its Derivatives as Bridging
Ligands in Transition-Metal Complex&
(R) 247
- Ether-Soluble Tio and Bis(@-arene)titanium(0) Complexes from the Reduction of TiC1, with Triethylhydroborate
(C) 1490
- One-Pot Syntheses of Novel Arene Tricarbonyl Chromium Macrocycles and
Macrobicycle: Structure of a Pentanuclear Trichromium(0)-Dicopper(1)
Cryptate (C) 775
Arenes
- Cyclobutarenes. The Chemistry of Benzocyclobutene, Biphenylene, and Related Compounds (B) 1264
- Oligo(9,10-anthrylenes), Organic Compounds with Stable High-Spin States (C)
448
- One-Pot
Multifunctionalization
of
Polymethyl Hydrocarbon x Ligands.
Maximum Space Occupancy by Double
Branching and Formation of Arboroles
(C) 458
- Rate Constants for the Attack of Carbenium Ions at Arenes-A Link between
the Chemistry of Aliphatic and Aromatic n Systems (C) 1613
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Structure of the Lowest Temperature
Phase of the Solid Benzene-Hexafluorobenzene Adduct (C) 1655
- The Benzene Ring as Dienophile in an
Intraniolecular [4+ 21 Cycloaddition :
Degenerate Rearrangement of 7,8-Benzobicyclo[4.2.2]deca-2,4,7,9-tetraene
(C)
872
- Thc First Hexabutadiynylbenzenes:
Synthesis and Structures (C) 1643
Aromaticity
- Aromatic Boron Heterocycles: The
Generation of 1 H-Borepin and the
Structure of Tricarbonyl(1-phenylborepin)molybdenum (C) 1255
Corannulene Tetraanion: A Novel Species with Concentric Anionic Rings (C)
1636
Equilibria between Nonclassical and
Classical Boron Compounds, Competition between Aromaticity in Two and
Three Dimensions (C) 607
- The First Stibepine: Synthesis and
Structure of Sh-Chlorobenzo[dstibepine (C) 1642
Arsenic compounds
An Arsanylidensilane (“Arsasilene”)
and its Derivatization with Tellurium
and Benzophenone(C)316
- (H,Si),E, and (Mes(tBu)Si),E,
(E = As, P): Incommensurable Systems
of Different Stability with Unusually
Long E-E Bonds ( C ) 460
- (0rganoarsonato)polyoxovanadium
Clusters: Properties and Structures of
the Vv Cluster [V,o0,,~,AsC,H,-4NH ),I4- and the V‘ IVY Cluster
~ H ~ ~ V 6 0 1 0 ~ 0 3 A s C ~ H ~(c)
~ ~ ) 197
l i ~
- The Reaction of Tetraniesityldisilene
with As,: Synthesis and Structure of a
Novel Arsenic-Silicon Tricyclic Ring
System (C) 1217
Ary lethenes
C-C Coupling with NOJAlkyl Substitution at the Vinylic Carbon by Reaction of 2-Arvl-I-nitro-I-alkeneswith
Dialkylzinc Compounds-A Novel Reaction (C) 1587
Arynes
2,4-Didehydrophenol-First Proof of a
metu-Aryne by IR Spectroscopy (C)
1230
Asymmetric syntheses
- A Short Diastereoselective Entry to Indole Alkaloids of the Corynanthe Type
by the Intramolecular Ene Reaction (C)
1079
- “Artificial Metabolisms” for the Asymmetric One-Pot Synthesis of BranchedChain Saccharides (C) 614
- Asymmetric Deprotonation as an Efficient Enantioselective Preparation of
Functionalized Secondary Alcohols (H)
1459
Asymmetric Ligands for TransitionMetal-Catalyzed
Reactions: 2-Diphenylphosphinobenzoyl Derivatives of
C,-Symmetric Diols and Diamines (C)
228
- truns-2-tert-Butylcyclohexanol,
a
Simple Selectively Optimized Cyclohexanol Auxiliary (C) 1190
- Diacetoneglucose as Auxiliary Group
for the Asymmetric Hetero-Diels-Alder
Reaction with Nitrosoalkenes (C) 1033
- Diastereoselective Addition of Allylsilanes to Aldehydes: Synthesis of Enantiomerically Pure Homoallylic Alcohols
(C) 1372
Diastereoselective Complexation of
Temporarily Chirally Modified Ligands: Enantioselective Preparation and
Configurational Assignment of Synthet-
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Angrw. Chcm. Int. Ed. Engl. 1992, 31, N o . 12
ically Valuable q6-Tricarbonylchromi- - Scanning Tunneling Microscopy and
Atomic Force Microscopy in Organic
um-l -tetralone Derivatives (C) 631
Chemistry (R) 1298
- Diastereoselective Synthesis of Substituted Cyclohexadienes from Enan- Atropo-enantioselectivi ty
- First
Atropo-Enantioselective Ring
tiomerically Pure Tricarbonyl(2-phenylOpening of Achiral Biaryls Containing
4.5-dihydrooxazole)chromium ComLactone Bridges with Chiral Hydrideplexes (C) 1071
Transfer Reagents Derived from Borane
Diastereoselective Three-Center
(C) 761
Michael Addition of P-Ketoesters to
Aza crown ethers
Prostereogenic %$-Unsaturated Car- Designing Synthetic Cationic Molecular
bony1 Compounds Catalyzed by K,CO,
Receptors for Alcohols (C) 478
or Cs,CO, (C) 1651
Azaallenium ion
- Enantiomerically Pure Tertiary Alcoof a
hols by TADDOL-Assisted Additions - Tetraferrioazaallenium-Product
Novel Reaction of Coordinated C N to Kctoncs-or How to Make a Grig(C) 590
nard Reagent Enantioselective (C) 84
Azdbordnes
Enantioselective Rhodium(rr) Catalysts
- Opening of an Aza-clam-dodecaborane
(H) 1183
to an Aza-nido-dodecaborate (C) 1227
- Enantioselective Syntheses of CyclopenAzacyclopen tadiene
tanoid Compounds from Isoprene and
- 2,2‘,5,5’-Tetra-tert-butyl-l,l‘-diazatruns-1.3-Pentadiene (C) 305
plumbocene-a Stable AzacyclopentaEnantioselective Synthesis of 3-Substidienyl Compound of Lead (C) 778
tuted 2-Ketoesters (C) 61 8
Azines
- Enantioselective Synthesis of the Antidepressant Rohprdm by Michael Addi- - An Organometallic Analogue of the
“Criss-Cross” Cycloaddition Reaction
tion to a Nitroolefin (C) 870
(C) 1053
- me.^ Epoxides in Asymmetric SynthcAziridines
sis: Enantioselective Opening by
Nucleophiles in the Presence of Chiral - The Total Synthesis of (+)-Mitomycin K (C) 91 5
Lewis Acids ( H ) 1179
First Atropo-Enantioselective Ring Azobenzenes
- Photoswitchable Association of an AzoOpening of Achiral Biaryls Containing
benzene-Bipyridinium Diad to Eosin:
Lactone Bridgcs with Chiral HydridePhotostimulated “On-Off” Guest BindTransfer Reagents Derived from Borane
ing (C) 1243
(C) 761
- Formate-Driven, Non-Enzymatic
Band theory
NAD(P)H Regeneration for the
- Band Theory of Solids. An introduction
Alcohol Dehydrogenase Catalyzed
from the Point of View of Symmetry (B)
Stereosclective Reduction of
1097
4-Phenyl-2-butanone (C) 1529
Barium compounds
Ligand Effccts in Grignard Additions
- Alkoxyalkyl-Substituted P-Diketonate
(C) 342
Complexes of Barium and Copper: Evi- New
Chiral r-Benzyloxyacryliron(I1)
dence for Inter- and Intramolecular StaComplcx for Asymmetric Synthesis of
bilization (C) 735
%,a-Dialkyl-a-hydroxycarbonyl Com- The New Subnitride NaBa3N; an Expounds (C) 193
tension of Alkali Metal Suboxide ChemOne-Pot Synthesis of Tagatose 1,6-Bisistry (C) 1519
phosphate by Diastereosclective EnzyBeilstein test
matic Aldol Addition (C) 56
- The Beilstein Test: An Unintentional
- Oxazaborolidines and Dioxaborolidines
Dioxin Source in Analytical and Rein Enantioselective Catalysis (H) 729
search Laboratories (C) 443
- Stereocontrollcd
Construction
of
6 . 5 6 and 5 5 . 6 Ring Systems Belousov-Zhabotinskii reaction
by Radical Tandem Cyclization (C) - Chemiluminescence Oscillations Driven
by a Flow-through Reactor in the
910
[Ru( bpy ) 3]
Catalyzed BelousovStereosclective Generation of 1-AcylZhabotinskii Reaction (C) 355
oxy-2-amino Carbanions by DeprotoBenzazepines
nation; Synthesis of Enantiomerically
and Diastereomerically Pure P-Amino - The Photochemistry of N-Phthaloyl aAmino Acid Esters: A New Approach
Alcohols (C) 1505
to P,y-Unsaturated %-Amino acids and
Stereosclectivc Nucleophilic Addition
Dihydrobenzazepinediones (C) 73
Reactions of Reactive Pseudopeptides
Benzothiazoles
(C) 1626
Sugars as Chiral Auxiliaries for the Syn- - A 1 : 1 Adduct of 2-Aminobenzothiazole
and a Urea Derivative, and Its Spatial
thesis of Enantiomerically Pure ComArrangement (C) 1634
pounds (H) 288
Biaryls
- The Hydroxyl-Directed Hydrogenation
of Vinylstannanes and Silanes: A Highly - First Atropo-Enantioselective Ring
Opening of Achiral Biaryls Containing
Diastereoselective Route to P-Stannyl
Lactone Bridges with Chiral Hydrideand fi-Silyl Alcohols (C) 232
Transfer Reagents Derived from Borane
The Tandem Sakurai-Carbonyl-Ene
(C) 761
Reaction: A New and Highly StereoBifluorenes
selective Sequential Transformation and
- Enantioselective Complexation of ChiIts Use for the Synthesis of Steroid
ral Dicarboxylic Acids in Clefts of FuncDerivatives (C) 1221
tionalized 9.9’Spirobifluorenes (C) 1521
Atomic force microscopy
Binaphthol complexes
Photodimerization of Anthracenes in
thc Solid State: New Results from - Unprecedented Stereospecific Ligand
Exchange at a W = W Template (C) 66
Atomic Force Microscopy (C) 595
- Photodimerization of Cinnamic Acid in
Biochemical messengers
the Solid State: New Insights on Appli- - Biochemical Messengers. Hormones,
Neurotransmitters and Growth Factors
cation of Atomic Force Microscopy (C)
(B) 657
592
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A i i g r k . Uim
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Ed. Engl. 1992. 31. N o . 12
Biochemistry
Biochemical Degradation of Cyanamide
and Dicyandiamide (C) 620
- 5’-P-Borane-Substituted
Thymidine
Monophosphate and Triphosphate (C)
1373
- Do Pheromone Receptors that Receive
the Same or Similar Signal Molecules
Have the Same or Similar Structure? (C)
330
Elementary Steps in Synaptic Transmission Revealed by Currents through
Single Ion Channels (Nobel Lecture)
(R) 830
Inorganic
Biochemistry of iron
Metabolism (B) 930
- ion Channels for Communication Between and Within Cells (Nobel Lecture)
(R) 824
Molecular Mechanism for Sensory Signals (B) 659
Natural Products as Probes of Cellular
Function: Studies of Immunophilins
(R) 384
- Radical Intermediates in the Coenzyme
B,, Dependent Methylmalonyl-CoA
Mutase Reaction Shown by ESR Spectroscopy (C) 215
- Selective Inhibition of Trypanosomal
Triosephosphate Isomerase by a Thiopeptide (C) 328
- Synthesis
of (2-Arylindol-3-yl)acetamides as Probes of Mitochondria1
Steroidogenesis-A
New Mechanism
for GABA, Receptor Modulation (C)
1060
- Synthesis of Octameric Phosphodiesters
of [3,3-Bis(hydroxymethyl)cyclobutyl]adenine and -thymine as well as their
Hybridization Properties (C) 482
- The Biochemistry and Uses of Pesticides. Structure, Metabolism, Mode of
Action and Uses in Crop Protection (B)
242
Bioinorganic chemistry
- Biocoordination Chemistry: Coordination Equilibria in Biologically Active
Systems (B) 803
- Synthesis of Cubane-like and Double
Cubane-like Tungsten-Copper-Sulfur
Clusters from the “Butterfly” Cluster
[Cu,S3W(O)(PPh3)31 (C) 1085
- Synthetic Models for Iron-Oxygen
Aggregation and Biominerdlization (H)
1010
Tris(cyclopentano1ato)oxovanadium(v): a Model for the Transition State
of Enzymatic Phosphoester Cleavage
(C), 447
Biomineralization
Control and Design Principles in Biological Mineralization (R) 153
- Synthetic Models for Iron-Oxygen
Aggregation and Biomineralization (H)
1010
Biopolymers
- Photolithographic
Immobihzdtion of
Biopolymers on Solid Supports (C) 759
Bioscnsors
- Molecular Mechanism for Sensory Signals (B) 659
Biotechnology
- Biotechnology. A Multi-Volume Comprehensive Treatise. Vol. 4. Measuring,
Modelling and Control (B) 1397
Biotin
99mTcLabeled Biotin Conjugate in a Tumor “Pretargeting” Approach with
Monoclonal Antibodies ( C ) 1507
Biradicals
2,4-Didehydrophenol-First
Proof of a
meta-Aryne by I R Spectroscopy (C)
1230
-
-
-
-
-
-
-
-
-
1673
Bismuth compounds
Bismuth Alkoxide Dimer Complexes
Containing Planar Bi,(p-OR), Cores:
Svntheses and Structures of
-
[SbCl([l 5]Crown-5)](SbCI6), and [BiCI([1S]Crown-B)(CH,CN),](SbCI,), :
Salts with Antimony(II1) and
Bismuth(nr) Dications (C) 334
Blood substitutes
- Protein Engineering: Modified
Hemoglobin as a Blood Substitute (H)
848
Bond-stretch isomerism
- Bond-Stretch Isomers: Fact or Artifact?
(H) 286
- Distortional Isomerism in Oxomolybdenum Systems; the Evidence Re-evaluated (C) 1607
Boron compounds
- Aromatic Boron Heterocycles: The
Generation of 1H-Borepin and the
Structure of Tricarbonyl( 1 -phenylborepin)molybdenum (C) 1255
- Bis(trisy1)oxadiborirane (C) 1040
- 1-Borabutadiene(cyclopentadieny1)cobalt Complexes (C) 1603
- 5’-P-Borane-Substituted
Thymidine
Monophosphate and Triphosphate (C)
1373
- Boriranes: Structures and Thermal Ring
Openings (C) 1384
- Compounds with Three-Membered
Rings Containing Boron (H) 1329
- Cyclometallaborazines: Borazines with
Metal Atoms as Ring Building Blocks:
PhB(MeN),(TiCI,), (C) 598
- Electron Deficient Boron and Carbon
Clusters (B) 660
- Equilibria between Nonclassical and
Classical Boron Compounds, Competition between Aromaticity in Two and
Three Dimensions (C) 607
- First Atropo-Enantioselective Ring
Opening of Achiral Biaryls Containing
Lactone Bridges with Chiral HydrideTransfer Reagents Derived from Borane
(C) 761
- Formation of a 2,5-Diborabicyclo[2.1.l]hexane Derivative and its Conversion to a Tetracarbahexaborane (C) 606
- Homodiboriranides: The Simplest Negatively Charged Homoaromatic Compounds (C) 1238
- Large Hyperconjugative and Inductive
Effects on C-C-X Bond Angles
(X = Main-Group Element): The Crystal Structure of Triethylborane and Ab
Initio Investigations (C) 314
- Molecular
Recognition of Primary
Amines by Three-Point Binding with
Boron-Containing Host Molecules (C)
1017
-
[NblB(rlb-C,H,),(CsH,),j(rlzH,CC,CH,)]: the First Compound with
Bent Tetraphenylborate as 12-Electron
Donor Ligand (C) 1235
- “Non-Coordinating” Anions: Underestimated Ligands (H) 1181
- Opening of an Aza-closo-dodecaborane
to an Aza-nido-dodecaborate (C) 1227
- Oxazaborolidines and Dioxaborolidines
in Enantioselective Catalysis (H) 729
- Reduction of a Boron-Nitrogen 1,3-Butadiene Analogue: Evidence for a
Strong B-B n-Bond (C) 1082
- Synthesis and Structure of the First
Trinuclear, Half-Sandwich Carboranegadolinium(II1) Cluster (C) 432
- The Green Flame: Surviving Government Secrecy (B) 1096
-
1674
Calicheamicins
Synthesis of the Calicheamicin Aryltetrasaccharide Domain Bearing a Reducing Terminus: Coupling of Fully
Synthetic Aglycone and Carbohydrate
Domains by the Schmidt Reaction (C)
338
- Total
Synthesis of CalicheamicinDynemicin Hybrid Molecules (C) 340
Calixarenes
Bicyclocalix[4]arenes (C) 96
Nitrocalix[4]arenes as Molecules for
Second-Order Nonlinear Optics (C)
1075
Calorimetry
- Microcalorimetry of the Spin-Transition
S ystems [Fe(bts),( NCS) z] and [Fe(2pic),]CI, . EtOH
in
the
Range
15 K < T < 300 K (C) 178
- The Stability of Buckminsterfullerene
I n37
(C,,): Experimental Determination of
the Heat of Formation (C) 63
Carbanions
- Preparative Polar Organometallic
Chemistry 2 (B) 485
bly End-On-Bound H,NN’H, Bridging
- Stereoselective Generation of 1-AcylLieands (C) 87
oxy-2-amino Carbanions by Deproto- Molecular Machines: Molecular Strucnation; Synthesis of Enantiomerically
ture of [(p-Tol,P),,Au,,Ag,,C18]and Diastereomerically Pure P-Amino
( P F , t a Cluster with a Biicosahedral
Alcohols (C) 1505
Rotorlike Metal Core and an Unusual
Arrangement of Bridging Ligands (C) Carbene complexes
Alkyne(carbene) Complexes: Stabiliza44 5
tion of an Intermediate of Carbene
- P ridine-2-thiolato Complexes of V”,
Annelation (C) 1236
V”, and V“ with Unusual Structural
Carbene Osmium Complexes by Double
Features (C) 1253
Metalation of Alkoxylalkyl- and
- Stable Intermediates in the Addition
Aminoalkylphosphanes (C) 1025
and Elimination of SnBuCI, at Molybdenum Centers by Cleavage or Forma- - Detection of the Tungsten-CarbeneOlefin Intermediates in Catalytic Metation of an Sn-CI Bond: Crystal Structhesis Systems Containing High-Valent,
ture
of
[Mo(CO),(PCy,)(p-Cl)(pMetal Centers (C)
S,CPCy,)(BuSnCI,)] . CH,CI, (C) 76
~, 1585
Carbenes
- The
Reaction of [Cp;Nb,(B,H,)J
(Cp’ = 7-EtMe,C,) with Sulfur: Stabi- - Enantioselective Rhodium(r1) Catalysts
(H) 1183
lization of the Tetrathioborato Ligand
in Novel Sulfido Niobium Clusters (C) Carbocations
- Cyclohexadienyl-Type Cationic Inter1021
mediates in the Friedel-Crafts Alkyla- The
Trapping of Iron Hydroxide
tion of Benzene Derivatives with the 9Units by the Ligand “heidi”: Two
Fluorenyl Cation-Observation
by
New Hydroxo(oxo)iron Clusters ConLaser Flash Photolysis (C) 743
taining 29 and 17 Iron Atoms (C)
- Houben-Weyl. Methoden der Organi191
schen Chemie. Band E19c: CarboButadienes
kationen, Carbokation-Radikale (B)
- Synthesis and Reactions of Isothio799
cyanate-Substituted Allenes and 1,3- Kinetics of Hydride Transfers from CH,
Butadienes (C) 90
SiH, GeH, and SnH Groups to Carbeni- Synthesis of Isocyanate-Substituted Alum Ions (C) 1046
lenes and 1,3-Butadienes by [3,3] SigmaCarbohydrates
tropic Rearrangements (C) 866
- A New Strategy for Solid-Phase SyntheButatrienes
sis of 0-Glycopeptides (C) 857
- Butatrienes by Desulfurization of Cyclic
- “Artificial Metabolisms” for the AsymTrithiocarbonates (C) 1611
metric One-Pot Synthesis of BranchedChain Saccharides (C) 614
Cadmium compounds
- Carbohydrates as Organic Raw Materi- Indirect ‘13Cd,14N Spin-Spin Coupling
als (B) 361
Constants as a Structural Probe of Solid
Detection of Subpicomole Levels of
Cadmium Thiocyanate Complexes ( C )
Compounds Containing Hydroxyl and
1222
Amino Groups with the Fluorogenic
Cage compounds
Reagent, 2-Naphthoylimidazole (C) 890
- A Donor Cage with Two TetrathiafulEmil Fischer’s Proof of the Configuravene Units (C) 309
tion of Sugars: A Centennial Tribute (R)
- A New Reaction Type in the Conversion
1541
of Enamines with 1,4-Diphenyl-ZOne-Pot Synthesis of Tagatose 1,6-Bisbutene-l,4-dione to Give Cage Comphosphate by Diastereoselective Enzypounds (C) 768
matic Aldol Addition (C) 56
A Rh’-Centered Cage Compound
Reagents with Hypervalent Iodine: Forwith Selective Catalytic Properties (C)
mation of Convenient Chiral Synthetic
905
Intermediates by Fragmentation of Car- C,,H,,-Tetrahedral
Clamping of
bohydrate Anomeric Alkoxy Radicals
Four Benzene Rings in a Spherical Hy(C) 772
drocarbon Framework (C) 1069
Selective Binding of Sugar to /?-CycloSelective Ketone Pyrolysis: New Syndextrin: A Prototype for Sugar-Sugar
thetic Method for Mono- and Polycyclic
Interactions in Water (C) 745
Hydrocarbons (C) 307
Zinc Pyrazolylborate Complexes Relevant to the Biological Function of Carbonic Anhydrase (C) 92
Bredt rule
- Anti-Bredt Enol Ethers by Transannular
Cyclization of Cycloalkynols (C) 791
Bridging ligands
- A New Structure-Magnetism Relationship for Face-Sharing Transition-Metal
Complexes with d3-d3 Electronic Configuration (C) 31 1
- A Structurally Distorted Ligand in an
Electron-Deficient Dizirconocene
Cation: Unusual 1,2- and 1.1-Dimetallioalkenes (C) 876
- Benzene and Its Derivatives as Bridging
Ligands in Transition-Metal Complexes
(R) 247
- Double Open-Edged PI,, Dihydrofulvalene as a 16-Electron Donor Ligand (C)
-
-
-
-
-
-
-
-
-
-
-
-
Angrit. Chem. In[. Ed Engi. 1992, 31, No. 12
Sugars as Chiral Auxiliaries for the Synthesis of Enantiomerically Pure Compounds (H) 288
Synthesis and Biological Activity of D-3Deoxy-3-FluorophosphatidylinositolA New D.irection in the Design of nonDNA Targeted Anticancer Agents (C)
1379
Synthesis of Esterase-resistant 9-UAcetylated Polysialoside as Inhibitor of
Influenza C Virus Hemagglutinin (C)
1478
Synthesis of C-Glycopeptides via Free
Radical Addition of Glvcosvl Bromides
to Dehydroalanine Dehvat&es (C) 902
Carbon dioxide
A One-Pot Synthesis of Ketones and
Aldehydes from Carbon Dioxide and
Organolithium Compounds (C) 1035
Carbon-carbon linkage
Addition of Benzvl Radicals to Alkenes:
The Role of Radical Deformation in the
Transition State (C) 635
Alkyne(carbene) Complexes: Stabilization of an Intermediate of Carbene
Annelation (C) 1236
Allylation of Quinones with Allylsilane
in the Presence of Lithium Perchlorate
in Ether (C) 313
Assistance by Electrophiles in Photoinduced Alkylidyne-Carbonyl Coupling
(C) 747
Catalysis of the Addition of Allyltrimethylsilane to Aldehydes by Silylating Agents. Me,SiB(OTf),, a New, ‘Supersilylating’ Reagent (C) 470
C-C Coupling with NO,/Alkyl Substitution at the Vinylic Carbon by Reaction of 2-Aryl-I-nitro-1-alkeneswith
Dialkylzinc Compounds-A Novel Reaction (C) 1587
Enantiomerically Pure Tertiary Alcohols by TADDOL-Assisted Additions
to Ketones---or How to Make a Grignard Reagent Enantioselective (C) 84
New Route to x-[(IE,3E)-dienyl]allenes
via Butadiene-tricarbonyliron Complexes (C) 224
Palladium(o)-Catalyzed Three-Component Coupling Reaction of Allyl Benzoates, Carbon Monoxide, and Zincioesters (C) 645
Reaction of Heterodinuclear ,u-Ethynediyl Complexes Containing Palladium
and Platinum: Multiple and Successive
Insertion of Isocyanides (C) 851
Carbonic anhydrase
- Zinc Pyrazolylborate Complexes Relevant to the Biological Function of Carbonic Anhydrase (C) 92
Carbonylation (B) 662
Carboranes
Formation of a 2,5-Diborabicyclo[2.1.l]hexane Derivative and its Conversion to a Tetracarbahexaborane (C) 606
- Multidentate Macrocyclic Lewis Acids:
Release of “[ 121 Mercuracarborand-4”
from Its Iodide Complex and the Structure of Its Tetra(tetrahydr0furan) Dihydrate Complex (C) 893
Synthesis and Structure of the First
Trinuclear, Half-Sandwich Carboranegadolinium(rr1) Cluster (C) 432
Carbosilanes
On the Bonding in Carbosilanes (C) 185
Carboxylic acids
- A Simple Method for the Replacement
of the OH Group in Free Carboxylic
Acids by the Phosphonium Ylide Group
(C) 1064
- Enzymatic Oxidation of Methyl Groups
on Aromatic Heterocycles: A Versatile
Method for the Preparation of Het-
-
-
-
A n , q w . C‘hcm. I n f . Ed. Ennl. 1992, 31, N o . 12
eroaromatic Carboxylic Acids (C)
774
Carbyne complexes
New Routes to Alkylidyne-Bridged Ditungsten Compounds Supported by
Alkoxide or Siloxide Ligands by the Activation of Ethvlene
462
Caro’s acid
- Caro’s Acid: Molecular Structure and
Association in the Solid State at
- 130 “C (C) 436
Caro tenoids
- Dual Fluorescence of Novel Modified
Carotenoids (01042
Cascade molecules
Dendrimers, Arborols, and Cascade
Molecules: Breakthrough into Generations of New Materials (H) 1571
Catalysis
- A Rh’-Centered Cage Compound with
Selective Catalytic Properties (C) 905
Activation Parameters i n d Stereochemistry of an Antibody-Catalyzed Claisen
Rearrangement (C) 182
- Asymmetric Ligands for TransitionMetal-Catalyzed
Reactions:
2-Diphenylphosphinobenzoyl Derivatives of
C,-Symmetric Diols and Diamines (C)
228
[tBuSiO(ReO,)],, a Model Compound
for Metal Oxides on Silicate SurfacesSynthesis from the Stable Trio1 tBuSi(OH), and Re,O, (C) 599
- Catalysis of the Addition of Allyltrimethylsilane to Aldehydes by Silylating Agents. Me,SiB(OTf),, a New, ‘Supersilylating’ Reagent (C) 470
Cationic Metallocene Polymerization
Catalysts. Synthesis and Properties of
the First Base-Free Zirconocene Hydride (C) 1375
- Dependence of the Reactivity of Ag and
Ni Clusters Deposited on Solid Substrates on the Cluster Size (C) 1062
High Molecular Weight Polypropylene
through Specifically Designed Zirconocene Catalysts (C) 1347
- Metal-Surface
Reaction Energetics.
Theory and Applications to Heterogeneous Catalysis, Chemisorption, and
Surface Diffusion (B) 1538
Model Compounds for Metal Oxides on
SiO, Surfaces (H) 586
On the Influence of Heteroatoms in xand P-Functionalized Alkyl TransitionMetal Compounds (R) 401
- Oxazaborolidines and Dioxaborolidines
in Enantioselective Catalysis (H) 729
- Proof of the Catalytic Activity of a
Naked Metal Cluster in the Gas Phase
(C) 636
Regioselectivity Control in the Palladium-Catalyzed Copolymerization of
Propylene with Carbon Monoxide (C)
303
Selective Oxidation of Methane to CO
and H, over Ni/MgO at Low Temperatures (C) 1189
- Selectivity Control By Temperature
Variation in the Formation of Isotactic
vs. Syndiotactic Polypropylene with a
Titanocene/Alumoxane Catalyst (C) 199
- Synthesis of Optically Active Macromolecules Using Metallocene Catalysts
(HI 47
‘Bis(oxazo1ines)’ as Ligands for SelfAssembling Chirdl Coordination Polymers-Structure of a Copper(1) Catalyst
for the Enantioselective Cyclopropanation of Olefins (C) 430
Catenanes
One-Step Synthesis of a Fourfold Functionalized Catenane (C) 1619
-
\
-
-
-
-
-
-
-
-
-
-
-
,
Ceramics
The Thermal Conversion of Poly[(silylene)diacetylene] Metal Oxide Composites: A New Approach to P-SiCMC Ceramics (C) 1195
Cesium effect
- Does the Naked Fluoride Ion Exist? (H)
292
C-H activation
Palladium-Catalyzed C-H Activation of
Methoxy Groups: A Facile Synthesis of
Substituted 6H-Dibenzo[b,d]pyrans (C)
1023
Chalcogen comoounds
Newtayered Iron-Lanthanum-OxideSulfide and -Selenide Phases:
Fe,La,O,E, (E = S,Se) (C) 1645
Charge transfer complexes
- A Donor Cage with Two Tetrathiafulvene Units (C) 309
Three-Dimensional Structure of an Unsymmetrical Proton-Electron Transfer
System Containing a Disulfide Bond:
The Bis(4-hydroxyphenyl)disulfideBenzoquinone Complex (C) 852
Chelate ligands
- Chelate
Complexes of Tripodal,
Aliphatic Triisocyanide Ligands (C)
1212
Chelate Stabilization of a Monomeric
Lithium Tellurolate (C) 1260
- Transition Metal in a CubeA Discrete Eight-Coordinate
[Mn2+c [2.2.2]cryptand] as a BodyCentered Cube with an N,O, Donor Set
(C) 764
Chemiluminescence
Chemiluminescence Oscillations Driven
by a Flow-through Reactor in the
[Ru(bp y),]
Catalyzed Belo usovZhabotinskii Reaction (C) 355
Chemistry of the atmosphere
- Transport and Fate of Organic Compounds in the Global Environment (R)
487
Chemometrics
Chemometrics. Applications of Mathematics and Statistics to Laboratory Systems (B) 663
Chiral auxiliaries
- Asymmetric Ligands for TransitionMetal-Catalyzed
Reactions : 2-Diphenylphosphinobenzoyl Derivatives of
C,-Symmetric Diols and Diamines (C)
228
- trans-2-tert-Butylcyclohexanol,
a
Simple Selectively Optimized Cyclohexanol Auxiliary (C) 1190
- Diacetoneglucose as Auxiliary Group
for the Asymmetric Hetero-Diels-Alder
Reaction with Nitrosoalkenes (C)
1033
Diastereoselective Complexation of
Temporarily Chirally Modified Ligands: Enantioselective Preparation and
Configurational Assignment of Synthetically Valuable q6-Tricarbonylchromiurn-1-tetralone Derivatives (C) 631
- Sugars as Chiral Auxiliaries for the Synthesis of Enantiomerically Pure Compounds (H) 288
Chirality
- A Diels-Alder Route to [5]- and [6]-Helicenes (C) 1093
Chirality and Optical Activity in
Organometallic Compounds (B) 1096
- Chirality-From
Weak Bosons to the
a-Helix (B) 800
Enantioselective Polymerization of 1,2Diisocyanoarenes-Synthesis
of Optically Active, Helical Poly(quinoxa1ine2,3-diyl)s (C) 1509
On Quantifying Chirality (R) 989
-
\
I
-
-
-
-
-
’,:
-
-
-
-
-
1675
Solid-state Columns Made from Twist- - Molecular Machines: Molecular Struc- Complexes with carbon ligands
ed, Self-Complementary Terpyridine
ture of [(p-Tol,P),,Au13Agl,C18]- A Paramagnetic, Mononuclear
Units (C) 1244
(PF+a
Cluster with a Biicosahedral
Organometallic Iridium(1r) Complex:
Chlorinated hydrocarbons
Rotorlike Metal Core and an Unusual
[Ir(C,Cl,),(cod)] (C) 1527
- Formation of a Toxic Dimerization
Arrangement of Bridging Ligands (C)
Mutual Catalysis of Neutral and AnionProduct of 3,4-Dichloroaniline by Lig44 5
ic Cobalt Carbonyls in their CO Scramnin Peroxidase from Phanerochaete - New Directions in Polyvanadate Chembling Reactions (C) 1596
chrysosporiurn (C) 68
istry: From Cages and Clusters to Bas- - On the Influence of Heteroatoms in (Y- The Beilstein Test: An Unintentional
kets, Belts, Bowls, and Barrels (H) 49
and /I-Functionalized Alkyl TransitionDioxin Source in Analytical and ReNew Intermediate Steps in the Synthesis
Metal Compounds (R) 401
search Laboratories (C) 443
of Larger Nickel Clusters (C) 321
- Tetraferrioazaallenium-Product
of a
Chlorins
- [Ni(PtBu),]-a
Strain on the 18 ElecNovel Reaction of Coordinated C N Chlorins Designed for Photodynamic
tron Rule? (H) 424
(C) 590
Tumor Therapy and as Model Systems - Novel Iron Carbonyl Telluride
Complexes with hydrido ligands
for Photosynthesis (C) 1592
Clusters: Synthesis and Charac- “[Cp*Co=CoCp*]” is a Hydride (C)
Chlorophins
terization of [F~,Tc,(CO),,]~- and
1341
- First Example of a Chlorophin from an
- [Cp*Cr(p,-H)],-a
Paramagnetic
[Fe,Te,,(CO),,IZ- (C) 913
Unexpected Oxidative Ring-Opening of
Chromium Hydride with a Cubane
Oxoniobates Containing Metal Clusters
Structure (C) 1077
an
(Octadehydrocorrinato)nickel(iI)
(R) 1437
Salt (C) 70
Dynamic Motion in [HFe(CO),]- Ions
- [(Ph,PAu),Mn(CO),]’,
a Cluster with
Choline derivatives
as Observed by Mossbauer SpecPentagonal-Bipyramidal Structure (C)
- 1-0-(2-Acetoxyhexadec-1-enyl)choline
troscopy-Evidence for Hydride “Tun464
Iodide, a New Anticancer Agent (C) 64
neling” (C) 884
Si,,, an Analogue of C,,? (H) 173
Chromatography
New Routes to Alkylidyne-Bridged DiStructure and Reactivity of Silicon Clustungsten Compounds Supported by
Handbook of Thin Layer Chromatograters in the Gas Phase (H) 172
Alkoxide or Siloxide Ligands by the Ac- Synthesis and Structure of [Ni(PtBu,)]
PhY (B) 360
tivation of Ethylene (C) 462
Chromium compounds
and [Ni,(PtBu),(CO),] and CalculaA New Structure-Magnetism Relationtions on the Electronic Structure of - On the Mechanism of Coherent Dihydrogen Tunneling in Transition Metal
ship for Face-Sharing Transition-Metal
[Ni(PfBu),] and (PR),, R = tBu, Me (C)
Trihydrides (C) 1369
Complexes with d3-d3 Electronic Con323
figuration (C) 31 I
Synthesis and Structure of the Cluster - On the Reaction of Pentamethylcyclopentadiene with Cobalt Atoms: A
[Cp *Cr(p H)],-a
Paramagnetic
[NaAu1,Se,l3- : An Inorganic CrypReexamination 1392
Chromium Hydride with a Cubane
tand Complex (C) 787
Transition Metal Hydrides (B) 1537
Structure (C) 1077
- Synthesis, Structure, and Bonding of
- Diastereoselective
Complexation of
[CpCoW,(OCH,tBu),], and Comments Complexes with nitrogen ligands
Arborols Based on Luminescent and
Temporarily Chirally Modified Ligon the Combining Properties of CO and
Redox-Active Transition Metal Comands: Enantioselective Preparation and
CpCo (C) 896
plexes (C) 1493
Configurational Assignment of Synthet- Synthetic Models for Iron--Oxygen Agically Valuable $-Tricarbonylchromigregation and Biomineralization (H) - Crystal and Solution Structures of the
Novel Complex of Sodium Ketimide
um-I-tetralone Derivatives (C) 631
1010
with Two Ketimine Ligands
- Diastereoselective Synthesis of Substi- The Trapping of Iron Hydroxide Units
[(tBu,,C=NNa),(HN=CtBu,),]:
tuted Cyclohexadienes from Enanby the Ligand “heidi”: Two New HyStacking of Complexed and Uncomtiomerically Pure Tricarbonyl(2-phenyldroxo(oxo)iron Clusters Containing 19
plexed (”a),
Rings to give a Highly
and 17 Iron Atoms (C) 191
4,5-dihydrooxazole)chromium ComDistorted (“a),
Cubane (C) 93
Cobalt compounds
plexes (C) 1071
- One-Pot Syntheses of Novel Arene Tri- 1-Borabutadiene(cyclopentadi- [Et,NI,[JMO(S,),~,(~,-S,)(~,HZNNH,)] (M = Mo, W)-Doubly
eny1)cobalt Complexes (C) 1603
carbonyl Chromium Macrocycles and
Bridged Complexes with S: and DouMacrobicycle: Structure of a Penta- - “[Cp*Co=CoCp*]” is a Hydride (C)
bly End-On-Bound H,NN’H2 Bridging
nuclear Trichromium(0)-Dicopper(r)
1341
Ligands (CJ 87
Cryptate (C) 775
- Cyclopentadienyl Cobalt Complexes of
- Indirect
Cd.’,N %in-Suin Couding
Cobaltapentalenes: Products Formed
- Stepwise Stacking of Three ParamagConstants as a Structiral Probe of Solid
by Reaction of (p-Cyclopentadienylnetic Metallocene Units: [CpNiCpCadmium Thiocyanate Complexes (C)
( S ~ M C , ) , C ~ C ~ C ~ ( S ~ M C , ) (C)
~ C ~ N ~idene)
C ~ ] Cobalt Complexes with Silyl1222
alkynes (C) 1058
1258
Nitrido Complexes of Transition Metals
Circular dichroism
- Inhibition of the [2+2+2] Cyclization
(R) 955
by the Formation of Chelates: Alkyne
- Chirality
and Optical Activity in
and Vinylidene Complexes with Cy- - Pgidine-2-thiolato Complexes of V“,
Organometallic Compounds (B) 1096
V , and VIV with Unusual Structural
clopentadienylcobalt(I) (C) 1066
Claisen rearrangements
Features (C) 1253
- Activation Parameters and StereochemMutual Catalysis of Neutral and Anionistry of an Antibody-Catalyzed Claisen
ic Cobalt Carbonyls in their CO Scram- - Self-Assembly of a Cu, Complex with
Coplanar Copper(1) Ions: Synthesis.
bling Reactions (C) 1596
Rearrangement (C) 182
Structure, and Electrochemical Proper- New
Thermo-Response Dyes: Col- - Novel Metal Thiolates:
ties (C) 733
oration by the Claisen Rearrangement
[Co,(SC,H,),]-,
the First Complex
and Intramolecular Acid-Base Reaction
with Face-Sharing MS, Tetrahedra (C) - Synthesis and Structure of a Mononuclear $-Hydrazine Complex by Pro1368
(C) 204
tonation of an [N,H,]*- Complex (C)
- On the Reaction of PentamethylcyClosest packings
1081
- Are Denser Packings of Spheres than
clopentadiene with Cobalt Atoms: A
The First Reaction of S,N,; Structure
Closest Packings Possible? How Many
Reexamination 1392
of a Complex Containing an S,N; LigClosest Packings of Spheres Exist? (H) - The Electrochemical Oxidation of
and (C) 616
[Co”(salen)] in Solvent Mixtures- ---An
727
The Synthesis and Structure of an UnExample of a Ladder Scheme with
Clusters
usual Uranium Pentachloride DerivaCoupled Electron-Transfer and Solvent- Dependence of the Reactivity of Ag
tive (C) 72
Exchange Reactions (C) 1215
and Ni Clusters Deposited on Solid
The Electronic Structure of I($- Trigonal-Monopyramidal M”’ ComSubstrates on the Cluster Size (C)
plexes of the Type[M(N,N)](M = Ti, V,
1062
C,H,),Co,]: Comment on the Existence
Cr, Mn. Fe; N,N = I(tBuMe,Si)of a Complex with an Unsupported Co- Electron Deficient Boron and Carbon
NCH,CH,],N) (C) <SO1
Co Double Bond (C) 471
Clusters (B) 660
- The Reaction of Unactivated Cobalt
- Empty
Octahedral Hexazirconium
[V(SNC&),I
and [V(SNH,C,%)ZPowder with lodophosphoranes. The
(SNHC,H,)]-,
Homoleptic VanadiClusters with Onlv Ten Electrons.
Synthesis of [Co(PMe,),I,] and the Isoum(irr) Complexes with Sulfur-Nitrogen
[Zr,X,,(PRd,I ( C ) iO50
lation of the “Frozen Transition-State”
Donor Ligands, and [V(SNC,H,),]-,
- Idealized Pentagonal-Planar CoordinaComplex [(nBu,PI),(p-I)][(nBu,PI)the First Thiolatovanadium(r1) Complex
tion
for
Indium
in
[(p5-Inb
(C) 1366
(p-I)C013] (C) 919
Wn(CO),J ,I2- (C) 350
-
-
-
-
-
-
-
-
-
-
-
,-
-
-
-
’’
-
-
-
1676
Angrn. Chem. I n l . Ed. EngI. 1992, 3i3N o . 12
- Stable Intermediates in the Addition
and Elimination of SnBuC1, at Molybdenum Centers by Cleavage or Formation of an Sn-CI Bond: Crystal Structure
of
[Mo(CO),(PCy3)(p-C1)(pS,CPCy,)(BuSnCI,)] CH,CI, (C) 76
- Synthesis of Cubane-like and Double
Cubane-like Tungsten-Copper-Sulfur
Clusters from the “Butterfly” Cluster
[Cu,S,W(O)(PPh,),] (C) 1085
- The Reaction of [CplNb,(B,H,),]
(Cp’ = rpEtMe,C,) with Sulfur: Stabilization of the Tetrathioborato Ligand
in Novel Sulfido Niobium Clusters (C)
1021
- [V(SNC,Htj),I
and [V(SNH2C,H4)?(SNHC,H,j] , Homoleptic Vanadium(n1) Complexes with Sulfur-Nitrogen
Donor Ligands, and [V(SNC,H,),]-,
the First Thiolatovanadium(r1) Complex
(C) 1366
Concave reagents
- Concave Wrapped Protons: Reagents
- Catecholates as 0-and x-Donating Ligands: The Synthesis and Structure
for Contra-Thermodynamic Protonations (C) 80
of(Et,N),[W(CO),(0,C6H4)] and the
“Sixteen Electron” Analogue Resulting
Con formation
- A Binary Quinone Receptor (C) 792
from CO Dissociation (C) 1503
- Distortional Isomerism in Oxomolybde- Calculation of Molecular Dynamics for
Peptides in Dimethyl Sulfoxide: Eliminum Svstems: the Evidence Re-evaluatnation of Vacuum Effects (C) 210
ed (C)’1607
- New Routes to Alkvlidvne-Bridged Di- Dynamic Forcing, a Method for Evaluating Activity and Selectivity Profiles of
tungsten Compounds .Supporied by
RGD (Arg-Gly-Asp) Peptides (C) 326
Alkoxide or Siloxide Ligands by the Ac- Flexible
Molecules with Defined
tivation of Ethylene (C) 462
- Tris(cyclopentano1ato)oxovanadiShape--Conformational
Design (R)
1124 (1657)
urn(\): a Model for the Transition State
of Enzymatic Phosphocster Cleavage - Molecular ’Modeling of the Class I Hu(C) 447
man
Histocompatibility
Molecule
HLA-A2 Presenting an Allele-Specific
Complexes with phosphorus ligands
Nonapeptide from Influenza Matrix
- Synthesis and Structure of [Ni(PtBu,)]
Protein (Cj 886
and [Ni,(PtBu),(CO),] and Calculations on the Electronic Structure of
- Pronounced Conformational Changes
in Sixfold Nitrogen-Functionalized
[Ni(PtBu),] and (PR),, R = tBu, Me (C)
Metacyclophanes: Syntheses and Crys323
tal Structures of Two 1.10-Di- The Formation of cyclo-P, Ligands with
aza[l l]metacyclophanes (C) 882
Maximum Electron Donor Ability (C)
1377
- Stereochemistry
of Organic Compounds. Principles and Applications (B)
- The Reaction of Unactivated Cobalt
1539
Powder with Iodophosphoranes. The
Conjugation
Synthesis of [Co(PMe,),I,] and the Isolation of the “Frozen Transition-State”
- Novel Cross-Conjugated Compounds
Derived from Tetraethynylethene (C)
Complex [(~BU,PI)~(~-I)][(~BU,PI)1240
(LL-IICOI,~
(CI 919
Cornp1exc;with silicon ligands
- meta-Phenylene Units as Conjugation
Barriers in Phenylenevinylene Chains
- The First Metal-Metal Silyi Migration
(C) 1653
in a Heterobimetallic Complex, and the
The First Hexabutadiynylbenzenes:
Structure of the Rearrangement Product
Synthesis and Structures (Cj 1643
[(OC),Fe(pPPh,)Pt{Si(OMe),}Coordination
(PPh3)](t.i-Pt) (C) 1583
Comolexes with sulfur ligands
Alkoxyalkyl-Substituted /3-Diketonate
Complexes of Barium and Copper: Evidence for Inter- and Intramolecular Stabilization (C) 735
BAdged &mplexes with S:-’and Do<bly End-On-Bound H,NNH, Bridging - Biocoordination Chemistry: CoordinaLigands (CJ 87
tion Equilibria in Biologically Active
- Indirect
Cd,14N Spin-Spin Coupling
Systems (B) 803
Constants as a Structural Probe of Solid
Bis(P,P-di-tert-butylphosphinic-N-isoCadmium Thiocyanate Complexes (C)
propylamidato-N,O)nickel(rl), a Para1222
magnetic Planar Complex (C) 612
- Molecular Mechanisms of the Reduc- Chelate
Complexes of Tripodal,
Aliphatic Triisocyanide Ligands (Cj
tion of NO to NH,OH at Mo-S Centers
1212
(C) 205
- [Ni,(SC,H,),Br]
and [NI,(SC,H7),I]:
- Idealized Pentagonal-Planar CoordinaMixed Valent Nickel Thiolates with Intion
for
Indium
in
[&-In)tegral and Nonintegral Metal Oxidation
(Mn(Co]41,lZ- ( c ) 350
States (C) 54
- Indirect
Cd,14N Spin-Spin Coupling
- Novel Metal Thiolates:
Constants as a Structural Probe of Solid
Cadmium Thiocyanate Complexes (C)
[Co,(SC,H,),]-,
the First Complex
with Face-Sharing MS, Tetrahedra (C)
1222
1368
- [Ni(PtBuj,]--a
Strain on the 18 Electron Rule? (H) 424
- P ridine-2-thiolato Complexes of V”,
V”. and V‘“ with Unusual Structural - Novel Metal Thiolates:
Features (C) 1253
[Co,(SC,H,)J,
the First Complex
Complexes with oxygen ligdnds
A Dramatic Difference in the Reactivities of Alkoxido- and Aryloxidorhenium
Complexes in Insertion Reactions (C)
220
- A New Type of Mn-0 Cluster with a
Mn, Chain Unit. Relevance to the Photosynthetic Oxygen Evolving Center (C)
1629
- A Phenoxy-Bridged Homodinuclear Zn
Complex with an Unusual Coordination
Sphere; Model Compound for the Active Site of Phospholipase C (C) 1647
Alkoxyalkyl-Substituted P-Diketonate
Complexes of Barium and Copper: Evidence for Inter- and Intramolecular Stabilization (C) 735
- Bismuth Alkoxide Dimer Complexes
Containing Planar Bi,(u-OR), Cores:
-
__
-
-
-
-
Angrii. ( ‘ 1 7 ~ .I i i r . Ed. Engl. 1992, 31, N o . 12
with Face-Sharing MS, Tetrahedra (C)
1368
- Phosphorus(v) Selenides with Phosphorus in a Trigonal-Planar Environment
(C) 1350
- Synthesis and Structure of AI(OAr*),
(Ar* = 2,6-tBu2-4-MeC,H,): The First
Three-Coordinate Homoleptic Aluminum Aryloxide (C) 921
- Synthesis and Structure of [Ni(PtBu,)]
and [Ni,(PtBu),(CO),] and Calculations on the Electronic Structure of
[Ni(PtBu),] and (PR),, R = tBu, Me (C)
323
- Template-Controlled Organization of a
Fluoride Surface-An Analogue of a
Crown Ether in the Reaction of [{(a5C,Me,)TiF,},] with Sodium Fluoride
(C) 864
- Tetrakis(q‘-phosphabenzene)nickel (C)
1343
- The First Metal-Metal Silyl Migration
in a Heterobimetallic Complex, and the
Structure of the Rearrangement Product
[(OC),Fe(p-PPh,)PtjSi(OMe),)(PPh,)](Fe-Pt) (C) 1583
- The Pentagonal Bipyramid as Fundamental Structure for Compounds with
the Coordination Number Seven* (C)
1036
- The Structure of Pentamethyltantalum
(C) 1462
- The Structures of Pentamethyltantalum
and -Antimony: One Square Pyramid
and One Trigonal Bipyramid C 1464
- Trigonal-Monopyramidal M”’ ) Complexes of the Type[M(N,N)](M = Ti, V,
Cr, Mn, Fe; N,N = [(tBuMe,Si)NCH,CH,],N) (Cj 1501
- Yriphosphatrisilacyclohexanes as Tridentate Coronands in Cr and Mo Complexes: Activation of Si-H in an Early
Stage versus Phosphane Coordination
(C) 1510
- Unusual
Coordination of the 1,3Diphosphacyclobutadiene Derivative
(iPr,NCP), to Two [Ni(CO),] Fragments (C) 95
Copper compounds
- One-Dimensional M”’Cu’’ Compounds
with an Unprecedented, Tubelike Structural Motif(M = Rare-Earth Metal) (C)
626
- Self-Assembly of a Cu, Complex with
Coplanar Copper(1) Ions: Synthesis,
Structure. and Electrochemical Prooerties (c) 733
- Stereoselective Nucleophilic Addition
Reactions of Reactive Pseudopeptides
(C) 1626
- ‘Bis(oxazo1ines)’ as Ligands for SelfAssembling Chiral Coordination Polymers-Structure of a Copper(1) Catalyst
for the Enantioselective Cyclopropanation of Olefins (C) 430
Corannulene
- Corannulene Tetraanion: A Novel Species with Concentric Anionic Rings (C)
1636
Corrigenda 1540, 1657
- On the Reaction of Pentamethylcyclopentadiene with Cobalt Atoms: A
Reexamination 1392
Corynanthe alkaloids
A Short Diastereoselective Entry to Indole Alkaloids of the Corynanthe Type
by the Intramolecular Ene Reaction (C)
1079
Criss-cross reaction
- An Organometallic Analogue of the
“Criss-Cross” Cycloaddition Reaction
(C) 1053
-
1677
Crown ethers
C,, and C,, in a Basket?-Investigations of Mono- and Multilayers from
Azacrown Compounds and Fullerenes
(C) 1599
- [SbCl([IS]Cro~n-5)](SbCl~)~
and [BiCI([l 8]Crown-6)(CH3CN),](SbCI,), :
Salts with Antimony(rr1) and
Bismuth(m) Dications (C) 334
Cryptands
- One-Pot Syntheses of Novel Arene Tricarbonyl Chromium Macrocycles and
Macrobicycle: Structure of a Pentanuclear Trichromium(0)-Dicopper(r)
Cryptate (C) 775
- Transition Metal in a CubeA Discrete Eight-Coordinate
[Mn2+c [2.2.2]cryptand] as a BodyCentered Cube with an N 2 0 6Donor Set
(C) 764
Crystal growth
- Control and Design Principles in Biological Mineralization (R) 153
Crystallization
The Science of Crystallization. Microscopic Interfacial Phenomena (B) 1536
Crystallography
- Optically Anomalous Crystals (R) 1
- Two-Dimensional Crystallography of
Amphiphilic Molecules at the AirWater Interface (R) 130
Cubanes
- A New, High-Yield Synthesis of Tetraphosphacubanes (C) 758
- [ c p * C r ( ~ ~ - H ) ] ~ -Paramagnetic
a
Chromium Hydride with a Cubane
Structure (C) 1077
- Cubanes: Starting Materials for the
Chemistry of the 1990s and the New
Century (R) 1421
- Octakisf 1,I ,2-trimethylpropyl)octasilacubane: Synthesis, Molecular Structure,
and Unusual Properties (C) 1354
- P-Functionalization of the Tetraphosphacubane System (C) 879
- Synthesis of Cubane-like and Double
Cubane-like Tungsten-Copper-Sulfur
Clusters from the “Butterfly” Cluster
[Cu,S,W(O)(PPh,),I (C) 1085
- The [ ( P ~ - W S ~ , ) , ( P , - ~ ~ ) , ( C U ,An),~~ion, an Inorganic Cluster with a Pinwheel Shape (C) 1477
Cumulenes
- Butatrienes by Desulfurization of Cyclic
Trithiocarbonates (C) 1611
Cyanamide
- Biochemical Degradation of Cyanamide
and Dicyandiamide (C) 620
Cyclic voltammetry
- Electrochemical Oxidation
of 1-@Dimethylaminopheayl)-3,3-dimethyltriazene-Cyclic Voltammetric Detection
of a Triazene Radical Cation and Dication (C) 332
Cyclizations
- Cascade Cyclizations (H) 1332
- Efficient Synthesis of Nanoscale Macrocyclic Hydrocarbons (C) 922
- Inhibition of the [2+2+2] Cyclization
by the Formation of Chelates: Alkyne
and Vinylidene Complexes with Cyclopentadienylcobalt(t) (C) 1066
- Stereocontrolled
Construction
of
6 . 5 . 6 and 5 . S . 6 Ring Systems by
Radical Tandem Cyclization (C) 910
Cycloaddi tions
- A New Reaction Type in the Conversion
of Enamines with 1,4-Diphenyl-2butene-1,4-dione to Give Cage Compounds (C) 768
- A New Synthesis for Imidazolo- and
Pyrrolophanes by [3 + 21 Cycloaddition
with Azaallenyl Radical Cations (C) 209
-
-
1678
An Organometallic Analogue of the
“Criss-Cross” Cycloaddition Reaction
(C) 1053
- Cycloaddition Reactions in Organic
Synthesis (B) 240
- Enantioselective Syntheses of Cyclopentanoid Compounds from Isoprene and
trans-1.3-Pentadiene (C) 305
- The Benzene Ring as Dienophile in an
Intramolecular [4+ 21 Cycloaddition:
Degenerate Rearrangement of 7,8-Benzobicyclo[4.2.2]deca-2,4,7,9-tetraene
(C)
872
- Transition Structures of Hydrocarbon
Pericyclic Reactions (R) 682
- Two Stereoisomeric [4.5.5.5]Fenestranes
Formed by Intramolecular [2 +2] Cycloaddition (C) 344
- [4 + 4]-Cycloaddition Reactions in the
Total Synthesis of Naturally Occurring
Eight-Membered Ring Compounds (H)
422
Cycloalkadi ynes
- Cycloalkadiynes-From
Bent Triple
Bonds to Strained Cage Compounds (R)
27
Cycloalkynols
- Anti-Bredt Enol Ethers by Transannukar
Cyclization of Cycloalkynols (C) 791
Cyclobutadienes
- How High is the Barrier for the Valence
Isomerization of Cyclobutadiene? (C)
738
Cyclobutanes
- Quest for Higher Ladderanes: Oligomerization of a Cyclobutadiene Derivative (C) 1488
Cyclobutarenes
- Cyclobutarenes. The Chemistry of Benzocyclobutene, Biphenylene, and Related ComDounds (B)
~, 1264
Cyclodexths
- Cvclodextrin Derivatives as Chiral Selectors-Investigation of the Interaction
with (R,S)-Methyl-2-chloropropionate
by Enantioselective Gas Chromatography, NMR Spectroscopy, and Molecular Dynamics Simulation ( c ) 319
- Cyclodextrins, Off-the-shelf Components for the Construction of Mechanically Interlocked Molecular Systems (H)
846
- Selective Binding of Sugar to p-Cyclodextrin: A Prototype for Sugar-Sugar
Interactions in Water (C) 745
- Synthesis and Complexation Properties
of a Cyclodextrin-Derived Siderophore
Analogue (C) 1381
- Synthesis of a Lipophilic Cyclodextrin[2]-Rotaxane (C) 783
- Threading Cyclodextrin Rings on Polymer Chains (C) 197
Cyclohexadienes
- Diastereoselective Synthesis of Substituted Cyclohexadienes from Enantiomerically Pure Tricarbonyl(2-phenyl4,5-dihydrooxazole)chromium Complexes (C) 1071
Cyclohexanones
- Effect of Torsional Strain and Electrostatic Interactions on the Stereochemistry of Nucleophilic Additions to Cyclohexanone and Related Systems (C)
1019
Cyclohexatrienes
- 1.2,4-Cyclohexatriene, an Isobenzene,
and Bicyclo[4.4.0]deca-l,3,5,7,8-pentaene, an Isonaphthalene: Generation and
Trapping Reactions (C) 473
- 1.2,4-Cyclohexatriene, an Isobenzene,
and its [2 + 21 Cycloaddition with
Styrene: A Theoretical Study (C)
476
-
Cyclopentanes
- Enantioselective Syntheses of Cyclopentanoid Compounds from Isoprene and
rrans-1,3-Pentadiene (C) 305
Cyclophanes
- A Donor Cage with Two Tetrathiafulvene Units (C) 309
- A New Synthesis for Imidazolo- and
Pyrrolophanes by [ 3 21 Cycloaddition
with Azaallenyl Radical Cations (C)
209
- Pronounced Conformational Changes
in Sixfold Nitrogen-Functionalized
Metacyclophanes: Syntheses and Crystal Structures of Two 1,IO-Diaza[l l]metacyclophanes (C) 882
- Selective Ketone Pyrolysis: New Synthetic Method for Mono- and Polycyclic
Hydrocarbons (C) 307
- Strain-Activated Formation of a TripleLayered Phane (C) 1073
Cyclopropanation
- ‘Bis(oxazo1ines)’ as Ligands for SelfAssembling Chiral Coordination Polymers-Structure of a Copper([) Catalyst
for the Enantioselective Cyclopropanation of Olefins (C) 430
a-Cyclopropyl esters
Nucleophilic Attack at the Central Carbon Atom of (x-Ally1)palladium Complexes: Formation of x-Cyclopropyl Esters (C) 234
Cytochromes
Cytochromes C. Evolutionary, Structural and Physicochemical Aspects (B)
1098
+
-
-
D-arnino acids
Proteins from the D-Chiral World (H)
1457
Dendrimers
- Arborols Based on Luminescent and
Redox-Active Tranvition Metal Complexes (C) 1493
- Dendrimers, Arborols, and Cascade
Molecules: Breakthrough into Generations of New Materials (H) 1571
- Novel Polyether Copolymers Consisting
of Linear and Dendritic Blocks (C) 1200
- One-Pot
Multifunctionalization
of
Polymethyl Hydrocarbon x Ligands.
Maximum Space Occupancy by Double
Branching and Formation of Arboroles
(C) 458
- Supramolecular Self-Assemblies of
Two-Directional Cascade Molecules:
Automorphogenesis (C) 917
Deprotonations
- Asymmetric Deprotonation as an Effcient Enantioselective Preparation of
Functionalized Secondary Alcohols (H)
1459
- Stereoselective Generation of 1-Acyloxy-2-amino Carbanions by Deprotonation; Synthesis of Enantiomerically
and Diastereomerically Pure /I-Amino
Alcohols (C) 1SO5
Desulfurations
- Butatrienes by Desulfurization of Cyclic
Trithiocarbonates (C) 1611
Deterministic chaos
- Chaotic Evolution and Strange Attractors (B) 798
Dewar benzenes
- Doubly Bridged Prismane and Dewar
Benzene Intermediates in an Unusual
Photochemical Rearrangement of Tricyclic Phthalic Esters (C) 862
- Spirocyclization of a Stable Phosphaalkyne with Aluminum Trichloride-Key Reaction for the Production of
Triphospha Dewar Benzene Derivatives
(C) 1055
-
Anyiw. Chcwn. Inf. Ed. Engl. 1992, 31, N o . 12
Diamond structures
Electron Localization in Solid-state
Structures of the Elements: the Diamond Structure (C) 187
Diazonium ions
- Origin of the Stabilization of Vinyldiazonium Ions by 8-Substitution; First
Crystal Structure of an Aliphatic Diazonium Ion: 8,P-Diethoxyethenediazonium Hexachloroantimonate (C) 740
Dibenzopyrans
Palladium-Catalyzed C-H Activation of
Methoxy Groups: A Facile Synthesis of
Substituted 6H-Dibenzo[h,d]pyrans (C)
1023
Dictionary
- Dictionary of Plants Containing Secondary Metabolites (B) 1396
Diels-Alder reactions
- A Diels-Alder Route to [5]- and [6]-Helicenes (C) 1093
- Diacetoneglucose as Auxiliary Group
for the Asymmetric Hetero-Diels-Alder
Reaction with Nitrosoalkenes (C) 1033
Dienes in the Diels-Alder Reaction (B)
364
Diisocyanogen
- Matrix Isolation of Diisocyanogen CNNC (C) 1218
Di ketones
A New Reaction Type in the Conversion
of Enamines with 1,4-Diphenyl-2butene-I ,4-dione to Give Cage Compounds (C) 768
Dioxinones
- Synthesis of (R)and (S)-2-tert-Butyl-6trifl uoromethyl- 1,3-dioxin-4-ones,
Transformations into 3-Hydroxy-3-(trifluoromethyl)alkanoates, and Surprising Differences in the Reactivity of
CH,- and CF,-Substituted Compounds
(C) 1083
Dioxins
- The Beilstein Test: An Unintentional
Dioxin Source in Analytical and Research Laboratories (C) 443
Diphosphacyclobutadienes
- Unusual
Coordination of the 1,3Diphosphacyclobutadiene Derivative
(iPr,NCP), to Two [Ni(CO),] Fragments (C) 95
Distorted molecules
- Distorted Molecules: Perturbation Design, Preparation and Structures (R) 550
Diynes
- Cycloa1kadiynes~-From
Bent Triple
Bonds to Strained Cage Compounds (R)
27
- Stereocontrolled
Construction
of
6 - 5 . 6 and 5 . 5 . 6 Ring Systems by
Radical Tandem Cyclization (C) 910
DNA
- A Milestone in Genome Sequencing:
The Complete DNA Sequence of the
Yeast Chromosome 111 (H) 1578
- DNA Recognition by Hybrid Oligoether-Oligodeoxynucleotide Macrocycles (C) 1617
- Interactions Between Acyclic and Cyclic
Peralkylammonium Compounds and
DNA (C) 1207
DNA cleavage
- [RuO(dppz)(tpy)J’+: a DNA Cleavage
Agent with High DNA Affinity (C) 1048
Doppler spectroscopy
- Reaction
Dynamics
of Aligned
Molecules (R) 526
Doppler-free spectroscopy
- High Resolution Spectroscopy below
the Doppler Width (R) 263
Dyes
- New Thermo-Response Dyes: Coloration by the Claisen Rearrangement
-
-
-
-
Angru C l m ? Int Ed EngI 1992. 31, No 12
and Intramolecular Acid-Base Reaction
(C) 204
Photoswitchable Association of an Azobenzene-Biwridinium Diad to Eosin :
Photostimdated “On-Off’ Guest Binding (C) 1243
[Ni(PtBu),] and (PR),, R = tBu, Me (C)
323
Enamines
- A New Reaction Type in the Conversion
of Enamines with 1,4-Diphenyl-2butene-1,4-dione to Give Cage Compounds (C) 768
Enantiomeric resolution
Eco1ogy
Metals and Their Comoounds in the En- - Salting Out Selective Extraction-A
vironment: Occurrence, Analysis and
Novel Method for the Optical Resolution of Chiral Sulfinylcarboxylic Acids
Biological Relevance (B) 102
- Sulfur Analogues of Polycyclic Aromatand Its Application for the Convenient
ic Hydrocarbons (Thiaarenes). EnvironDetermination of Optical Purity (C) 1631
mental Occurrence, Chemical and Bio- Ene reactions
logical Properties (B) 364
- A Short Diastereoselective Entry to In- The Beilstein Test: An Unintentional
dole Alkaloids of the Corynanthe Type
Dioxin Source in Analytical and Reby the Intramolecular Ene Reaction (C)
search Laboratories (C) 443
1079
- Transport and Fate of Organic ComEnediynes
pounds in the Global Environment (R) - Synthesis of the Calicheamicin Aryl487
tetrasaccharide Domain Bearing a ReEdshammar polyhedra
ducing Terminus: Coupling of Fully
Generalized Edshammar Polyhedra for
Synthetic Aglycone and Carbohydrate
the Description of a Family of SolidDomains by the Schmidt Reaction (C)
State Structures (C) 924
338
Eicosanoids
- Ten-Membered Ring Enediynes with
- Pheromones of Marine Brown Algae; A
Remarkable Chemical and Biological
New Branch of the Eicosanoid
Profiles (C) 1044
Metabolism (C) 1246
- Total
Synthesis of Calicheamicin Electrochemistry
Dynemicin Hybrid Molecules (C) 340
Molecular Switching by Electron Trans- - Total Synthesis of the Carbohydrate
fer-the
Spiroperimidine/Quinonimine
Fragments of Esperamicin A, (C) 855
System (C) 1498
Enol ethers
- Organic Electrochemistry. An Introduc- Anti-Bredt Enol Ethers by Transannular
tion and a Guide (B) 656
Cyclization of Cycloalkynols (C) 791
- The
Electrochemical Oxidation of - Semiconductor-Catalyzed Photoaddi[Co”(salen)] in Solvent Mixtures-An
tion of Cyclic Enol Ethers to 1,2-DiExample of a Ladder Scheme with
azenes (C) 1039
Coupled Electron-Transfer and Solvent- Enols
Exchange Reactions (C) 1215
- The Chemistry of Enols (B) 105
Electron localization
Enterobactin
Electron Localization in Solid-State
- The First Structural Characterization of
Structures of the Elements: the Diaa Metal-Enterobactin Complex:
mond Structure (C) 187
[V(enterobactin)]’ (C) 466
- On the Bonding in Carbosilanes (C)
Enzymatic catalysis
185
- “Artificial Metabolisms” for the AsymElectron microscopy
metric One-Pot Synthesis of Branched- Microscopy (B) 1534
Chain Saccharides (C) 614
Electron transfer
- Chain Elongation of Thiodipeptides
- A Homologous Series of Stable Polywith Proteases (C) 1229
enes: Synthesis, Structure, and Redox - Chemoenzymatic Syntheses of the OptiBehavior (C) 1588
cally Active Hydroperoxides of Phos- [(CO),(PPh,),OsAg(O,CCF,)I:
A
phatidylglycerol and PhosphatidylModel for an Intermediate on the Reacethanolamine with Lipase, Lipoxygention Coordinate in Electron Transfer (C)
ase, and Phospholipase D (C) 1336
770
- Enzymatic Oxidation of Methyl Groups
- Molecular Switching by Electron Transon Aromatic Heterocycles: A Versatile
Spiroperimidine/Quinonimine
fer-the
Method for the Preparation of HetSystem (C) 1498
eroaromatic Carboxylic Acids (C) 774
Three-Dimensional Structure of an Un- - Enzymatic Preparation of Enantiomerisymmetrical Proton-Electron Transfer
cally Pure N-alkyl Amino Acids (C) 195
System Containing a Disulfide Bond: - Radical Intermediates in the Coenzyme
The Bis(4-hydroxyphenyl)disulfideB,, Dependent Methylmalonyl-CoA
Benzoquinone Complex (C) 852
Mutase Reaction Shown by ESR SpecElectronic structure
troscopy (C) 215
- A New Structure-Magnetism RelationEnzyme models
ship for Face-Sharing Transition-Metal - A Rh’-Centered Cage Compound with
Complexes with d3-d3 Electronic ConSelective Catalytic Properties (C) 905
figuration (C) 311
Enzymes
- A Paramagnetic, Mononuclear
Multifield Saturation Magnetization
Organometallic Iridium(I1) Complex:
Measurements of Oxidized and Re[Ir(C6Cl,),(cod)] (C) 1527
duced Ribonucleotide Reductase from
- Empty
Octahedral
Hexazirconium
Escherichia coli (C) 151 3
Clusters with Onlv Ten Electrons.
- Proteins from the D-Chiral World (H)
3 457
[Zr6X14(PR3)41(C)
[Ni(PtBu),]-a
Strain on the 18 Elec- - Selective Inhibition of Trypanosomal
tron Rule? (H) 424
Triosephosphate Isomerase by a Thio- Oligo(9,I 0-anthrylenes), Organic Compeptide (C) 328
pounds with Stable High-Spin States (C) Epoxides
448
- meso Epoxides in Asymmetric Synthe- Synthesis and Structure of [Ni(PtBu,)]
sis: Enantioselective Opening by
and [Ni,(PtBu),(CO),] and CalculaNucleophiles in the Presence of Chiral
tions on the Electronic Structure of
Lewis Acids (H) 1179
-
-
-
-
~
-
-
loso
1679
Esperamicins
Total Svnthesis of the Carbohvdrate
Fragments of Esperamicin A , (Cj 855
ESR spectroscopy
- Electrochemical Oxidation
of I-@Dimethylaminophenyl)-3,3-dimethyltriazene-Cyclic Voltammetric Detection
of a Triazene Radical Cation and Dication (C) 332
- Modern Pulsed and Continuous-Wave
Electron Spin Resonance (B) 243
- Radical Intermediates in the Coenzyme
B,, Dependent Methylmalonyl-CoA
Mutase Reaction Shown by ESR Spectroscopy (C) 215
- Stable N,N-Di-tevt-butyl-metaphenylenebisni troxides-Unexpected
Ground-State Singlets (C) 180
Estradiol
- Estradiols Modified by Metal Carbonyl
Clusters as Suicide Substrates for the
Study of Receptor Proteins: Application to the Estradiol Receptor (C) 753
Evolution
- Chemical Evolution. Origin of the Elements, Molecules and Living Systems
(B) 1533
-
Felkin-Anh model
Effect of Torsional Strain and Electrostatic Interactions on the Stereochemistry of Nucleophilic Additions to Cyclohexanone and Related Systems (C)
1019
Fenestranes
- Two Stereoisomeric 14.5.5.51Fenestranes
Formed by Intramofecular (2 + 21 Cycloaddition (C) 344
Field-effect transistors
- Field-Effect Transistors as Sensors of
Neural Svstems (H) 45
Fischer, Emil
- Emil Fischer’s Proof of the Confieuration of Sugars: A Centennial Tribuc (R)
1541
Fluorescence
- Dual Fluorescence of Novel Modified
Carotenoids ~, 1042
Fluorides
- A Safe Svnthesis of Dbhosuhazenium
Salts (C) 350
- Template-Controlled Organization of a
Fluoride Surface-An Analogue of a
Crown Ether in the Reaction of [ { ( q 5 C,Me,)TiF,],] with Sodium Fluoride
(C) 864
- The Pentagonal Bipyramid as Fundamental Structure for Compounds with
the Coordination Number Seven* (C)
1036
Fluorine compounds
- Catalytic Oxidation of Partially and
Fully Fluorinated Olefins with Osmium
Tetroxide (C) 1345
- Does the Naked Fluoride Ion Exist‘! (H)
292
- Perfluorotriethylamine: An Amine with
Unusual Structure and Reactivity (C)
1467
- Structure of the Lowest Temperature
Phase of the Solid Benzene-Hexafluorobenzene Adduct (C) 1655
The Structure and Stability Trends of
Fluoro(methy1)plumbanes (C) 1224
Fractals
- Elementary Introduction to Spatial and
Temporal Fractals (B) 659
Friedel-Crafts reactions
Cyclohexadienyl-Type Cationic Intermediates in the Friedel-Crafts Alkylation of Benzene Derivatives with the 9Fluorenyl Cation-Observation
by
Laser Flash Photolysis (C) 743
-
\
I
I
-
-
1680
.
Rate Constants for the Attack of Carbenium Ions at Arenes-A Link between
the Chemistry of Aliphatic and Aromatic x Systems (C) 1613
Fruit ripening
- Inhibition of Fruit Ripening by Antisense-RNA Technology (H) 175
Fullerenes
- A New Fullerene Synthesis (C) 223
- C,, and C,, in a Basket?--1nvestigations of Mono- and Multilayers from
Azacrown Compounds and Fullerenes
(C) 1599
- C,,: Buckminsterfullerene. The Celestial Sphere that Fell to Earth (R) 111
- C,,-Fullerene-~A
Playground
for
Chemical Manipulations on Curved
Surfaces and in Cavities (H) 293
- Fullerene Sugars: Preparation of Enantiomerically Pure, Spiro-Linked C-Glycosides of C,, (C) 1388
- Material Properties and Purity of C 6 ,
(C) 868
- Optimization of the Production and
Separation of Fullerenes (C) 1640
- Preparative-Scale Separation of C,, and
C,, on Polystyrene Gel (C) 644
- Product Predictions for Nucleophilic
Additions to C,, (C) 1468
- Reaction of C,, with Dimethyldioxirane--Formation of an Epoxide and a
1,3-Dioxolane Derivative (C) 351
- Se uential Insertion of 3He and ,He in
C,,9 (C) 605
- Si,,, an Analogue of C,,? (H) 173
- Structure of a Product of Double
-
Synthetic Approaches toward Molecular and Polvmeric Carbon Allotrooes
(R) 1101
- The Euidemic Suread of Fullerene Research’(C) 588 (i540)
- The Neutralization of HeC,;
in the Gas
Phase: Compelling Evidence for the Existence of an Endohedral Structure for
He (dC,, (C) 183
- The Stability of Buckminsterfullerene
(C,,): Experimental Determination of
the Heat of Formation (C) 63
- The Structure of C,,: Orientational Disorder in the Low-TemDerature Modification of C,, (C) 640
- Titration ofC,,: A Method for the Synthesis of Organofullerenes (C) 766
Fulvalenes
- A Donor Cage with Two Tetrathiaful309
vene Units
- Double Open-Edged P,, Dihydrofulvalene as a 16-Electron Donor Ligdnd (C)
1027
- Tetraphosphafulvalene Dianions:
Isoelectronic Species of Tetrathiafulvalene Dications (C) 1031
-
(6
GABA, receptor
- Synthesis of (2-Arylindol-3-yl)acetamides as Probes of Mitochondria1
Steroidogenesis-A
New Mechanism
for GABA, Receptor Modulation (C)
1060
Gadolinium compounds
- Synthesis and Structure of the First
Trinuclear. Half-Sandwich Carboranegadohium(ri1) Cluster ( C ) 432
GALLEX
- The Chemistrv of GALLEX-Measurement of Sola; Neutrinos with a Radiochemical Gallium Detector (R) 1283
Gallium compounds
- (Ga(C,H,)]: Synthesis, Identification,
and Ab Initio Investigations (C) 1362
[Ga,{C(SiMe,),),] with a Tetrahedral
Ga, Skeleton (C) 1364
- The Chemistry of GALLEX-Measurement of Solar Neutrinos with a Radiochemical Gallium Detector (R) 1283
Garlic
The Organosulfur Chemistry of the
Genus ANium-Implications for the Organic Chemistry of Sulfur (R) 1135
Gas-phase reactions
- Gas-Phase
Reactions of M + and
[CpM]’ (M = Fe, Co, Ni) with 1,3,5Trisilacyclohexane: First Evidence for
the Formation of 1,3,5-Trisilabenzene
(C) 1633
- Observation and Properties of a Hydrogen Bond to Carbon in a Short-Lived,
Gas-Phase Complex of Methyl Isocyanide and Hydrogen Fluoride (C) 202
- The Pyrolysis of Tetranitromethane in
the Gas Phase (C) 900
Gene technology
- Inhibition of Fruit Ripening by Antisense-RNA Technology (H) 175
- Protein Engineering: Modified
Hemoglobin as a Blood Substitute (H)
848
Genome sequencing
A Milestone in Genome Sequencing:
The Complete DNA Sequence of the
Yeast Chromosome I11 (H) 1578
Germanium compounds
- A Germanium Sesquisulfide,
(tBuGe),S,. without Adamantane
Structure (C) 59
- Ag,GeO,, a New Semiconducting Oxide (C) 653
- Stable Cyclic Germanediyls (“Cyclogermylenes”): Synthesis, Structure,
Metal Complexes, and Thermolyses (C)
1485
Glycopeptides
- A New Strateev for Solid-Phase Svnthe‘
sis of 0-GlycGeptides (C) 857
- Synthesis of C-Glycopeptides via Free
Radical Addition of Glycosyl Bromides
to Dehydroalanine Derivatives (C) 902
Glycosides
- Fullerene Sugars: Preparation of Enantiomerically Pure, Spiro-Linked C-Glycosides of C,, (C) 1388
Gold compounds
- Molecular Machines: Molecular Structure of [(p-Tol,P),,Au, ,Ag,,CI8](PF,)-,-a Cluster with a Biicosahedral
Rotorhke Metal Core and an Unusual
Arrangement of Bridging Ligands (C)
445
- [(Ph,PAu),Mn(CO),]+, a Cluster with
Pentagonal-Bipyramidal Structure (C)
464
- Synthesis and Structure of the Cluster
[NaAu,,Se8l3- : An Inorganic Cryptand Complex (C) 787
Grignard reactions
- Enantiomerically Pure Tertiary Alcohols by TADDOL-Assisted Additions
to Ketones-or How to Make a Grignard Reagent Enantioselective (C) 84
- Ligdnd Effects in Grignard Additions
(C) 342
-
-
-
Halogen compounds
Alkynyl- and Alkenyl(pheny1)iodonium
Compounds (R) 274
- Azidoiodoiodine(1 +) Hexafluoroantimonate: The First Binary NitrogenIodine Cation (C) 1338
- Does the Naked Fluoride Ion Exist? (H)
292
Helicenes
- A Diels-Alder Route to (51-and [6]-Helicenes (C) 1093
-
Angen. Cliem. Innt. Ed. Engl. 1992. 31. No. 12
- New Impetus for Inorganic Host-Guest
zlices
Chemistry (H) 11 85
An Unusual Interplay Between Macromolecular and Supramolecular Helicity - (0rganoarsonato)polyoxovanadium
Clusters: Pronerties and Structures of
in Polyisocyanates Dissolved in a Chiral
the V" Cluster [V,,024~0,AsC6H4-4Liquid Crystal (C) 88
NH ),I4and the V' 4V" Cluster
Supramolecular Self-Assemblies of
Two-Directional Cascade Molecules:
[ H ~ ~ V V ~ ~ , , ( ~ , A S C , H S )( ,c})I1197
Hexabutadi ynylbenzenes
Automorphogenesis (C) 917
The First Self-Assembled Dinuclear - The FirsCHkxabutadiynylbenzenes:
Synthesis and Structures (C) 1643
Triple-Helical Lanthanide Complex:
High-pressure liquid chromatography
Synthesis and Structure (C) 1622
- Detection of Subpicomole Levels of
Helium compounds
Compounds Containing Hydroxyl and
- The Neutralization of HeC,;
in the Gas
Amino Groups with the Fluorogenic
Phase: Compelling Evidence for the ExReagent, 2-Naphthoylimidazole (C) 890
istence of an Endohedral Structure for
Histocompatibility molecule
Hew C,, (C) 183
- Molecular Modeling of the Class I HuHcptatriene
man
Histocompatibility
Molecule
- Investigation of the [1,7] Sigmatropic
HLA-A2 Presenting an Allele-Specific
Hydrogen Shift in a Parent Compound
Nonapeptide from Influenza Matrix
Z,Z-l,3,5-Heptatriene and Its MonoProtein (C) 886
deuterium Analogue (C) 781
History of chemistry
Heteroarenes
- Aromatic
Boron Heterocycles: The - August Wilhelm Hofmann-"Reigning
Chemist-in-Chief' (R) 1265
Generation of 1 H-Borepin and the
Structure of Tricarbonyl(1-phenylbor- - Ce0: Buckminsterfullerene, The Celestial Sphere that Fell to Earth (R) 111
epin)molybdenum (C) 1255
- Chemical Evolution. Origin of the Ele- Diprotonated Tetra(2-pyridy1)pyrazine
ments. Molecules and Living Systems
and its Chemical Mimesis due to Differ(€3)1533
ent Hydrogen Bridges (C) 299
Contrasts in Scientific Style. Research
- Enzymatic Oxidation of Methyl Groups
Groups in the Chemical and Biochemion Aromatic Heterocycles: A Versatile
cal Sciences (B) 103
Method for the Preparation of Het- Emil Fischer's Proof of the Configuraeroaromatic Carboxylic Acids (C) 774
tion of Sugars: A Centennial Tribute (R)
- Gas-Phase Reactions
of M t and
3541
[CpM]+ (M = Fe, Co, Ni) with 1,3,5My 132 Semesters of Chemistry Studies.
Trisilacyclohexane: First Evidence for
Vladimir Prelog (B) 1395
the Formation of 1,3,5-Trisilabenzene
Optically Anomalous Crystals (R) 1
(C) 1633
- Physical Chemistry from Ostwald to
- Homodiboriranides: The Simplest NegPauling. The Making of a Science in
atively Charged Homoaromatic ComAmerica (B) 797
pounds (C) 1238
Sulfur Analogues of Polycyclic Aromat- - The Green Flame: Surviving Government Secrecy (B) 1096
ic Hydrocarbons (Thiaarenes). Environmental Occurrence, Chemical and Bio- - The Kaiser's Chemists. Science and
Modernization in Imperial Germany (B)
logical Properties (B) 364
803
Tetrathienylethylenes, a New Class of
- The World of Peptides. A Brief History
Electron Donors-Dications Twisted by
of Peptide Chemistry (B) 1535
YO" Stabilized by Formation of PolyHofmann. August Wilhelm von
methinc Units (C) 455
- August' Wilgelm Hofmann-"Reigning
Heterocyclcs
Chemist-in-Chief' (R) 1265
A New Synthesis for Imidazolo- and
Hole burning
Pyrrolophanes by [3 + 21 Cycloaddition
with Azaallenyl Radical Cations (C) 209 - Spectral Hole Burning at Room Temperature and with a Single Molecule:
- Benzo-I ,2,3-triselenolium
TrifluoroTwo New Perspectives (H) 426
methanesulfonate--a
C,Se, Radical
Cationic Salt with Unusual Solid-state Homoallylic alcohols
- Diastereoselective Addition of AllylsiStructure (C) 779
lanes to Aldehydes: Synthesis of Enan- Bis(trisy1)oxadiborirane (C) 1040+
tiomerically Pure Homoallylic Alcohols
- Gas-Phase Reactions
of M
and
(C) 1372
[CpM]' (M = Fe, Co, Ni) with 1,3,5Trisilacyclohexane: First Evidence for Hormones
the Formation of 1.3,5-Trisilabenzene - Estradiols Modified by Metal Carbonyl
Clusters as Suicide Substrates for the
(C) 1633
Study of Receptor Proteins: Applica- Spirocyclization of a Stable Phosphation to the Estradiol Receptor (C) 753
alkyne with Aluminum Trichloride-Host-guest chemistry
Key Reaction for the Production of
- A Binary Quinone Receptor (C) 792
Triphospha Dewar Benzene Derivatives
- A Nonaromatic Expanded Porphyrin
(C) 1055
Derived from Anthracene-A Macro- Synthesis. Structure, and Thermolysis of
cycle which Unexpectedly Binds Anions
an Unusual Azaphosphasiliridine (C) 751
(C) 452
- The First Stibepine: Synthesis and
- A Novel Host/Guest System with a
Structure of Sb-Chlorobenzo[dJstibNanometer Large Cavitv for Anions
epine (C) 1642
- Triphosphatrisilacyclohexanes as Tridentate Coronands in Cr and Mo Complexes: Activation of Si-H in an Early Stage
versus Phosphane Coordination (C) 1510 - A ' Supramolecular Assembly of Two
Torands, Two Lithium Ions, and Three
Heteropolyanions
Water Molecules (C) 348
- A Novel Host/Guest System with a
Nanometer Large Cavity for Anions - Conformational Preference of the
Torand Ligand in Its Complexes with
and Cations: [ 2 N H l , 2C1- c
Potassium and Rubidium Picrate (C)
Vi,022(0H)4(H20),(C,H,P0,),16345
(C) 1192
-
-
-
~
-
~
AngPib Chr.m In, Ed Engl 1992. 31. N o I 2
Cyclodextrin Derivatives as Chiral Selectors-Investigation of the Interaction
with (R,S)-Methyl-2-chloropropionate
by Enantioselective Gas Chromatography, NMR Spectroscopy, and Molecular Dynamics Simulation (C) 319
- Decamethylcucurbit[S]uril (C) 1475
- Designing Synthetic Cationic Molecular
Receptors for Alcohols (C) 478
- Frontiers in Supramolecular Organic
Chemistry and Photochemistry (B)
363
- Host-Guest
Molecular Interactions.
From Chemistry to Biology (B) 1263
- Molecules with
Large Cavities in
Supramolecular Chemistry (R) 528
- Multidentate Macrocyclic Lewis Acids:
Release of '"1 21 Mercuracarborand-4"
from Its Iodide Complex and the Structure of Its Tetra(tetrahydr0furan) Dihydrate Complex (C) 893
- New Impetus for Inorganic Host-Guest
Chemistry (H) 1185
- Photoswitchable Association of an Azobenzene-Bipyridinium Diad to Eosin:
Photostimulated "On-Off' Guest Binding (C) 1243
- Svnthesis and Comulexation ProDerties
oE a Cyclodextrin-Derived Siderdphore
Analogue (C) 1381
- Threading Cyclodextrin Rings on Polymer Chains (C) 197
Houben-Weyl
- Houben-Weyl. Methoden der Organischen Chemie. Band E19c: Carbokationen, Carbokation-Radikale (B)
799
- Houben-Weyl. Methods of Organic
Chemistry. Additional and supplementary volumes to the 4th Edition. Vol. E
12 b. Organotellurium Compounds (B)
237
Hydrazines
- Semiconductor-Catalyzed Photoaddition of Cyclic Enol Ethers to 1,2-Diazenes (C) 1039
- Synthesis and Structure of a Mononuclear q2-Hydrazine Complex by Protonation of an [N,H,]'- Complex
(C) 1081
Hydride transfer
- Hydride Transfer by Hydrido Transition-Metal Complexes. Ionic Hydrogenation of Aldehydes and Ketones,
and Structural Characterization of an
Alcohol Complex (C) 1233
- Kinetics of Hydride Transfers from CH,
SiH, GeH, and SnH Groups to Carbenium Ions (C) 1046
H ydrodesulfurization
- Dimerization of Thiouhene to Give a
Linear S(CH),S
Fragment
with
[(C,Mes)Rh(C2Hd,I ( c ) 357
Hydrogen bridges
- A 1 : 3 Adduct of 2-Aminobenzothiazole
and a Urea Derivative. and Its Snatial
Arrangement (C) 1634
- A
Water-Complexed Organolithium
Compound:
[LiCH(CN), . H 2 0 . TMEDA], (C) 77
- Diprotonated Tetra(2-pyridy1)pyrazine
and its Chemical Mimesis due to Different Hydrogen Bridges (C) 299
- Dynamic Proton Exchange in the Hydrogen Dihydroxide Ion H,O; of the
Hvdroxosodalite Hvdrate
\~a4(H,0,)]2[SiA10,]6:
H MAS NMR SpectroscoDic Evidence
(C) 1210
- En Route to Synthetic Phosphodiesterases: Supramolecular PhosphorylTransfer Mediated by AmidiniumPhosphate Contact Ion-Pairs (C) 207
-
1681
Induction of Ferroelectricity in Polymeric Systems through Hydrogen Bonding (C) 1531
Intermolecular Forces. An Introduction
to Modern Methods and Results (B)
1538
Observation and Properties of a Hydrogen Bond to Carbon in a Short-Lived,
Gas-Phase Complex of Methyl Isocyanide and Hydrogen Fluoride (C) 202
Three-Dimensional Structure of an Unsymmetrical Proton-Electron Transfer
System Containing a Disulfide Bond:
The Bis(4-hydroxyphenyl)disulfideBenzoquinone Complex (C) 852
Hydrogen dihydroxide ion
- Dynamic Proton Exchange in the Hydrogen Dihydroxide Ion H,O; of the
Hydroxosodalite Hydrate
‘H MAS NMR
[Na,(H,O,)],[SiAIO,],:
Spectroscopic Evidence (C) 1210
Hydrogen shifts
- Investigation of the [1,7] Sigmatropic
Hydrogen Shift in a Parent Compound
Z,Z-1,3,5-Heptatriene and Its Monodeuterium Analogue (C) 781
Hydrogenation
- Hvdride Transfer bv Hvdrido Transitiin-Metal Complexes. ’Ionic Hydrogenation of Aldehydes and Ketones,
and Structural Characterization of an
Alcohol Complex (C) 1233
- The Hydroxyl-Directed Hydrogenation
of Vinylstannanes and Silanes: A Highly
Diastereoselective Route to B-Stannyl
and p-Silyl Alcohols (C) 232
- The Uncatalyzed Transfer Hydrogenation of %-Methylstyrene by Dihydroanthracene or Xanthene--a Radical Reaction (C) 1523
Hydroperoxides
- Chemoenzymatic Syntheses of the Optically Active Hydroperoxides of Phosphatidylglycerol and Phosphatidylethanolamine with Lipase, Lipoxygenase, and Phospholipase D (C) 1336
H ydroxyaldehydes
- 1-0-(2-Acetoxyhexadec-1-enyl)choline
Iodide, a New Anticancer Agent (C) 64
- g-Hydroxyaldehyde Derivatives Arising
from Oxidation of Plasmalogens (C) 468
Hydroxybutyric acid
- The Triolide of (R)-3-Hydroxybutyric
acid-Direct
Preparation from Polyhydroxybutyrate and Formation of a
Crown Estercarbonyl Complex with Na
Ions (C) 434
Hydroxycarbonyl compounds
- New
Chiral z-Benzyloxyacryliron(1i)
Complex for Asymmetric Synthesis of
qa-Dialkyl-a-hydroxycarbonyl Compounds (C) 193
Hydroxycarboxylic acids
- Synthesis of (R)- and (S)-2-tert-Butyl-6trifluorome thyl-I ,3-dioxin-4-ones,
Transformations into 3-Hydroxy-3-(trifluoromethyl)alkanoates, and Surprising Differences in the Reactivity of
CH,- and CF,-Substituted Compounds
(C) 1083
Hyperconjugation
- Large Hyperconjugative and Inductive
Effects on C-C-X Bond Angles
(X = Main-Group Element): The Crystal Structure of Triethylborane and Ab
Initio Investigations (C) 314
Immobilization
Photolithographic Immobilization of
Biopolymers on Solid Supports (C) 759
Immunology
- Synthesis of the Species-Specific M y cobacterium
avium
Trisaccharide
-
1682
(Serovar 21) for the Preparation of a
Neoglycoprotein for Immunological
Studies (C) 1358
Immunophilins
- Natural Products as Probes of Cellular
Function: Studies of Immunophilins
(R) 384
Indigo
- Indigoid paw-Quinodimethanes (C) 1202
- Reduction of Dispersed Indigo Dye by
Indirect Electrolysis (C) 1068
Indium compounds
- Idealized Pentagonal-Planar Coordination
for
Indium
in
[&-In){Mn(C0),I5l2- (C) 350
Indoly lacetamides
- Synthesis
of (2-Arylindol-3-yl)acetamides as Probes of Mitochondria1
Steroidogenesis -A New Mechanism
for GABA, Receptor Modulation (C)
1060
Industrial chemistry
- Photochemical Technology (B) 360
Inhibitors
- Synthesis of Esterase-resistant 9 - 0 Acetylated Polysialoside as Inhibitor of
Influenza C Virus Hemagglutinin (C)
1478
Inorganic chemistry
- NMR, NOR. EPR, and Mossbauer
Spectroscopy in Inorganic Chemistry
(B) 108
Insertion reactions
- A Dramatic Difference in the Reactivities of Alkoxido- and Aryloxidorhenium
Complexes in Insertion Reactions (C)
220
Intermolecular interactions
- Intermolecular Forces. An Introduction
to Modern Methods and Results (B)
1538
- Structure of the Lowest Temperature
Phase of the Solid Benzene-Hexafluorobenzene Adduct (C) 1655
- The Structure of Water--a Mixture of
Cubes and Planar Four-Membered
Rings? (H) 1577
lodazide
- Azidoiodoiodine(1 +) Hexafluoroantimonate: The First Binary NitrogenIodine Cation (C) 1338
Iodine compounds
- Alkynyl- and Alkenyl(pheny1)iodonium
Compounds (R) 274
Efficient Synthesis of Nanoscale Macrocyclic Hydrocarbons (C) 922
- Multidentate Macrocyclic Lewis Acids:
Release of ‘“121 Mercuracarborand-4”
from Its Iodide Complex and the Structure of Its Tetra(tetrahydr0fura.n) Dihydrate Complex (C) 893
- Reagents with Hypervalent Iodine: Formation of Convenient Chiral Synthetic
Intermediates by Fragmentation of Carbohydrate Anomeric Alkoxy Radicals
(C) 772
- The Reaction of Unactivated Cobalt
Powder with Iodophosphoranes. The
Synthesis of [Co(PMe,),I,] and the Isolation of the “Frozen Transition-State”
Complex [(nBu,PI),(p-I)][(nBu,Pl)~
(,LL-I)COI,]
(C) 919
Ion channels
- Elementary Steps in Synaptic Transmission Revealed by Currents through
Single Ion Channels (Nobel Lecture)
(R) 830
- Ion Channels for Communication Between and Within Cells (Nobel Lecture)
( R) 824
- Synthetic Chain-Substituted Phospholipids: Ion Transport Across Their Bilayer Membranes (C) 898
~
Towards Artificial Ion Channels: Transport of Alkali Metal Ions across Liposoma1 Membranes
by
“Bouquet”
Molecules (C) 1637
Ion exchangers
- Ion Exchangers (B) 802
Ion pairs
- Penetrated Ion Pairs: a New Form of
Ion Pair (H) 731
- The Crystal Structure of [(Pyrene’-)A Model for
{Na+[(C,H,),O]}]:
Stacked Radical Anion Salts (C) 878
I R spectroscopy
- 2,4-Didehydrophenol-First
Proof of a
meta-Aryne by IR Spectroscopy (C)
1230
Iridium compounds
- A Paramagnetic, Mononuclear
Organometallic Iridium(I1) Complex :
[lr(C6Cl,),(cod)] (C) 1527
Structure of a Product of Double
-
Iron compounds
Dynamic Motion in [HFe(CO),]- Ions
as Observed by Mossbauer Spectroscopy-Evidence for Hydride “Tunneling” (C) 884
- Inorganic
Biochemistry of
Iron
Metabolism (B) 930
Iron Oxides in the Laboratory. Preparation and Characterization (B) 658
- Microcalorimetry of the Spin-Transition
Systems [Fe(bts),(NCS),] and [Fe(2pic),]CI, EtOH
in
the
Range
15 K < T < 300 K (C) 178
- Mossbauer Spectroscopy and Electronic
Structure Calculations of the Nitridoferrates(rr1): Li,[FeN,] and Ba,[FeN,] (C)
1624
- Multifield Saturation
Magnetization
Measurements of Oxidized and Reduced Ribonucleotide Reductase from
Escherichia coli (C) 1513
- New Chiral a-Benzyloxyacryliron(n)
ComDlex for Asymmetric Synthesis of
a,a-Dialkyl-a-hydroxycarbonyl Compounds (C) 193
- New Route to a-l(l E.3E)-dienvllallenes
via Butadiene-t&arbonyliroG Complexes (C) 224
- Novel Iron Carbonyl Telluride
Clusters: Synthesis and Characterization of [Fe,Te,(CO),,]’and
[Fe,Teio(CO)2ol2- (C) 913
- Proof of the Catalytic Activity of a
Naked Metal Cluster in the Gas Phase
(C) 636
- Synthetic Models for Iron-Oxygen
Aggregation and Biomineralization (H)
1010
- Tetraferrioazaallenium-Product
of a
Novel Reaction of Coordinated CN(C) 590
- The Trapping of Iron Hydroxide Units
by the Ligand “heidi”: Two New Hydroxo(oxo)iron Clusters Containing 19
and 17 Iron Atoms (C) 191
Isoarenes
- 1,2,4-Cyclohexatriene, an Isobenzene,
and Bicyclo[4.4.0]deca-l,3,5,7,8-pentaene, an Isonaphthalene: Generation and
Trapping Reactions (C) 473
- 1,2,4-CycIohexatriene, an Isobenzene,
and its [2 + 21 Cycloaddition with
Styrene: A Theoretical Study,(C) 476
Isocoumarins
- 3,4-Dihydroisocoumarins, a New Class
of Ant Trail Pheromones (C) 795
Isocyana tes
- An Unusual Interplay Between Macromolecular and Supramolecular Helicity
-
~
A
Angew. Chrm. I n f . Ed. En$ 1992, 31. No. 12
in Polyisocyanates Dissolved in a Chiral
Liquid Crystal (C) 88
Synthesis of Isocyanate-Substituted Allencs and l ,3-Butadienes by [3,3]Sigmatropic Rearrangements (C) 866
Isocyanide complexes
(1socyanide)ruthenate Analogues of
Tetracarhonylferrate (C) 83
Isocyanides
Chelate Complexes of Tripodal,
Aliphatic Triisocyanide Ligands (C)
1212
Enantioselective Polymerization of 1.2Diisocyanoareiia Synthesis of -0ptically Active, f lelical Poly(quinoxa1ine2.3-diyl)s (C) 1509
-. Lithiodiphenylmethylisocyanide-(
-)sparteine bis(tetrahydrofuran): Crystal
Structure of a Lithiated lsocyanide (C)
79
Observation and Properties of a Hydrogen Bond to Carbon in a Short-Lived,
Gas-Phase Complex of Methyl Isocyanide and Hydrogen Fluoride (C)
202
Reaction of Heterodinuclear p-Ethynediyl Complexes Containing Palladium
and Platinum: Multiple and Successive
Insertion of lsocyanides (C) 851
Isoinversion principle
/rrms-2-tcrr-Butylcyclohex~inol,a
Simple Selectively Optimized Cyclohexunol Auxiliary (C) 1190
lsolohal relationship
Synthesis, Structure, and Bonding of
[CpCoWZ(OCt[ZtBu)h],
and Comments
on the Combining Properties of C O and
CpCo (C) 896
Isomerintion
Intermolecular Additions and Cycloisomeri7ations hy ii Pd-Catalyzed Sequence
of an Intramolecular Redox Reaction
and an Addition (C) 1335
Isothiocyanatcs
- Synthesis and Reactions of Isothiocyanate-Substituted Allciies and 1,3Butadienes (C) 90
Isotope effect
Deuterium-Induced Phase Transition of
an Organic Metal-- -An Unusual Isotope
Effect ( C ) 859
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Ketenimines
Investigations of the Structure and Reactivity of a Stannakctcnimine (C) 437
Kctimines
Crystal and Solution Structures of the
Novel Complex of Sodium Ketimide
with Two Ketimine Ligands
[(tBu,C=NNii),(HN =CtBu,),]:
Stacking of Complexed and Uncomplexcd
Rings to give a Highly
Distorted (“a),
Cuhane (C) 93
Kotocsters
Diastereosclective Three-Center
Michael Addition of [I-Ketoesters to
Prostcrcoecnic 3.M-Unsaturated Carhonyl CoGpounck Cat‘ilyxd by K,CO,
or Cs,CO, ( C ) 1651
Enan6oselective Synthesis of 3-Substituted 2-Ketoesters (C) 618
Kctone pyrolysis
Sclectivc Ketone Pyrolysis: New Synthetic Method for Mono- and Polycyclic
Hydrocarbons (C) 307
Kctoncs
A One-Pot Synthesis of Ketones and
Aldehydes from Carbon Dioxide and
Organolithium Compounds (C) 1035
Kinetics
Chemical Kinetics (B) 239
Chemical Oscillations and Instabilities.
Nonlinear Chemical Kinetics (B) 109
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‘4fly~’ll~
(‘h~,lil
1111 Ed Dr,q/. 1992. 31.
vo. 12
Kinetics of Hydride Transfers from CH,
SiH, GcH, and SnH Groups to Carbenium Ions (C) 1046
Rate Constants for the Attack of Carbenium Ions at Arenes-A Link between
the Chemistry of Aliphatic and Aromatic T[ Systems (C) 1613
Laboratory practicc
Essential Molecular Biology. A Practical Approach (B) 1099
- Microscale Techniques for the Organic
Laboratory (B) 799
Ladderanes
-- Quest for Higher Ladderanes: Oligomerization of a Cyclobutadiene Derivative (C) 1488
Langmuir films
Two-Dimensional Crystallography of
Amphiphilic Molecules at the AirWater Interface ( R ) 130
Lanthanide compounds
- One-Dimensional M”’Cu” Compounds
with an Unprecedented, Tubelike Structural Motif (M = Rare-Earth Metal) (C)
626
Synthesis and Structure of a Mononuclear nZ-Hvdrazine Comdex bv Protonation’of i n [N,H,]’- C‘ompl~x
( C ) 1081
Synthesis of Lanthanide and Actinide
Compounds (B) 105
- The First Self-Assembled Dinuclear
Triple-Helical Lanthanide Complex:
Synthesis and Structure (C) 1622
Lanthanoid compounds
KCeSe,: A New Solid-state L;!nthanide
Polychalcogenide (C) 1594
- New Layered Iron-Lanthanum-OxideSulfide and -Selenide Phases:
Fc,La,O,E, ( E = S,Se) (C) 1645
Laser photolysis
Cyclohexadienyl-Type Cationic Intermediates in the FriedelLCrafts Alkylation of Benzene Derivatives with the 9Fluoreiiyl Cation-Observation
by
Laser Flash Photolysis (C) 743
Laser spectroscopy
High Resolution Spectroscopy below
the Doppler Width (R) 263
Layer structures
- TaNi,Te,, A Novel Layered Telluride,
and TaCo2Te,, a Structural Variant
with Peierls Distortion (C) 217
Lead compounds
- 2,2’,5,5’-Tetra-r(.rr-butyl-l
,l’-diazaplumbocene-a
Stable Azacyclopentadienyl Compound of Lead (C) 778
- The Structure and Stability Trends
of
Fluoro(methyl)plumbanes
(C)
1224
Lignin peroxidase
- Formation of a Toxic Dimerization
Product of 3.4-Dichloroaniline by Lignin Peroxidase from Phanerochaete
c . h r ? . s o ~ / ~ ~ ~(C)
r i i u68
i/
Lignins
Matrix-Assisted Laser Desorption Mass
Spectromctry of Lignins (C) 762
Lipids
High-Yield Synthesis of Lipid Systems
with Giant Rings (C) 1492
Synthetic Bilayer Membranes: Molecular Design, Self-organization, and Application ( R ) 709
Lipopeptides
Ion-Spray Mass Spectrometry of
Lipopeptide Vaccines (C) 226
Liposomes
Towards Artificial Ion Channels: Transport of Alkali Metal Ions across Liposoma1
Membranes
by
“Bouquet”
Molecules (C) 1637
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Liquid crystals
An Unusual Interplay Between Macromolecular and Supramolecular Helicity
in Polyisocyanates Dissolved in a Chiral
Liquid Crystal (C) 88
- Induction of Ferroelectricity in Polymeric Systems through Hydrogen Bonding (C) 1531
Liquid Crystallinity in Polymers. Principles and Fundamental Properties (B)
358
- Paramagnetic Chiral Smectic C Materials: A New Class of Ferroelectric Liquid
Crystals (C) 1471
ortha Lithiation
“Kinetically Enhanced metal at ion"--^How Substituents Direct ortho Lithiation (C) 755
Lithium amides
A Novel Six-Center Deprotonation--Lithiation Reaction Mechanism Supported by the X-Ray Structure Analysis of a Lithium Carbazolide (C)
1209
[Lithium Piperidide-Piperidine],: Crystal Structure of an Oligomeric 1 : 1 Lithium Amide-Amine Mixed Complex, an
lntermediate in the N-Lithiation of
Amines (C) 1205
Lithium perchlorate
Allylation of Quinones with Allylsilane
in the Presence of Lithium Perchlorate
in Ether (C) 313
Low-valent compounds
- A New Approach to Bis(arene)titanium(o) and -titanium( --I) Complexes;
Structure of Bis(arene)titanates(l - ) (C)
1495
- Ether-Soluble Tio and Bis(q‘-arene)titanium(o) Complexes from the Reduction of TiCI, with Triethylhydroborate
(C) 1490
[Ga(C,H 5)] :, Synthesis, Identification,
and Ah lnitio Investigations (C) 1362
[Ga,(C(SiMe,),J,] with a Tetrahedral
Ga, Skeleton (C) 1364
Stable Cyclic Germanediyls (“Cyclogerniylcnes”): Synthesis, Structure.
Metal Complexes, and Thermolyses (C)
1485
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Macrocycles
- A Binary Quinone Receptor (C) 792
A Nonaromatic Expanded Porphyrin
Derived from Anthracene A Macrocycle which Unexpectedly Binds Anions
(C) 452
- A Supramolecular Assembly of Two
Torands, Two Lithium Ions, and Three
Water Molecules (C) 348
Conformational Preference of the
Torand Ligand in Its Complexes with
Potassium and Rubidium Picrate (C)
345
Decamethylcucurhit[S]uril (C) 1475
Designing Synthetic Cationic Molecular
Receptors for Alcohols (C) 478
Efficient Synthesis of Nanoscale Macrocyclic Hydrocarbons (C) 922
- High-Yield Synthesis of Lipid Systems
with Giant Rings (C) 1492
- Ion-Selective
Hydrazone-Azine Tautomerism of a 14-Membered Macrocyclic Ligand (C) 749
Molecular Recognition of Primary
Amines by Three-Point Binding with
Boron-Containing Host Molecules (C)
1017
One-Pot Syntheses of Novel Arene Tricarbonyl Chromium Macrocycles and
Macrobicycle: Structure of a Pentanuclear Trichromium(o)-Dicopper(1)
Cryptate (C) 775
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Matrix Isolation of Diisocyanogen CNOne-Step Synthesis of a Fourfold FuncNC (C) 1215
tionalized Catenane (C) 1619
Maximum entropy method
- Selective Ketone Pyrolysis: New SynMaximum Entropy in Action (€3) 928
thetic Method for Mono- and Polycyclic
Medium-sized rings
Hydrocarbons (C) 307
Ten-Membered Ring Enediynes with
The Triolide of (R)-3-Hydroxybutyric
Remarkable Chemical and Biological
acid Direct Preparation from PolyProfiles (C) 1044
hydroxybutyrate and Formation of a
Membranes
Crown Estcrcarbonyl Complex with Na
- Synthetic Bilayer Membranes: MolecuIons (C) 434
lar Design, Self-organization, and ApMagnetic properties
plication (R) 709
A Novel Pol oxotungstate Containing a
Y
Synthetic Chain-Substituted Phosphotricmgtrlo Ni; Cluster with Fcrromagnetlipids: Ion Transport Across Their Biic Exchange Interactions and an S=3
layer Membranes (C) 898
Ground State (C) 649
Towards Artificial Ion Channels: TransBis(P,P-di-tc,rt-butylphosphinic-~-isoport of Alkali Metal Ions across Liposopropylamidato-N,O)nickel(rr), a Parama1 Membranes
by
“Bouquet”
magnetic Planar Complex (C) 622
Molecules (C) 1637
Induction o f Ferroelectricity in PolyMercury compounds
meric Systems through Hydrogen Bond- Multidentate Macrocyclic Lewis Acids:
ing (C) 1531
Release of “[I 21 Mercuracarborand-4”
Multifield Saturation Magnetization
from Its Iodide Complex and the StrucMeasurements of Oxidized and Reture of Its Tetra(tetrahydrofuran) Dihyduced Ribonucleotidc Reductase from
drate Complex (C) 893
E.drr,ric.hiu coli (C) 1513
Metabolites
One-Dimensional M”’Cu” Compounds
with an Unprecedented, Tubelike Struc- - Dictionary of Plants Containing Sccondary Metabolites (B) 1396
tural Motif(M = Rare-Earth Metal) (C)
Metacyclophanes
626
Pronounced Conformational Changes
Paramugnetic Chiral Smectic C Materii n Sixfold Nitrogen-Functionalized
als: A New Class of Ferroelectric Liquid
Metacyclophanes: Syntheses and CrysCrystals (C) 1471
tal Structures of Two 1,IO-DiManganese compounds
aza[l l]metacyclophancs (C) 882
A New Type of Mn-O Cluster with a
Metal compounds
Mn, Chain Unit. Relevance to the PhoMetals and Their Compounds in the Entosynthelic Oxygcn Evolving Center (C)
vironment: Occurrence, Analysis and
1629
Biological Relevance (B) 102
A Remarkable Change in Framework
Metalates
Cation Positions upon Lithium Exchange: the Crystal Structure of LiMnThe [(p,-WSe,),(p3-Se),(Cu,!,14~ Anion, an Inorganic Cluster with a PinPO,(OH) (C) 1090
wheel Shape (C) 1477
Idealized Pentagonal-Planar Coordination
for
Indium
in
[(p5-ln)- Metalation
Chemical Attachment of Organometal(Mn(CO),j J 2 (C) 350
lics to Proteins in Reverse Micelles (C)
[(Ph3PAu)6Mn(C0)3]+,a Cluster with
789
Pentagonal-Bipyramidal Structure (C)
Metallacumulenes
464
Metallacumulenes: Activation of
Transition Metal in a Cube
Diynes and Access to a Novel BisA Discrete Eight-Coordinate
(Alkenylalleny1idcnc)ruthcnium
[ M n 2 +c [2.2.2]cryptand] as a BodyComplex with the Structural Unit
Centered Cube with an N,O, Donor Set
R,C = C = C = R u = C = C = C R ,
(C) 764
M,d s.s. spectrometry
.
(C) 651
Met allacycles
- Ion-Spray
Mass Spectrometry of
Cyclometallaborazines: Borazines with
Lipopcptide Vaccines (C) 226
Metal Atoms as Ring Building Blocks:
Matrix-Assisted Laser Desorption Mass
PhB(MeN),(TiCI,), ( C ) 598
Spcctromctry of Lignins (C) 762
Cyclophosphazene Metal Oxides, a New
0-11 Bond Activation in the Gas Phase:
Class of Compounds, and Model ComThe Reactions of Water and Methanol
pounds for the Polymerization of Phoswith [FeCH,]’ (C) 603
phazenes (C) 601
Proof of the Catalytic Activity of a
1,3-Dimetallabenzene Derivatives of
Naked Metal Cluster in the Gas Phase
Niobium or Tantalum (C) 1261
( C ) 636
Mctathesis
Structure and Reactivity of Silicon ClusA Cyclometalatcd Aryloxy(ch1oro)ters in the Gas Phase (H) 172
neopentylidcnctungsten Complex: A
The Neutralization of HeC,,f in the Gas
Highly Active and Stereoselective CataPhase: ComDellinrr Evidence for the Exlyst for the Metathesis of cis- and trunsistence of an End%hedral Structure for
2-Pentenc, Norbornene, I-MethylnorI l C f < C C,,, (C) 183
borncnc. and Ethyl Oleate (C) 628
The Phosnhorus Ylide CH-PH, i s
Detection of the Tungsten-CarbeneStablc in the Gas Phase (C) 8 8
Olefin lntcrmediates in Catalytic MetaMaterials science
thesis Systems Containing High-Valent,
Spectral Hole Burning at Room TemMetal Centers (C) 1585
perature and with a Single Molecule:
Michael additions
Two New Perspectives (H) 426
Diastereoselective Three-Center
The Photochemistry of Stilbenoid ComMichael Addition of jf-Ketoesters to
pounds and Their Role in Materials
Prostereogenic a,P-Unsaturated CarTechnology ( R ) 1399
bony1 Compounds Catalyzed by K,CO,
Matrix isolation
or Cs,CO, (C) 1651
2,4-Didchydrophenol First Proof of a
Enantioselectivc Synthesis of the Antitncm-Aryne by IR Spectroscopy (C) 1230
depressant Rolipram by Michael AddiEvidence for [PdSiO] from IR Spection to a Nitroolefin (C) 870
troscopy ( C ) 638
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Microscopy (B) 1534
Mitomycins
The Total Synthesis of (+)-Mitomycin K (C) 915
Mixed-valent compounds
- Mono- and Binuclear Molybdenum
Complexes Incorporating 4-(4-Hydroxypheny1)pyridine: Metal-Metal
Interactions Across an Asvmmetric
Bridging Ligand (C) 1515‘
[Ni,(SC,H,),Br]
and [Ni4(SC3H7)81]:
Mixed Valent Nickel Thiolatcs with Integral and Nonintegral Metal Oxidation
States (C) 54
Molecular biology
- A Milestone i n Genome Sequencing:
The Complete DNA Sequence of the
Yeast Chromosome Ill (H) 1578
- Essential Molecular Biology. A Practical Approach (B) 1099
Molecular dynamics
Calculation of Molecular Dynamics for
Peptides in Dimethyl Sulfoxide: Elimination of Vacuum Effects (C) 210
Cyclodcxtrin Derivatives as Chiral Selectors-Investigation of the Interaction
with (R,S)-Mcthyl-2-chloropropionate
by Enantioselectivc Gas Chromatography, N M R Spectroscopy, and Molecular Dynamics Simulation (C) 319
Dynamic Forcing. a Method for Evaluating Activity and Selectivity Profiles of
R G D (Arg-Gly-Asp) Peptides (C) 326
Molecular electronics
- Molecular Electronics (B) IS36
Molecular modeling
Molecular Modeling of the Class I Human
Histocompatibility
Molecule
HLA-A2 Presenting an Allele-Specific
Nonapcptide from Inlluenza Matrix
Protein (C) 886
Molecular recognition
A Synthetic Receptor for Cyclic
Adenosine Monophosphate (C) 61
Crosslinking of Adjacent Guanine
Residues in an Oli onucleotide by cis. Analysis
[Pt(NH,)2(H,0),]2 4 ,. Kinetic
of the Two-Step Rcaction (C) 1483
DNA Recognition by Hybrid Oligoether-Oligodeoxvnucleotide Macrocycles (CF1617
Enantioselectivc Comulexation of Chiral Dicarboxylic Acids’in Clefts of Functionalized 9.9’-Spirobifluorenes ( C ) I521
In Vitro Selection of Specific Ligandbinding Nucleic Acids (R) 979
Interactions Between Acyclic and Cyclic
Peralkylammonium Compounds and
DNA (C) 1207
Molecular Recognition of Primary
Amines by Three-Point Binding with
Boron-Containing Host Molecules (C)
1017
Selective Binding of Sugar to /l-Cyclodcxtrin: A Prototype for Sugar-Sugar
Interactions in Water (C) 745
Molybdenum compounds
Distortional Isomerism in Oxomolvbdenum Systems; the Evidence Re-evaluated (C) I607
Molecular Mechanisms of the Reduction
of NO toNH,OH at M e S Centers(C) 205
Mono- and Binuclear Molybdenum
Complexes Incorporating 4-(4-Hydroxypheny1)pyridine: Metal-Metal
Interactions Across an Asymmetric
Bridging Ligand (C) 1515
Stable Intermediates in the Addition
and Elimination of SnBuCI, at Molybdenum Ccntcrs by Cleavage or Formation of an Sn-Cl Bond: Crystal Structure
of
[Mo(CO),(PCy,)(p-Cl)(pS,CPCy,)(BuSnCI,)] CH,CI, (C) 76
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Mossbauer spectroscopy
Dynamic Motion in [HFe(CO),]- Ions
as Observed bv Mossbauer Soectroscopy --Evidei;ce for Hydride ‘‘funneling” (C) 884
Moscbauer Spectroscopy and Electronic
Structure Calculations of the Nitridofcrratcs(nr): Li,[FeN,] and Ba,[FeN,] (C)
1624
- [SbCI([l 5]Crown-5)](SbCI6), and [BiCI([ 1 8]Crown-6)(CH,CN),](SbCI6), :
Salts with Antimony(r1i) and
Bismuth(ii1) Dications (C) 334
Multiple bonds
An Arsanylidensilane (“Arsasilene”)
and its Derivatization with Tellurium
and Benzophenone (C) 316
lnvcstigations of the Structure and Reactivity of a Stannaketenimine (C) 437
Novel Strategies for the Synthesis and
Crystallization of Electrophilic Dinuclear Cations: Solution and Solid-State
Propertics of [Re,(NCCH,),,][Mo,01912 (C) 1360
On the Reaction of Pentamethylcyclopentadiene with Cobalt Atoms: A
Reexamination 1392
- Reduction of a Boron-Nitrogen 1,3-Butadiene Analogue: Evidence for a
Strong B-B K-Bond (C) 1082
Thc Electronic Structurc of, [ ( q 5 C,H,),Co,]: Comment on the Existence
of a Complex with an Unsupported CoCo Double Bond (C) 471
The First Complex with a 0 2 7 c 4 Triple
Bond between Vanadium Atoms in a
Ligand Framework of Fourfold Svm-
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Miltipie Peptidc Synthesis Methods
and Their Applications (R) 367
NADH
Formate-Driven, Non-Enzymatic
NAD(P)H Regeneration for the
Alcohol Dehydrogenase Catalyzed
Stercoselcctive Reduction of
4-Phenyl-2-butanone (C) 1529
Natural products
Dictionary of Plants Containing Secondary Metabolites (B) 1396
Flexible Molecules with Defined
Shape Conformational Design (R)
1124 (1657)
Natur‘al Products as Probes of Cellular
Function: Studies of Immunophilins
(R) 384
Pheromones of Marine Brown Algae; A
New Branch of the Eicosanoid
Metabolism (C) 1246
Structurc of the Tunichrome of Tunicates and its Role in Conccntrating
Vanadium (C) 52
- Synthesis of the Calicheamicin Aryltctrasaccharide Domain Bearing a Reducing Terminus: Coupling of Fully
Synthetic Aglycone and Carbohydratc
Domains by the Schmidt Reaction (C)
338
- The Enchanting Alkaloids of Yuzuriha
(R) 665
- The Organosulfur Chemistry of the
Genus Alliimm Implications for the Organic Chemistry of Sulfur (R) 1135
The Total Synthesis of (+)-Mitomycin K (C) 915
- Total
Synthesis of CalicheamicinDynemicin Hybrid Molecules (C) 340
[4 41-Cycloaddition Reactions in the
Total Synthesis of Naturally Occurring
Eight-Membered Ring Compounds (H)
422
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Nervous system
Field-Effect Transistors as Sensors of
Neural Systems (H) 45
Nickel compounds
A Novel Pol oxotungstate Containing a
triungulo Ni\7Cluster with Ferromagnetic Exchange Interactions and an S=3
Ground State (C) 649
Nitrilimine Stabilized by Non-Heteroatom Substituents (C) 439
- Azidoiodoiodine(1 + ) Hexafluoroantimonate: The First Binary NitrogenIodine Cation (C) 1338
- Biochemical Degradation of Cyanamide
and Dicyandiamide (C) 620
- Crystalline Nitrogen Oxides -- Crystal
Bis(P,P-di-tert-butylphosphinic-N-iso- Structure of N,O, and a Remark Conpropylamidato-N,O)nickel(ii), a Paracerning the Crystal Structure of N,O,
magnetic Planar Complex (C) 612
(C) 301
- First Example of a Chlorophin from an
Electrochemical Oxidation of 1-(pUnexpected Oxidative Ring-Opening of
Dimethylaminophenyl)-3,3-dimethyltrian
(Octadehydrocorrinato)nickel(ri)
azene-Cyclic Voltammetric Detection
of a Triazene Radical Cation and DiSalt (C) 70
cation (C) 332
New Intermediate Steps in the Synthesis
Molecular Mechanisms of the Reducof Larger Nickel Clusters (C) 321
- [Ni(PtBu),]-a
Strain on the 18 Election of N O to NH,OH at Mo-S Centers
tron Rule? (H) 424
(C) 205
[Ni,(SC,H,),Br]
and [Ni,(SC,H,),I]:
- Phosphorus Nitrides- the Cinderella of
Mixed Valent Nickel Thiolates with InPhosphorus Chemistry? (H) 170
tegral and Nonintegral Metal Oxidation
- Se,N,CI,,
a Novel Selenium-Nitrogen
States (C) 54
Chloride: Reinvestigation of “Se,N,”
1518
Oxygen Activation on Nickel(i1)SeiNCI, and [Se,NCI,]+[GaCI,]-,
tetrahydrosalen Complexes with the
Chloride Nitrides of Trivalent Selenium
Formation of Nickel(ii)dihydrosalen
Complexes (C) 623
(C) 1251
- Spontaneous Self-Assembly of a Di- The Chemistry of Amidines and Iminickel(rr) Double Helicate Containing a
dates. Vol. 2 (B) 1395
1,3-Benzenediyl Spacer Group (C) 230
The First Reaction of S,N,; Structure
of a Complex Containing an S,N, LigStepwise Stacking of Three Paramagand (C) 616
netic Metallocene Units: [CpNiCp(SiMe,),CpCrCp(SiMe,),CpNiCp] (C) Nitrogen fertilizers
1258
Biochemical Degradation of Cyanamide
and Dicyandiamide (C) 620
Synthesis and Structure of [Ni(PtBu,)]
and [Ni,(PrBu),(CO),] and Calcula- Nitrogen fixation
tions on the Electronic Structure of - An Opinion on the Heterogeneous
Photoreactions of N, with H,O (C) 480
[Ni(PtBu),] and (PR),, R = tBu, Me (C)
Nitronates
323
Tetrakis(q’-ph0sphabenzene)nickel (C) - Concave Wrapped Protons: Reagents
1343
for Contra-Thermodynamic Protona- Unusual
Coordination of the 1,3tions (C) 80
Diphosphacyclobutadiene Derivative Nitrosoalkenes
(iPr,NCP), to Two [Ni(CO),] Frag- - Diacetoneglucose as Auxiliary Group
ments (C) 95
for the Asymmetric Hetero-Dielslder Reaction with Nitrosoalkenes (C)
Niobium compounds
1033
BaNb,O,, a New Oxoniobate with
Nitroxides
Double Layers of Corner-Sharing Nb,
Octahedra (C) 212
- Stable N,N’-Di-terr-butyl-metu- 1,3-Dimetallabenzene Derivatives of
phenylenebisnitroxides-Unexpected
Niobium or Tantalum (01261
Ground-State Singlets (C) 180
NMR microscopy
- LNb{ B(qh-C6H5)2(C,6Hi)2’1(q2H,CC,CH,)]: the First Compound with
Principles of Nuclear Magnetic ResoBent Tetraphenylborate as 12-Electron
nance Microscopy (B) 1394
Donor Ligand (C) 1235
N M R spectroscopy
- Oxoniobzes Containing Metal Clusters
- Determination of the HN-H“ Coupling
(R) 1437
Constant in Large Isotopically Enriched
- The
Reaction of [Cp~Nb,(B,H,),]
Proteins (C) 1609
(Cp’ = rT-EtMe,C,) with Sulfur: StabiDynamic Proton Exchange in the Hydrogen Dihydroxide Ion H,O; of the
lization of the Tetrathioborato Ligand
in Novel Sulfido Niobium Clusters (C)
Hydroxosodalite Hydrate
1021
~Na,(H,O,)I,[SiAIO,I, :
Nitric oxide
H MAS NMR Spectroscopic Evidence
- Tetramethyl-orrho-quinodimethane,
(C) 1210
First Member of a Family of Custom- - Indirect ‘13Cd,14N Spin-Spin Coupling
Constants as a Structural Probe of Solid
Tailored Cheletropic Spin Traps for Nitric Oxide (C) 891
Cadmium Thiocyanate Complexes (C)
1222
Nitrides
- Nitrido Complexes of Transition Metals
Investigation of the [1,7] Sigmatropic
Hydrogen Shift in a Parent Compound
(R) 955
Nitridoferrates
Z,Z-I .3,5-Heptatriene and Its Monodeuterium Analogue (C) 781
Mossbauer Spectroscopy and Electronic
Structurc Calculations of the Nitridofer- - Modern NMR Techniques, and Their
rates(ri1): LiJFeN,] and Ba,[FeN,] (C)
Applications in Chemistry (B) 484
1624
Nuclear Magnetic Resonance Fourier
Nitrilimines
Transform Spectroscopy (Nobel Lec- A Straightforward Synthesis of Nitrilture) (R) 805
imines; X-Ray Crystal Structure of a - On the Mechanism of Coherent DihyNitrilimine Stabilized by Non-Heterodrogen Tunneling in Transition Metal
atom Substituents (C) 439
Trihydrides (C) 1369
Nitrogen compounds
- One Dimensional and Two Dimensional
A Straightforward Synthesis of NitrilNMR Spectra by Modern Pulse Techimines; X-Ray Crystal Structure of a
niques (B) 245
-
-
-
-
-
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-
-
-
-
-
-
-
-
-
Separation of Overlapping Multiplets in
Two-Dimensional NMR Spectra by Selective "Injection" of Magnetization (C)
1248
Solid-State NMR Spectroscopic and XRay Diffraction Studies of the LowTemoerature Structural Transformation
of Hidrated Porous Aluminophosphate
VPI-5 (C) 610
The 3'P-NMR Spectroscopic Determination of the Enantiomeric Excess of
Unprotected Amino Acids (C) 1092
Nobel lecture
- Elementary Steps in Synaptic Transmission Revealed by Currents through
Single Ion Channels (Nobel Lecture) (R)
830
- Ion Channels for Communication Between and Within Cells (Nobel Lecture)
(R) 824
Nuclear Magnetic Resonance Fourier
Transform gpectroscopy (Nobel Lecture) (R) 805
- Soft Matter (Nobel Lecture) (R) 842
Nonlinear optics
- Nitrocalix[4]arenesas Molecules for Second-Order Nonlinear Optics (C) 1075
Nucleic acids
In Vitro Selection of Specific Ligandbinding Nucleic Acids (R) 979
Modern Methods in Protein- and Nucleic Acid Research (B) 245
- Peptide Nucleic Acids (PNAs)-Unusual Properties of Nonionic Oligonucleotide Analogues (H) 1008
Synthesis of Octameric Phosphodiesters
of [3,3-Bis(hydroxymethyl)cyclobutyl]adenine and -thymine as well as their
Hybridization Properties (C) 482
Nucleofuges
Electrostatic Activation of Nucleofuges :
Cationic Leaving Groups (C) 21 6
Nucleosides
- A
Synthetic Receptor for Cyclic
Adenosine Monophosphate (C) 61
5'-P-Borane-Substituted
Thymidine
Monophosphate and Triphosphate (C)
1373
- Nucleoside
Synthesis. Organosilicon
Methods (B) 1098
- Stereoselective Synthesis of PhosphateModified Building Blocks of DNA (C)
1386
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-
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-
Oligosaccharides
Synthesis of the Species-Specific Mycobacterium
uvium
Trisaccharide
(Serovar 21) for the Preparation of a
Neoglycoprotein for Immunological
Studies (C) 1358
Optical anomaly
- Optically Anomalous Crystals (R) 1
Organic conductors
- Deuterium-Induced Phase Transition of
an Organic Metal-An Unusual Isotope
Effect (C) 859
- Oligo(9,10-anthrylenes), Organic Compounds with Stable High-Spin States (C)
448
Organosulfur chemistry
- The Organosulfur Chemistry of the
Genus AIlium-Implications
for the
Organic Chemistry of Sulfur (R)
1135
Oscillations
- Chemical Oscillations and Instabilities.
Nonlinear Chemical Kinetics (B) 109
Osmium compounds
- Carbene Osmium Complexes by Double
Metalation of Alkoxylalkyl- and
Aminoalkylphosphanes (C) 1025
- Catalytic Oxidation of Partially and
Fully Fluorinated Olefins with Osmium
Tetroxide (C) 1345
- [(CO),(PPh3),0sAg(O,CCF,)I:
A
Model for an Intermediate on the Reaction Coordinate in Electron Transfer (C)
770
Oxadi boriranes
- Bis(trisy1)oxadiborirane (C) 1040
Oxidations
- Catalytic Oxidation of Partially and
Fully Fluorinated Olefins with Osmium
Tetroxide (C) 1345
- [ ( C O ) ~ ( P P ~ ~ ) , O S A ~ ( O , C CA
F~)]:
Model for an Intermediate on the Reaction Coordinate in Electron Transfer (C)
770
- Electrochemical Oxidation
of I-@Dimethylaminophenyl)-3,3-dimethyltriazene-Cyclic Voltammetric Detection
of a Triazene Radical Cation and Dication (C) 332
- Enzymatic Oxidation of Methyl Groups
on Aromatic Heterocycles: A Versatile Method for the Preparation of
Heteroaromatic Carboxylic Acids (C)
774
- Selective Oxidation of Methane to CO
and H, over Ni/MgO at Low Temperatures (C) 1189
- Tetrathienylethylenes, a New Class of
Electron Donors-Dications Twisted by
9 0 Stabilized by Formation of Polymethine Units (C) 455
- The
Electrochemical Oxidation of
[Co"(salen)] in Solvent Mixtures-An
Example of a Ladder Scheme with
Coupled Electron-Transfer and SolventExchange Reactions (C) 1215
Oxygen activation
- Oxygen Activation on Nickel(I1)tetrahydrosalen Complexes with the
Formation of Nickel(1r)dihydrosalen
Complexes (C) 623
-
0 - H Activation
0-H Bond Activation in the Gas Phase:
The Reactions of Water and Methanol
with [FeCH,]+ (C) 603
Oligoanthrylenes
- Oligo(9,10-anthrylenes), Organic Compounds with Stable High-Spin States (C)
448
Oligomerization
Scavenger Templates: Synthesis and
Electrospray Mass Spectrometry of a
Linear Porphyrin Octamer (C) 907
Oligonucleotides
Crosslinking of Adjacent Guanine
Residues in an Oli onucleotide by cis[Pt(NH3),(H20),]2' : Kinetic Analysis
of the Two-step Reaction (C) 1483
DNA Recognition by Hybrid OligoPalladium compounds
ether-Oligodeoxynucleotide Macro- Evidence for [PdSiO] from IR Speccycles (C) 1617
troscopy (C) 638
- Oligonucleotides and Analogues. A
Practical Approach (B) 1398
- Nucleophilic Attack at the Central Carbon Atom of (n-Allvlballadium Com- Peptide Nucleic Acids (PNAs)-Unusua1 Properties of Nonionic Oligonucleoplexes: Formation of &-*CyclopropylEstide Analogues (H) 1008
ters (C) 234
Particle beam microanalysis
- Synthesis of Octameric Phosphodiesters
of [3,3-Bis(hydroxymethyl)cyclobutyl]- - Particle Beam Microanalysis. Fundamentals, Methods and Applications (B)
adenine and -thymine as well as their
108
Hybridization Properties (C) 482
-
-
-
-
1686
Pattern recognition
Similarity Models in Organic Chemistry, Biochemistry and Related Fields
(B) 359
Peptide nucleic acids
- Peptide Nucleic Acids (PNAs)-Unusua1 Properties of Nonionic Oligonucleotide Analogues (H) 1008
Peptides
- Calculation of Molecular Dynamics for
Peptides in Dimethyl Sulfoxide: Elimination of Vacuum Effects (C) 210
Configurativelv Stable DiDeDtide Aldehydes-from D-Glucosamiie Hydrochloride (C) 1391
- Dynamic Forcing, a Method for Evaluating Activity and Selectivity Profiles
of RGD (Arg-Gly-Asp) Peptides (C)
326
Ion-Spray Mass Spectrometry of
Lipopeptide Vaccines (C) 226
- Multiple Peptide Synthesis Methods
and Their Applications (R) 367
- N-Perbenzylation of Oligopeptides with
P4-Phosphazene Base; A New Protecting-Group Technique for Modification
and Solubilization of Peptides in Apolar
Organic Solvents (C) 1481
- Retro-Inverso Amide Bonds between
Trifunctional Amino Acids (C) 785
- Selective Inhibition of Trypanosomal
Triosephosphate Isomerase by a Thiopeptide (C) 328
- Stereoselective Nucleophilic Addition
Reactions of Reactive Pseudopeptides
(C) 1626
- The Chemical Synthesis of Peptides (B)
798
- The World of Peptides. A Brief History
of Peptide Chemistry (B) 1535
Pericyclic reactions
- Transition Structures of Hydrocarbon
Pericyclic Reactions (R) 682
Pesticides
- The Biochemistrv and Uses of Pesticides. Structure, 'Metabolism, Mode of
Action and Uses in Crop Protection (B)
242
Pharmaceutics
- Plants for Medicines. A Chemical and
Pharmacological Survey of Plants in the
Australian Region (B) 107
Sulphur-Containing Drugs and Related Organic Compounds. Chemistry,
Biochemistry and Toxicology (B)
107
Phen ylenevinylenes
meta-Phenylene Units as Conjugation
Barriers in Phenylenevinylene Chains
(C) 1653
Pheromones
3,4-Dihydroisocoumarins, a New Class
of Ant Trail Pheromones (C) 795
Do Pheromone Receptors that Receive
the Same or Similar Signal Molecules
Have the Same or Similar Structure? (C)
330
Pheromones of Marine Brown Algae; A
New Branch of the Eicosanoid
Metabolism (C) 1246
Phosphaalkynes
- Spirocyclization of a Stable Phosphaalkyne with Aluminum TrichlorideKey Reaction for the Production of
Triphospha Dewar Benzene Derivatives
(C) 1055
Unusual Coordination of the 1,3Dinhosnhacvclobutadiene
Derivative
(&,NeP), 'to Two [Ni(CO),] Fragments (C) 95
Phosphabenzene
- Tetrakis(q'-phosphabenzene)nickel
(C)
1343
-
-
-
-
-
-
-
-
-
Angew. Chem. Int. Ed. Enxl. 1992, 31, No. 12
Phosphanes
Carbene Osmium Complexes by Double
Metalation of Alkoxylalkyl- and
Aminoalkylphosphanes (C) 1025
Phosphatidylinositol
- Synthesis and Biological Activity of D-3Deoxy-3-FluorophosphatidylinositolA New Direction in the Design of nonDNA Targeted Anticancer Agents (C)
1379
Phosphazenes
- N-Perbcnzylation of Oligopeptides with
P4-Phosphazene Base; A New Protecting-Group Technique for Modification
and Solubilization of Peptides in Apolar
Organic Solvents (C) 1481
Phosuhazenium ions
A ‘Safe Synthesis of Diphosphazenium
Salts (C) 850
Phospholipases
A Phenoxy-Bridged Homodinuclear Zn
Complex with an Unusual Coordination
Sphere; Model Compound for the Active Site of Phospholipase C (C) 1647
Phospholipids
Chemoenzymatic Syntheses of the Optically Active Hydroperoxides of Phosphatidylglycerol and Phosphatidylethanolamine with Lipase, Lipoxygenase. and Phospholipase D (C) 1336
Synthetic Chain-Substituted Phospholipids: Ion Transport Across Their Bilayer Membranes (C) 898
Phosphorus compounds
A New, High-Yield Synthesis of Tetraphosphacubanes (C) 758
- Cyclophosphazene Metal Oxides, a New
Class of Compounds, and Model Comoounds for the Polvmerization of Phosphazenes (C) 601 ’
- Double Open-Edged PI, Dihydrofulvalene as a 16-Electron Donor Ligand (C)
-
~
~
~
~
~
1n11
Electrostatic Activation of Nucleofuges:
Cationic Leaving Groups (C) 216
- Novcl Binuclear Phosphinidene Compounds by Dimerization of the P-HFunctional Phosphenium Complexes
[C,R,(CO),W = PH(Mes)] (R = H, Me)
(C) 1525
- P-Functionalization of the Tetraphosphacubane System (C) 879
- Phosphorus Nitrides-the Cinderella of
Phosphorus Chemistry? (H) 170
- Phosphorus(v) Selenides with Phosphorus in a Trigonal-Planar Environment
(C) 1350
- Ring
Expansion of a 1,2-Diphosphaspiropentane: Formation of a
Diphosphamethylenecyclobutane and a
1,4-Diphosphanorbornadiene(C) 625
- Synthesis, Structure, and Thermolysis of
an Unusual Azaphosphasiliridine (C)
751
- Tetraphosphafulvalene Dianions:
Isoelectronic Species of Tetrathiafulvalene Dications (C) 1031
- The Formation of cyclo-P, Ligands with
Maximum Electron Donor Ability (C)
1377
- The Phosphorus Ylide CH,PH,
is
Stable in the Gas Phase (C) 86
- Three Independent Molecules in the
Unit Cell of a Phosphorus Ylide;
Changes in the Molecular Geometry on
Rotation about the Phosphorus-Carbon Ylide Bond (C) 99
- Zn,[P,,N,,]CI,-A
Sodalite with a
Phosphorus-Nitrogen Framework (C)
21 3
Phosphoryl transfer
- En Route to Synthetic Phosphodiesterases: Supramolecular Phosphoryl-
A n g w . C I i ~ i nI n t . Ed. Enpl. 1992, 31, N o . I2
Transfer Mediated by AmidiniumPhosphate Contact Ion-Pairs (C) 207
Photochemistry
- An Opinion on the Heterogeneous
Photoreactions of N, with H,O (C)
480
- Assistance by Electrophiles in Photoinduced Alkylidyne-Carbonyl Coupling
(C) 747
- Doubly Bridged Prismane and Dewar
Benzene Intermediates in an Unusual
Photochemical Rearrangement of Tricyclic Phthalic Esters (C) 862
- Electronic Aspects of Organic Photochemistry (B) 242
- Frontiers in Supramolecular Organic
Chemistry and Photochemistry (B) 363
- Photochemical Technology (B) 360
- Photodimerization of Anthracenes in
the Solid State: New Results from
Atomic Force Microscopy (C) 595
- Photodimerization of Cinnamic Acid in
the Solid State: New Insights on Application of Atomic Force Microscopy (C)
592
- Photoselective Processes in Cyclooctasulfur Layers: Desorption versus Polymerization (C) 874
- Photoswitchable Association of an Azobenzene-Bipyridinium Diad to Eosin:
Photostimulated “On-Off’ Guest Binding (C) 1243
- Semiconductor-Catalyzed
Photoaddition of Cyclic Enol Ethers to 1,2-Diazenes (C) 1039
- Supramolecular Photochemistry (B) 104
- The Photochemistry of N-Phthaloyl aAmino Acid Esters: A New Approach
to P,y-Unsaturated a-Amino acids and
Dihydrobenzazepinediones (C) 73
- The Photochemistry of Stilbenoid Compounds and Their Role in Materials
Technology (R) 1399
Pho tochromism
- Photochromism. Molecules and Systems (B) 804
Photoelectron spectroscopy
- The Pyrolysis of Tetranitromethane in
the Gas Phase (C) 900
Photolithography
- Photolithographic
Immobilization of
Biopolymers on Solid Supports (C)
759
Photosensitizers
- Stepwise Synthesis of Binuclear Photoactive Complexes with a Bridging 3,4Dihydroxyphenylterpyridine Ligand (C)
1028
Photosynthesis
- A New Type of Mn-O Cluster with a
Mn, Chain Unit. Relevance to the Photosynthetic Oxygen Evolving Center (C)
1629
- Chlorins Designed for Photodynamic
Tumor Therapy and as Model Systems
for Photosynthesis (C) 1592
Physical chemistry
- Physical Chemistry from Ostwald to
Pauling. The Making of a Science in
America (B) 797
Plants
- Dictionary of Plants Containing Secondary Metabolites (B) 1396
Plants for medicines
- Plants for Medicines. A Chemical and
Pharmacological Survey of Plants in the
Australian Region (B) 107
Plasmalogens
- a-Hydroxyaldehyde Derivatives Arising
from Oxidation of Plasmalogens (C) 468
Platinum compounds
- The First Metal-Metal Silyl Migration
in a Heterobimetallic Complex, and the
Structure of the Rearrangement Product
[(OC),Fe(p-PPh,)Pt{ Si(OMe),)(PPh,)](Fe-Pt) (C) 1583
Polarized light microscopy
- Optically Anomalous Crystals (R) 1
Polycycles
- Two Stereoisomeric [4.5.5.5]Fenestranes
Formed by Intramolecular [2 + 21 Cycloaddition (C) 344
- [4 + 4]-Cycloaddition Reactions in the
Total Synthesis of Naturally Occurring
Eight-Membered Ring Compounds (H)
422
Polyenes
- A Homologous Series of Stable Polyenes: Synthesis, Structure, and Redox
Behavior (C) 1588
- Dual Fluorescence of Novel Modified
Carotenoids (C) 1042
- Svnthetic Auuroaches toward Molecular and Pofimeric Carbon Allotropes
(R) 1101
Poiyethers
- Novel Polyether Copolymers Consisting
of Linear and Dendritic Blocks (C) 1200
Polymerization
- Cationic Metallocene Polymerization
Catalysts. Synthesis and Properties of
the First Base-Free Zirconocene Hydride (C) 1375
- Enantioselective Polymerization of 1,2Diisocvanoarenes-Svnthesis of ODtically Active, Helical‘Poly(quinoxa1he2.3-divl)s (CI 1509
- ReacGon of’Heterodinuclear p-Ethynediyl Complexes Containing Palladium
and Platinum: Multiple and Successive
Insertion of Isocyanides (C) 851
- Regioselectivity Control in the Palladium-Catalyzed Copolymerization of
Propylene with Carbon Monoxide (C)
303
Selectivity Control By Temperature
Variation in the Formation of Isotactic
vs. Syndiotactic Polypropylene with a
Titanocene/Alumoxane Catalyst (C)
199
- Synthesis of Optically Active Macromolecules Using Metallocene Catalysts
(HI 47
Polymers
- Liquid Crystallinity in Polymers. Principles and Fundamental Properties (B)
358
- meta-Phenylene Units as Conjugation
Barriers in Phenvlenevinvlene Chains
(C) 1653
- Polvmer Solutions (B) 240
- Soff Matter (NobelLecture) (R) 842
- The Chemistry of Polymers (B) 486
Poly oxometalates
- A Novel Pol oxotungstate Containing a
triungulo Ni, Cluster with Ferromagnetic Exchange Interactions and an S = 3
Ground State (C) 649
- BaNb,O,, a New Oxoniobate with
Double Layers of Corner-Sharing Nb,
Octahedra (C) 212
- New Directions in Polyvanadate Chemistry: From Cages and Clusters to Baskets, Belts, Bowls, and Barrels (H) 49
Polypropylene
- High Molecular Weight Polypropylene
through Specifically Designed Zirconocene Catalysts (C) 1347
- Selectivity Control By Temperature
Variation in the Formation of Isotactic
vs. Syndiotactic Polypropylene with a
Titanocene/Alumoxane Catalyst (C) 199
Polysiloxanes
- Induction of Ferroelectricity in Polymeric Systems through Hydrogen Bonding (C) 1531
~
x
1687
Polyynes
Efficient Synthesis of Nanoscale Macrocyclic Hydrocarbons (C) 922
Novel Cross-Conjugated Compounds
Derived from Tetraethynylethene (C) 1240
Synthetic Approaches toward Molecular and Polymeric Carbon Allotropes
(R) 1101
- The Thermal Conversion of Poly[(silylene)diacetylene] Metal Oxide Composites: A New Approach to P-SiCMC Ceramics (C) 1195
Porph yrinoids
- A Nonaromatic Expanded Porphyrin
Derived from Anthracene-A Macrocycle which Unexpectedly Binds Anions
(C) 452
- First Example of a Chlorophin from an
Unexpected Oxidative Ring-Opening of
an
(Octadehydrocorrinato)nickel(n)
Salt (C) 70
- Scavenger Templates: Synthesis and
Electrospray Mass Spectrometry of a
Linear Porphyrin Octamer (C) 907
- Spectroscopic Characterization of Two
Types of Tetraarylporphyrin Cation
Radicals (C) 1615
Prelog, Vladimir
- My 132 Semesters of Chemistry Studies.
Vladimir Prelog (B) 1395
Prismanes
- Doubly Bridged Prismane and Dewar
Benzene Intermediates in an Unusual
Photochemical Rearrangement of Tricyclic Phthalic Esters (C) 862
Protecting groups
- N-Perbenzylation of Oligopeptides with
P4-Phosphazene Base; A New Protecting-Group Technique for Modification
and Solubilization of Peptides in Apolar
Organic Solvents (C) 1481
- Protective Groups in Organic Synthesis
(9) 658
Proteins
- Chemical Attachment of Organometallics to Proteins in Reverse Micelles (C)
789
- Cytochromes C . Evolutionary, Structural and Physicochemical Aspects (B)
1098
- Determination of the HN-H" Coupling
Constant in Large Isotopically Enriched
Proteins (C) 1609
- Docking of a Second Functional Protein
Layer to a Streptavidin Matrix on a
Solid Support: Studies with a Quartz
Crystal Microbalance (C) 1087
- Modern Methods in Protein- and Nucleic Acid Research (9) 245
- Molecular Modeling of the Class 1 Human
Histocompatibility
Molecule
HLA-A2 Presenting an Allele-Specific
Nonapeptide from Influenza Matrix
Protein (C) 886
- Proteins from the D-Chiral World (H)
1457
Protonations
- Concave Wrapped Protons: Reagents
for Contra-Thermodynamic Protonations (C) 80
Pyrans
Palladium-Catalyzed C-H Activation of
Methoxy Groups: A Facile Synthesis of
Substituted 6H-Dibenzo[h,djpyrans (C)
1023
Pyrazines
- Diprotonated Tetra(2-pyridy1)pyrazine
and its Chemical Mimesis due to Different Hydrogen Bridges (C) 299
Pyrenes
The Crystal Structure of [(Pyrene'-){Na+[(C,H,),O])]:
A Model for
Stacked Radical Anion Salts (C) 878
-
-
-
-
-
1688
Pyrrolidones
Enantioselective Synthesis of the Antidepressant Rolipram by Michael Addition to a Nitroolefin (C) 870
-
Quantum mechanics
Quanta. A Handbook of Concepts (B)
1095
Quartz-crystal microbalance
- Docking of a Second Functional Protein
Layer to a Streptavidin Matrix on a
Solid Support: Studies with a Quartz
Crystal Microbalance (C) 1087
- Quantification of the Reactivity of 3Aininopropyltriethoxysilane Monolayers with the Quartz-Crystal Microbalance (C) 336
Quinodimethanes
- lndigoid
para-Quinodimethanes (C)
1202
Tetrameth yl-orlho-quinodimethane.
First Member of a Family of CustomTailored Cheletropic Spin Traps for Nitric Oxide
891
Quinones
- Allylation of Quinones with Allylsilane
in the Presence of Lithium Perchlorate
in Ether (C) 313
Quinonimines
- Molecular Switching by Electron Transfer- the SpiroperimidineiQuinonimine
System (C) 1498
-
_ _
Radialenes
Preparation and Properties, Reactions,
and Applications of Radialenes (R) 931
Radical anions
- Deuterium-Induced Phase Transition of
an Organic Metal -An Unusual Isotope
Effect (C) 859
- The Crystal Structure of [(Pyrene'-){Na'[(C,H,),O])]:
A Model for
Stacked Radical Anion Salts (C) 878
Radical cations
- A New Synthesis for Imidazolo- and
Pyrrolophanes by [3 + 21 Cycloaddition
with Azaallenyl Radical Cations (C) 209
- Benzo-l,2,3-triselenolium
Trifluoromethanesulfonate--a C,Se, Radical
Cationic Salt with Unusual Solid-state
Structure (C) 779
- Electrochemical Oxidation
of 1-@Dimethylaminophenyl)-3,3-dimethyltriazene- -Cyclic Voltammetric Detection
of a Triazene Radical Cation and Dication (C) 332
- Houben-Wevl. Methoden der Ormnischen Chemie. Band E19c: Cgrbokationen, Carbokation-Radikale (B)
799
- Snectroscopic Characterization of Two
Types of 'Tetraarylporphyrin Cation
Radicals (C) 161 5
Radical reactions
- The Uncatalyzed Transfer Hydrogenation of a-Methvlstvrene bv Dihvdroanthracene or Xanthene -a Radical Reaction (C) 1523
Radicals
- Addition of Benzyl Radicals to Alkenes:
The Role of Radical Deformation in the
Transition State (C) 635
- Reagents with Hypervalent Iodine: Formation of Convenient Chiral Synthetic
Intermediates by Fragmentation of Carbohydrate Anomeric Alkoxy Radicals
(C) 772
- Stable N,N'-Di-tcrt-butyl-mzc.taphen ylenebisnitroxides-Unexpected
Ground-State Singlets (C) 180
- Synthesis of C-Glycopeptides via Free
Radical Addition of Glycosyl Bromides
to Dehydroalanine Derivatives (C) 902
-
Tetramethyl-orrho-quinodimethane,
First Member of a Family of CustomTailored Cheletropic Spin Traps for Nitric Oxide (C) 891
Radiochemistry
- The Chemistry of GALLEX -Measurement of Solar Neutrinos with a Radiochemical Gallium Detector (R) 1283
Reaction mechanisms
- [2,3] Wittig Rearrangements of Nonconjugated Secondary a-Lithioethers: Proof
of Stereospecificity and Inversion of the
Configuration of the Carbanion C
Atom (C) 647
- A Novel Six-Center Deprotonation-Lithiation Reaction Mechanism Supported by the X-Ray Structure Analysis
of a Lithium Carbazolide (C) 1209
- Addition of Benzyl Radicals to Alkenes:
The Role of Radical Deformation in the
Transition State (C) 635
- Chemiluminescence Oscillations Driven
by a Flow-through Reactor in the
[Ru(bpy),]',f
Catalyzed BelousovZhabotinskii Reaction (C) 355
- Mutual Catalysis of Neutral and Anionic Cobalt Carbonyls in their CO Scrambling Reactions (C) 1596
- Reaction
Dynamics
of
Aligned
Molecules (R) 526
- Reaction Mechanisms of Inorganic and
Organometallic Systems (B) 1397
- The Benzene Ring as Dienophile in an
Intramolecular [4 +2] Cycloaddition:
Degenerate Rearrangement of 7.8-Benzobicydo[4.2.2]deca-2,4,7,9-tetraene
(C)
872
Reactive intermediates
- Cyclohexadienyl-Type Cationic lntermediates in the FriedelLCrafts Alkylation of Benzene Derivatives with the 9Fluorenyl Cation-Observation
by
Laser Flash Photolysis (C) 743
- Cyclopropane Derived Reactive Intermediates (9) 241
- Doubly Bridged Prismane and Dewar
Benzene Intermediates in an Unusual
Photochemical Rearrangement of Tricyclic Phthalic Esters (C) 862
- Short-Lived Molecules (B) 362
- Structures of Two Highly Reactive Intermediates upon LiAIH, Reduction
in the Solid State and in Solution:
[(Me,Si),NAIH,Li . 2 Et,O], and
[(Me,Si),N],AIH,Li . 2 Et,O (C) 854
Reagents
A Safe Synthesis of Diphosphazeniuni
Salts (C) 850
- A Simple Method for the Replacement
of the OH Group in Free Carboxylic
Acids by the Phosphonium Ylide Group
(C) 1064
- Alkynyl- and Alkenyl(pheny1)iodonium
Compounds (R) 274
- Allylation of Quinones with Allylsilane
in the Presence of Lithium Perchlorate
in Ether (C) 313
- C-C Coupling with NOJAlkyl Substitution at the Vinylic Carbon by Reaction of 2-Aryl-1 -nitro- 1 -alkenes with
Dialkylzinc Compounds-A Novel Reaction (C) 1587
- Does the Naked Fluoride Ion Exist'? (H)
292
- Ligand Effects in Grignard Additions
(C) 342
- N-Lithiomethyl-N,N',N',N'-tetramethyldiethylenetriamine: The First
Alkyllithium Compound which is
Monomeric in Hydrocarbons (C) 633
- [Lithium Piperidide-Piperidine],: Crystal Structure of an Oligomeric 1 :1 Lithium Amide-Amine Mixed Complex. an
-
-
Atigeir.
Ciwn Int. Ed. Engl. 1992, 31. N o . 12
Intermediate in the N-Lithiation of
Amines (C) 1205
- Preparative Polar Organometallic
Chemistry 2 (B) 485
- Reductions by the Alumino- and Borohydrides in Organic Synthesis (B) 1534
- The Chemistry of Amidines and Imidates. Vol. 2 (B) 1395
Rearrangements
- Synthcsis and Reactions of Isothiocyanate-Substituted Allenes and 1,3Butadienes (C) 90
- Synthesis of Isocyanate-Substituted Allenes and 1,3-Butadienes by [3,3]Sigmatropic Rearrangements (C) 866
- The Benzene Ring as Dienophile in an
Intramolecular [4+ 21 Cycloaddition:
Degenerate Rearrangement of 7,8-Benzobicyclo[4.2.2]deca-2,4,7,9-tetraene
(C)
872
Receptors
- Estradiols Modified by Metal Carbonyl
Clusters as Suicide Substrates for the
Study of Receptor Proteins: Application to the Estradiol Receptor (C) 753
Redox enzymes
Chemical Attachment of Organometallics to Proteins in Reverse Micelles (C)
789
Reductions
- Formate-Driven, Non-Enzymatic
NAD(P)H Regeneration for the
Alcohol Dehydrogenase Catalyzed
Stereoselective Reduction of
4-Phenyl-2-butanone (C) 1529
- Reduction of Dispersed Indigo Dye by
Indirect Electrolysis (C) 1068
- Reductions by the Alumino- and Borohydrides in Organic Synthesis (B) 1534
- Structures of Two Highly Reactive Intermediates upon LiAIH, Reduction
in the Solid State and in Solution:
[(Me,Si),NAIH,Li . 2 Et,O], and
[(Me,Si),N],AIH,Li . 2 E t , 0 (C) 854
Renewable raw materials
- Carbohydrates as Organic Raw Materials (B) 361
- Wood and Cellulosic Chemistrv (B) 801
Retro-inverso peptides
Retro-Inverso Amide Bonds between
Trifunctional Amino Acids (C) 785
Rhenium compounds
A Dramatic Difference in the Reactivities of Alkoxido- and Aryloxidorhenium
Complcxes in Insertion Reactions (C)
220
- [tBuSiO(ReO,)],,
a Model Compound
for Metal Oxides on Silicate Surfaces-Synthesis from the Stable Trio1 tBuSi(OH), and Re,O, (C) 599
- Cyclophosphazene Metal Oxides, a New
Class of Compounds, and Model Compounds for the Polymerization of Phosphazenes (C) 601
- Novel Strategies for the Synthesis and
Crystallization of Electrophilic Dinuclear Cations: Solution and Solid-state
Propcrtics of [Re,(NCCH,),,]IMo,O 912 ( C ) 1360
Rhodium comoounds
- A Rhl-Centered Cage Compound with
Selective Catalytic Properties (C) 905
- Dimerization o f Thiophene to Give a
S(CH),S
Fragment
with
Linear
L(CsMe5)Rh(CzHJzI (C) 357
- Double Open-Edged PI, Dihydrofulvalene as a 16-Electron Donor Ligand (C)
1027
- Enantioselective Rhodium(r1) Catalysts
(H) 1183
- The Formation of cycb-P, Ligands with
Maximum Electron Donor Ability (C)
1377
-
,
\
-
-
A n p i v . Clwin. I n r . Ed Engl. 1992, 31, No. 12
,
Ribonucleotide reductase
Multifield Saturation Magnetization
Measurements of Oxidized and Reduced Ribonucleotide Reductase from
Escherichia coli (C) 1513
Ri bozymes
- In Vitro Selection of Specific Ligandbinding Nucleic Acids (R) 979
Rotaxanes
- Cyclodextrins, Off-the-shelf Components for the Construction of Mechanically Interlocked Molecular Systems (H)
846
- Synthesis of a Lipophilic Cyclodextrin[2]-Rotaxane (C) 783
- Threading Cyclodextrin Rings on Polymer Chains (C) 197
Ruthenium compounds
- Arborols Based o n Luminescent and
Redox-Active Transition Metal Complexes (C) 1493
- (1socyanide)ruthenate
Analogues of
Tetracarbonylferrate (C) 83
- Metallacumulenes: Activation of
Diynes and Access to a Novel Bis(Alkeny1allenylidene)ruthenium
Complex with the Structural Unit
R , C = C = C = Ru = C = C = C R ,
(C) 651
Preparation, Ligand Exchange Reactions, and Structure of a Diene(aaua)ruthenium Complex [(cod)Ru(H,O),](OTs), (C) 440
- [RuO(dppz)(tpy)]’+ : a D N A Cleavage
Agent with High DNA Affinity(C) 1048
- Steowise Svnthesis of Binuclear Photoactive Complexes with a Bridging 3,4Dihydroxyphenylterpyridine Ligand (C)
1028
The Structure of the [l.l]Ruthcnocenophane Dication : Metal-Metal
Bond Formation and the Consequences
of Proximity (C) 1352
-
-
Sandwich complexes
A New Approach to Bis(arene)titanium(o) and -titanium( --I) Complexes;
Structure of Bis(arene)titanates(I - ) (C)
1495
- A Structurally Distorted Ligand in an
Electron-Deficient Dizirconocene
Cation: Unusual 1,2- and I , I -Dimetallioalkenes (C) 876
- I-Borabutadiene(cyc1opentadienyl)cobalt Complexes (C) 1603
- “[Cp*Co=CoCp*]” is a Hydride (C)
1341
- [(q5-Cp),Sn(p-q5:Cp)Na
PMDETA],
a Compound with a Trigonal-Planar
“Paddle Wheel” Triorganostannate Ion
(C) 1226
- Cyclopentadienyl Cobalt Complexes of
Cobaltapentalenes: Products Formed
by Reaction of (p-Cyclopentadienylidene) Cobalt Complexes with Silylalkynes (C) 1058
Ether-Soluble Tio and Bis(q‘-arene)titanium(o) Complexes from the Reduction of TiCI, with Triethylhydroborate
(C) 1490
- [(x-Me,C,),SiH]+--A
Novel Silyl
Cation ((3 1605
”brB(r16-cC,H5)2(CbH5)2}(112H,CCZCH,)]: the First Compound with
Bent Tetrmhenvlborate as 12-Electron
Donor L i g k d (C) 1235
- “Non-Coordinating” Anions: Underestimated Ligands (H) 1181
- On the Reaction of Pentamethylcyclopentadiene with Cobalt Atoms: A
Reexamination 1392
One-Pot MultifUnCtiondlizdtiOn
of
Polymethyl Hydrocarbon TC Ligands.
-
-
-
Maximum Space Occupancy by Double
Branching and Formation of Arboroles
(C) 458
- Stepwise Stacking of Three Paramagnetic Metallocene Units: [CpNiCp(SiMe,),CpCrCp(SiMc,),CpNiCp](C)
1258
- Synthesis and Structure of the First
Trinuclear. Half-Sandwich Carboranegadolinium(1rr) Cluster (C) 432
- Synthesis of Optically Active Macromolecules Using Metallocene Catalysts
(H) 47
- 2,2’,5,5’-Tetra-terf-butyl-l
,l’-diazaplumbocene-a
Stable Azacyclopentadienyl Compound of Lead (C) 778
- The Electronic Structure of, [ ( q s C,H,),Co,]: Comment on the Existence
of a Complex with an Unsupported CoCo Double Bond (C) 471
- The Structure of the [l.l]Ruthenocenophane Dication: Metal-Metal
Bond Formation and the Consequences
of Proximity (C) 1352
Scanning tunneling microscopy
- Molecular Imaging of Alkanol Monolayers on Graphite (C) 189
- Scanning Tunneling Microscopy and
Atomic Force Microscopy in Organic
Chemistry (R) 1298
Selenium compounds
- Benzo-I ,2,3-triselenolium
Trifluoromethanesulfonate--a C,Se3 Radical
Cationic Salt with Unusual Solid-state
Structure (C) 779
- KCeSe, : A New Solid-State Lanthanide
Polychalcogenide (C) 1594
- New Intermediate Steps in the Synthesis
of Larger Nickel Clusters (C) 321
- Phosphorus(v) Selenides with Phosphorus in a Trigonal-Planar Environment
(C) 1350
- Selenonium
Hexafluoroantimonate,
H,Se+SbF; (C) 643
Se3N,CI,, a Novel Selenium-Nitrogen
Chloride: Reinvestigation of “Se,N,”
(C) 1518
Se,NCI,
and [Se,NCI,]+[GaCl,]~,
Chloride Nitrides of Trivalent Selenium
( C ) 1251
- Synthesis and Structure of the Cluster
[NaAu,,SeJ- : An Inorganic Cryptand Complex (C) 787
- The [(p,-wse4),(p3-se)*(c~3)z14Anion, an Inorganic Cluster with a Pinwheel Shape (C) 1477
Self-assem bly
Decamethylcucurbit[5]uril (C) 1475
- Induction of Ferroelectricity in Polymeric Systems through Hydrogen Bonding (C) 1531
- Self-Assembly of a Cu, Complex with
Coplanar Copper(1) Ions: Synthesis,
Structure, and Electrochemical Properties (C) 733
- Solid-state Columns Made from Twisted, Self-complementary Terpyridine
Units (C) 1244
- Spontaneous Self-Assembly o f a Dinickel(r1) Double Helicate Containing
a 1.3-Benzenediyl Spacer Group (C)
230
- Supramolecular
Self-Assemblies o f
Two-Directional Cascade Molecules:
Automorphogenesis (C) 917
- Synthetic Bilayer Membranes: Molecular Design, Self-Organization, and Application (R) 709
- The First Self-Assembled Dinuclear
Triple-Helical Lanthanide Complex :
Synthesis and Structure (C) 1622
Self-replication
- Artificial Replication Systems (H) 1013
-
-
-
1689
Self-Replication by Condensation of
3-Aminobenzamidines and 2-Formylphenoxyacetic Acids (C) 654
Semiempirical calculations
- Product Predictions for Nucleophilic
Additions to C,, (C) 1468
Sensors
- Field-Effect Transistors as Sensors of
Neural Systems (H) 45
Separation techniques
- Non-Chromatographic Continuous
Separation Techniques (B) 484
Serovar 21
- Synthesis of the Species-Specific Mycobacteriurn
nviurn
Trisaccharide
(Serovar 21) for the Preparation of a
Neoglycoprotein for Immunological
Studies (C) 1358
Sesquichalcogenides
- A Germanium Sesquisulfide,
(tBuGe),S,, without Adamantane
Structure (C) 59
Sialosides
- Synthesis of Esterase-resistant
9-0Acetylated Polysialoside as Inhibitor of
Influenza C Virus Hemagglutinin (C)
1478
Siderophores
- Synthesis and Complexation Properties
of a Cyclodextrin-Derived Siderophore
Analogue (C) 1381
- The First Structural Characterization of
a Metal-Enterobactin Complex:
[V(enterobactin)]’- (C) 466
Si-H activation
- Triphosphatrisilacyclohexanes as Tridentate Coronands in Cr and Mo Complexes: Activation of Si-H in an Early
Stage versus Phosphane Coordination
(C) 1510
Silicon compounds
- An
Arsanylidensilane (“Arsasilene”)
and its Derivatization with Tellurium
and Benzophenone(C)316
- [tBuSiO(ReO+)],, a Model Compound
for Metal Oxides on Silicate SurfacesSynthesis from the Stable Trio1 tBuSi(OH), and Re,O, (C) 599
- Control and Design Principles in Biological Mineralization (R) 153
- Gas-Phase
Reactions of M’ and
[CpM]’ (M = Fe, Co, Ni) with 1,3,5Trisilacyclohexane : First Evidence for
the Formation of 1,3,5-Trisilabenzene
(C) 1633
- (H,Si)2E, and (Mes(tBu)Si),E,
(E = As, P): Incommensurable Systems
of Different Stability with Unusually
Long E-E Bonds (0460
- [(rc-~e,C,),SiH]+-~A Novel
Silyl
Cation (C) 1605
- Model Compounds for Metal Oxides on
SiO, Surfaces (H) 586
- Octakis(l,1,2-trimethylpropyl)octasilacubane: Synthesis, Molecular Structure,
and Unusual Properties (C) 1354
- On the Bonding in Carbosilanes (C) 185
- S&. an Analogue of C,,? (H) 173
- Structure and Reactivity of Silicon Clusters in the Gas Phase (H) 172
- Synthesis, Structure, and Thermolysis of
an Unusual Azaphosphasiliridine (C)
751
- The Reaction of Tetramesityldisilene
with As,: Synthesis and Structure of a
Novel Arsenic-Silicon Tricyclic Ring
System ( C ) 1217
- The Thermal Conversion of Poly[(si1ylene)diacetylenel Metal Oxide Composites: A New Approach to ,&Sic-MC Ceramics (C) 1195
- Triphosphatrisilacyclohexanes as Tridentate Coronands in Cr and Mo Com-
1690
dexes: Activation of Si-H in an Early
Stage versus Phosphane Coordination
(C) 1510
Silicon monoxide
Evidence for [PdSiO] from 1R Spectroscopy (C) 638
Silver comoounds
- Ag,Ged,, a New Semiconducting Oxide (0653
- [(CO)i(PPh ,) ,OsAg(O ,CCF ,)I : A
Model for an Intermediate on the Reaction Coordinate in Electron Transfer (C)
770
- Molecular Machines: Molecular Structure
of [@-Tol,P),,Au,,Ag,,C1,](PF,)-a
Cluster with a Biicosahedral
Rotgrlike Metal Core and an Unusual
Arrangement of Bridging Ligands (C)
445
Similarity modeling
- Similarity Models in Organic Chemistry,
Biochemistry and Related Fields (B) 359
Size exclusion chromatography
- Preparative-Scale Separation of C,, and
C,o, on Polystyrene Gel (C) 644
Sodalite
- Zn,[P,,N,,]Cl,-A
Sodalite with a
Phosphorus-Nitrogen Framework (C)
21 3
Solid-phase synthesis
- A New Strategy for Solid-Phase Synthesis of 0-Glycopeptides (C) 857
Solid-state chemistry
Bonding and Structure: Structural Principles in Inorganic and Organic Chemistry (B) 663
- KCeSe,: A New Solid-state Lanthanide
Polychalcogenide (C) 1594
- Solid State Chemistry-Compounds
(B)
1396
Synchrotron X-ray and Neutron Diffraction Studies in Solid-state Chemistry (R) 1557
Solid-state structures
- A Remarkable Change in Framework
Cation Positions upon Lithium Exchange: the Crystal Structure of LiMnPO,(OH) (C) 1090
- Are Denser Packings of Spheres than
Closest Packings Possible? How Many
Closest Packings of Spheres Exist? (H)
721
- Band Theory of Solids. An Introduction
from the Point of View of Symmetry (B)
3 097
- Generalized Edshammar Polyhedra for
the Description of a Family of SolidState Structures (C) 924
- New Layered Iron-Lanthanum-OxideSulfide and -Selenide Phases:
Fe,La,O,E, (E = S,Se) (C) 1645
- Oxoniobates Containing Metal Clusters
(R) 1437
Solvation
- Penetrated Ion Pairs: a New Form of
Ion Pair (H) 731
Spectroscopy
- Atomic Spectroscopy (B) 236
- High Resolution Spectroscopy below
the Doppler Width (R) 263
- NMR, NQR, EPR, and Mossbauer
Spectroscopy in Inorganic Chemistry
(B) 108
- Reaction
Dynamics
of Aligned
Molecules (R) 516
Spin transitions
- Microcalorimetry of the Spin-Transition
Systems [Fe(bts),(NCS),] and [Fe(2pic),]CI, . EtOH
in
the
Range
15 K < T < 300 K (C) 178
Spin traps
- Tetramethyl-ortho-quinodimethane,
First Member of a Family of Custom-
-
-
Tailored Cheletropic Spin Traps for Nitric Oxide (C) 891
Squalenes
- The Folding of Saualene: An Old Problem has N& Reiults (H) 582
Statistics
- Chemometrics. Applications of Mathematics and Statistics to Laboratory Systems (B) 663
Stereochemistry
- Flexible
Molecules with Defined
Shape--Conformational
Design (R)
1124 (1657)
- Stereochemistry
of Organic Compounds. Principles and Applications (B)
1539
Steroids
Synthesis of (2-Arylindol-3-yl)acetamides as Probes of Mitochondria1
Steroidogenesis-A
New Mechanism
for GABA, Receptor Modulation (C)
1060
- The Folding of Squalene; An Old Problem has New Results (H) 582
- The Tandem Sakurai-Carbonyl-Ene
Reaction: A New and Highly Stereoselective Sequential Transformation and
Its Use for the Synthesis of Steroid
Derivatives (C) 1223
Stilbenes
- The Photochemistry of Stilbenoid Compounds and Their Role in Materials
Technologv (R) 1399
Strained rings
- Anti-Bredt
Enol Ethers by Transannular Cvclization of Cvcloalkvnols
(C) 791
- Boriranes: Structures and Thermal Ring
Openings (C) 1384
Compounds with Three-Membered
Rings Containing Boron (H) 1329
- Cubanes: Starting Materials for the
Chemistrv of the 1990s and the New
Century (R) 1421
- Cycloalkadiynes-From
Bent Triple
Bonds to Strained Cage Compounds (R)
-
-_
I
-
17
’51
Cyclobutarenes. The Chemistry of Benzocyclobutene, Biphenylene, and Related Compounds (B) 1264
1,2,4-CycIohexatriene. an Isobenzene,
and Bicyclo[4.4.0]deca-l,3,5,7,8-pentaene, an Isonaphthalene: Generation and
Trapping Reactions (C) 473
- 1,2,4-Cyclohexatriene, an Isobenzene,
and its [2 + 21 Cycloaddition with
Styrene: A Theoretical Study (C)
476
- Cyclopropane Derived Reactive Intermediates (B) 241
- Homodiboriranides: The Simplest Negatively Charged Homoaromatic Compounds (C) 1238
- Nucleophilic Attack at the Central Carbon Atom of (rc-Ally1)palladium Complexes: Formation of x-Cyclopropyl Esters (C) 234
- Preparation and Properties, Reactions,
and Applications of Radialenes (R)
931
- Quest for Higher Ladderanes: Oligomerization of a Cyclobutadiene Derivative (C) 1488
- Ring
Expansion of a 1,2-Diphosphaspiropentane: Formation of a
Diphosphamethylenecyclobutane and a
1.4-Diphosphanorbornadiene(C) 625
- Strain-Activated Formation of a TripleLayered Phane (C) 1073
- The Reaction of Tetramesityldisilene
with As,: Synthesis and Structure of a
Novel Arsenic-Silicon Tricyclic Ring
System (C) 1217
-
-
Angrw. Chem. Inl. Ed. Engl. 1992, 31, N o . 12
S trcptavidin
Docking of a Second Functional Protein
Layer to a Streptavidin Matrix on a
Solid Support: Studies with a Quartz
Crystal Microbalance (C) 1087
Structure elucidation
- Bond-Stretch Isomers: Fact or Artifact?
(H) 286
- Caro’s Acid: Molecular Structure and
Association in the Solid State at
- 130 “C (C) 436
- Crystalline Nitrogen Oxides -- Crystal
Structure of N,O, and a Remark Concerning the Crystal Structure of N,O,
(C) 301
- Diprotonated Tetra(2-pyridy1)pyrazine
and its Chemical Mimesis due to Different Hydrogen Bridges (C) 299
- Distorted Molecules: Perturbation Design, Preparation and Structures (R) 550
- Novel Strategies for the Synthesis and
Crystallization of Electrophilic Dinuclear Cations: Solution and Solid-state
Properties of [Re,(NCCH,),,JIMo,O,,I, (C) 1360
- Perfluorotriethvlamine: An Amine with
Unusual Structure and Reactivity (C)
1467
- Solving the Structure of a Metal-Substituted Aluminum Phosphate Catalyst by
Electron Microscopy, Computer Simulation, and X-ray Powder Diffraction
(C) 1472
- Structure of the Lowest Temperature
Phase of the Solid Benzene-Hexaffuorobcnzene Adduct (C) 1655
- Synchrotron X-ray and Neutron Diffraction Studies in Solid-state Chemistry (R) 1557
- The Isomers of the Acetylene Derivatives C,Li,: Transferabie Structural
Units in Hyperlithiated Compounds (C)
1602
- The New Subnitride NaBa,N; an Extension of Alkali Metal Suboxide Chemistry (C) 1519
- The Structure ofC,,: Orientational Disorder in the Low-Temperature Modification of C,, (C) 640
- The Structure of Water-a
Mixture of
Cubes and Planar Four-Membered
Rings? (H) 1577
Structure-activity relationship
- Do Pheromone Receptors that Receive
the Same or Similar Signal Molecules
Have the Same or Similar Structure? (C)
330
- Similarity Models in Organic Chemistry, Biochemistry and Related Fields
(B) 359
Styrenes
- The Uncatalyzed Transfer Hydrogenation of u-Methylstyrene by Dihydroanthracene or Xanthene-a Radical Reaction (C) 1523
Subnitrides
- The New Subnitride NaBa,N; an Extension of Alkali Metal Suboxide Chemistry (C) 1.519
Sugars
- Emil Fischer’s Proof of the Configuration of Sugars: A Centennial Tribute (R)
1541
Sulfinylcarboxylic acids
- Salting Out Selective Extraction-A
Novel Method for the Optical Resolution of Chiral Sulfinylcarboxylic Acids
and Its Application for the Convenient
Determination of Optical Purity (C) 3631
Sulfur
- Photoselective Processes in Cyclooctasulfur Layers: Desorption versus Polymerization (C) 874
Angel%.Chon In1 Ed Enxl. 1992. 31, No. 12
Sulfur compounds
A Germanium Sesquisulfide,
(tBuGe),S,, without Adamantane
Structure (C) 59
- Caro’s Acid: Molecular Structure and
Association in the Solid State at
- 130 “C (C) 436
- Chemistry of Organsulfur Compounds.
General Problems (B) 238
- Dimerization of Thiophene to Give a
Linear S(CH),S
Fragment
with
[(C,Me,)Rh(C,H,),I (C) 357
- Sulfur Analogues of Polycyclic Aromatic Hydrocarbons (Thiaarenes). Environmental Occurrence, Chemical and Biological Properties (B) 364
- The First Reaction of S,N,; Structure
of a Complex Containing an S,N; Ligand (C) 616
- The Organosulfur Chemistry of the
Genus Allium- Implications for the
Organic Chemistry of Sulfur (R)
1135
- The Structures of Thiosulfuric Acid
H S 0 and Its Monoanion HS,O; (C)
-
-
582
*
Sulfur-containing drugs
Sulphur-Containing Drugs and Related
Organic Compounds. Chemistry, Biochemistry and Toxicology (B) 107
Supramolecular chemistry
- Molecules with
Large Cavities in
Supramolecular Chemistry (R) 528
- Supramolecular Photochemistry (B) 104
Surface chemistry
- Dependence of the Reactivity of Ag and
Ni Clusters Deposited on Solid Substrates on the Cluster Size (C) 1062
- Quantification of the Reactivity of 3Aminopropyltriethoxysilane Monolayers with the Quartz-Crystal Microbalance(C)336
- Spectral Hole Burning at Room Temperature and with a Single Molecule:
Two New PersDectives (Hl 426
Surfaces
- [tBuSiO(ReO,)],, a Model Compound
for Metal Oxides on Silicate SurfacesSynthesis from the Stable Trio1 tBuSXOHL and Re,O, (0
599
- Electrochemical Intekaces. Modern
Techniques for in-situ Interface Characterization (B) 238
- Metal-Surface Reaction Energetics.
Theory and Applications to Heterogeneous Catalysis, Chemisorption, and
Surface Diffusion (B) 1538
- Model Compounds for Metal Oxides on
SiO, Surfaces (H) 586
- Molecular Imaging of Alkanol Monolayers on Graphite (C) 189
- Photodimerization of Anthracenes in
the Solid State: New Results from
Atomic Force Microscopy (C) 595
- Photodimerization of Cinnamic Acid in
the Solid State: New Insights on Application of Atomic Force Microscopy (C)
592
- Two-Dimensional Crystallography of
Amphiphilic Molecules at the AirWater Interface (R) 130
Surfactants
- Soft Matter (Nobel Lecture) (R) 842
Syngas
- Selective Oxidation of Methane to co
and H, over Ni/MgO at Low Temperatures (C) 1189
Synthetic methods
- A One-Pot Synthesis of Ketones and
Aldehydes from Carbon Dioxide and
Organolithium Compounds (C) 1035
- Alkynyl- and Alkenyl(pheny1)iodonium
Compounds (R) 274
-
-
-
-
-
-
i
!
\
-
-
-
Design and Optimization in Organic
Synthesis (B) 1393
Diastereoselective Addition of Allylsilanes to Aldehydes: Synthesis of Enantiomerically Pure Homoallylic Alcohols
(C) 1372
Intermolecular Additions and Cycloisomerizations by a Pd-Catalyzed Sequence
of an Intramolecular Redox Reaction
and an Addition (C) 1335
Modern Synthetic Methods 1992. Vol. 6
(B) 1393
Multiple Peptide Synthesis Methods
and Their Applications (R) 367
Nucleoside Synthesis. Organosilicon
Methods (B) 1098
N-Perbenzylation of Oligopeptides with
P4-Phosphazene Base; A New Protecting-Group Technique for Modification
and Solubilization of Peptides in Apolar
Organic Solvents (C) 1481
Preparation and Properties, Reactions,
and Applications of Radialenes (R)
93 1
Reagents with Hypervalent Iodine: Formation of Convenient Chiral Synthetic
Intermediates by Fragmentation of Carbohydrate Anomeric Alkoxy Radicals
(C) 712
Scavenger Templates: Synthesis and
Electrospray Mass Spectrometry of a
Linear Porphyrin Octamer (C) 907
Synthesis of (R)-and (S)-2-tert-Butyl-6trifluoromethyl-I ,3-dioxin-4-ones,
Transformations into 3-Hydroxy-3-(trifluoromethyl)alkanoates, and Surprising Differences in the Reactivity of
CH,- and CF,-Substituted Compounds
(C) 1083
The Enchanting Alkaloids of Yuzuriha
(R) 665
Transition Metals in Total Synthesis (B)
365
Tandem reactions
- Cascade Cyclizations (H) 1332
- Stereocontrolled
Construction
of
6 . 5 . 6 and 5 . 5 . 6 Ring Systems by
Radical Tandem Cyclization (C) 910
- The Tandem Sakurai-Carbonyl-Ene
Reaction: A New and Highly Stereoselective Sequential Transformation and
Its Use for the Synthesis of Steroid
Derivatives (C) 1221
Tantalum compounds
- 1,3-Dimetallabenzene Derivatives of
Niobium or Tantalum (C) 1261
- The Structure of Pentamethyltantalum
(C) 1462
- The Structures of Pentamethyltantalum
and -Antimony: One Square Pyramid
and One Trigonal Bipyramid (C) 1464
Tautomerism
- Ion-Selective Hydrazone-Azine
Tautomerism of a 14-Membered Macrocyclic Ligand (C) 749
Technetium compounds
- 99mTcLabeled Biotin Conjugate in a Tumor “Pretargeting” Approach with
Monoclonal Antibodies (C) 1507
Tellurium compounds
- Chelate Stabilization of a Monomeric
Lithium Tellurolate (C) 1260
- Control of the Reaction of n-Butyllithiurn with Benzo[b]tellurophene by the
Solvent-Either Metalation or Tellurium-Lithium Exchange To Give an Interesting Lithiostyryllithium (C) 1339
- Houben-Weyl. Methods of Organic
Chemistry. Additional and supplementary volumes to the 4th Edition. Vol. E
12b. Organotellurium Compounds (B)
237
1691
Novel Iron Carbonyl Telluride
Clusters: Svnthesis and Characterization +of [Fe,Te,(CO),,]2and
[Fe8Te,0(C0),012- ( c ) 913
- TaNi,Te,, A Novel Layered Telluride,
and TaCo,Te,, a Structural Variant
with Peierls Distortion (Cf 217
- The Pentagonal Bipyramid as Fundamental Structure for Compounds with
the Coordination Number Seven* (C)
1036
Terpyridines
- Solid-state Columns Made from Twisted, Self-Complementary Terpyridine
Units (C) 1244
- Stepwise Synthesis of Binuclear Photoactive Complexes with a Bridging 3,4Dihydroxyphenylterpyridine Ligand (C)
1028
Tetraal kynylmethanes
- Tetraalkynylmethanes: Synthesis of Diethynyldipropargyl- and Tetrapropargylmethane (C) 1648
Tetraethynylethene
- Novel Cross-Conjugated Compounds
Derived from Tetraethynylethene (C)
1240
Tetranitromethane
- The Pyrolysis of Tetranitromethane in
the Gas Phase (C) 900
Tetrathiafulvalenes
- Tetraphosphafulvalene Dianions:
Isoelectronic Species of Tetrathiafulvalene Dications (C) 1031
Tetrathien yle thylenes
- Tetrathienylethylenes, a New Class of
Electron Donors-Dications Twisted by
90” Stabilized by Formation of Polymethine Units (C) 455
Tetrathioborate
- The
Reaction of [CpiNb,(B,H,),]
(Cp’ = q-EtMe,C,) with Sulfur: Stabilization of the Tetrathioborato Ligand
in Novel Sulfido Niobium Clusters (C)
1021
Textbooks
- Essential Molecular Biology. A Practical Approach (B) 1099
- Microscale Techniques for the Organic
Laboratory (B) 799
- The Science of Crystallization. Microscopic Interfacial Phenomena (B) 1536
Theoretical chemistry
- Chemical Bonding Theory (B) 663
- Electron Localization in Solid-state
Structures of the Elements: the Diamond Structure (C) 387
- Metal-Surface
Reaction Energetics.
Theory and Applications to Heterogeneous Catalysis, Chemisorption, and
Surface Diffusion (B) 1538
- On the Bonding in Carbosilanes (C) 185
- Quanta. A Handbook of Concepts (B)
1095
- Structures, Structures, and Structures
(H) 290
Thermochromicity
- New Thermo-Response Dyes: Coloration bv the Claisen Rearrangement
and Intramolecular Acid-Base Reaction
(C) 204
Thin films
- An Introduction to Ultrathin Organic
Films from Langmuir-Blodgett to SelfAssembly (B) 929
- C,, and C,, in a Basket?--1nvestigations of Mono- and Multilayers from
Azacrown Compounds and Fullerenes
(C) 1599
- Docking of a Second Functional Protein
Layer to a Streptavidin Matrix on a
Solid Support: Studies with a Quartz
Crystal Microbalance (C) 1087
-
1692
- Molecular Imaging of Alkanol Monolayers on Graphite (C) 189
- Photoselective Processes in Cyclooctasulfur Layers: Desorption versus Polymerization (C) 874
- Quantification of the Reactivity of 3Aminopropyltriethoxysilane Monolayers with the Quartz-Crystal Microbalance (C) 336
- Two-Dimensional Crystallography of
Amphiphilic Molecules at the AirWater Interface (R) 130
Thin-layer chromatography
- Handbook of Thin Layer ChromatograPhY (B) 360
Thiocyanates
- Indirect 113Cd,14N
Spin-Spin Coupling
Constants as a Structural Probe of Solid
Cadmium Thiocyanate Complexes (C)
1222
Thiopeptides
- Chain Elongation of Thiodipeptides
with Proteases (C) 1229
- Selective Inhibition of Trypanosomal
Triosephosphate isomerase by a Thiopeptide (C) 328
Thiophene
- Dimerization of Thiophene to Give a
Linear S(CH),S
Fragment with
~(C,Me,)Rh(C,H,),I (C) 357
Thiophcnes
- Tetrathienylethylenes, a New Class of
Electron Donors--Dications Twisted by
90” Stabilized by Formation of Polymethine Units (C) 455
Thiosulfuric acid
- The Structures of Thiosulfuric Acid
H S 0 and Its Monoanion HS,O; (C)
5x’
Tin compounds
- A Homologous Series of Stable Polyenes: Synthesis, Structure, and Redox
Behavior (C) 1588
- [(q’-Cp),Sn(p-$_Cp)Na . PMDETA],
a Compound with a Trigonal-Planar
“Paddle Wheel” Triorganostannate Ion
(C) 1226
- Investigations of the Structure and
Reactivity of a Stannaketenimine (C) 437
- Stable Intermediates in the Addition
and Elimination of SnBuCI, at Molybdenum Centers by Cleavage or Formation of an Sn-CI Bond: Crystal Structure
of
[Mo(CO),(PCy,)(pCI)(pS,CPCy,)(BuSnCI,)] . CH,CI, (C) 76
- The Hydroxyl-Directed Hydrogenation
of Vinylstannanes and Silanes: A Highly
Diastereoselective Route to /I-Stannyl
and /l-Silyl Alcohols (C) 232
Titanium compounds
- A New Approach to Bis(arene)titanium(o) and -titanium( -I) Complexes;
Structure of Bis(arene)titanates(l - ) (C)
1495
- Cyclometallaborazines: Borazines with
Metal Atoms as Ring Building Blocks:
PhB(MeN),(TiCI ) 2 (C) 598
- Ether-Soluble Ti’ and Bis($-arene)titanium(o) Complexes from the Reduction of TiCI, with Triethylhydroborate
(C) 1490
- Template-Controlled Organization of a
Fluoride Surface-An
Analogue of a
Crown Ether in the Reaction of [((v5C,Me,)TiF,),] with Sodium Fluoride
(C) 864
Torands
- A Supramolecular Assembly of Two
Torands, Two Lithium Ions, and Three
Water Molecules (C) 348
- Conformational Preference of the Torand
Ligand in Its Complexes with Potassium
and Rubidium Picrate (C) 345
Total syntheses
Synthesis of the Calicheamicin Aryltetrasaccharide Domain Bearing a Reducing Terminus: Coupling of Fully
Synthetic Aglycone and Carbohydrate
Domains by the Schmidt Reaction (C)
338
- The Total Synthesis of (+)-Mitomycin K (C) 915
- Total Synthesis of CalicheamicinDynemicin Hybrid Molecules (C)
340
- Total Synthesis of the Carbohydrate
Fragments of Esperamicin A, (C) 855
- Transition Metals in Total Synthesis (B)
365
- [4
4]-Cycloaddition Reactions in the
Total Synthesis of Naturally Occurring
Eight-Membered Ring Compounds (H)
422
Toxicity
- Formation of a Toxic Dimerization
Product of 3,4-Dichloroaniline by Lignin Peroxidase from Phanerochaete
chrysosporium (C) 68
Triolides
- The First Structural Characterization of
a Metal-Enterobactin Complex:
[V(enterobactin)]’ - (C) 466
- The Triolide of (R)-3-Hydroxybutyric
acid-Direct
Preparation from Polyhydroxybutyrate and Formation of a
Crown Estercarbonyl Complex with Na
Ions (C) 434
Triquinanes
- Stereocontrolled
Construction
of
6 . 5 . 6 and 5 . 5 . 6 Ring Systems by
Radical Tandem Cyclization (C) 910
Tungsten compounds
- A
Cyclometalated Aryloxy(ch1oro)neopentylidenetungsten Complex: A
Highly Active and Stereoselective Catalyst for the Metathesis of cis- and trans2-Pentene, Norbornene, 1 -Methylnorbornene, and Ethyl Oleate (C) 628
- A Novel Pol oxotungstate Containing a
triangulo Ni;7Cluster with Ferromagnetic Exchange Interactions and an S = 3
Ground State (C) 649
- Assistance by Electrophiles in Photoinduced Alkylidyne-Carbonyl Coupling
( C ) 747
- Catecholates as o-and n-Donating Ligands: The Synthesis and Structure
of(Et,N),[W(CO),(O,C6H4)] and the
“Sixteen Electron” Analogue Resulting
from CO Dissociation (C) 1503
- Detection of the Tungsten-CarbeneOlefin Intermediates in Catalytic Metathesis Systems Containing High-Valent,
Metal Centers (C) 1585
- Hydride Transfer by Hydrido Transition-Metal Complexes. Ionic Hydrogenation of Aldehydes and Ketones,
and Structural Characterization of an
Alcohol Complex (C) 1233
- New Routes to Alkylidyne-Bridged Ditungsten Compounds Supported by
Alkoxide or Siloxide Ligands by the Activation of Ethylene (C) 462
- Novel Binuclear Phosphinidene Compounds by Dimerization of the P-HFunctional Phosphenium Complexes
[C,R,(CO),W = PH(Mes)] (R = H, Me)
(C) 1525
- Synthesis of Cubane-like and Double
Cubane-like Tungsten-Copper-Sulfur
Clusters from the “Butterfly” Cluster
[Cu,S,W(O)(PPh,),l (C) 1085
- Synthesis, Structure, and Bonding of
[CpCoW,(OCH,rBu),], and Comments
on the Combining Properties of CO and
CpCo (C) 896
-
+
Angex. Chem. Innt. Ed. Engl. 1992, 31. No. 12
- Unprccedented Stereospecific Ligand
Exchange at a W = W Template (C) 66
Tunichromes
- Structure of the Tunichrome of Tunicatcs and its Role in Concentrating
Vanadium (C) 52
Uranium compounds
- The Synthesis and Structure of an Unusual Uranium Pentachloride Derivative (C) 72
Urea derivatives
- A 1 : 1 Adducl of 2-Aminobenzothiazole
and a Urea Derivative, and Its Spatial
Arrangemcnt (C) 1634
Valence isomerization
How High is the Barrier for the Valence
Isomerization of Cyclobutadiene? (C)
738
Vanadium compounds
- A Novel Host/Guest System with a
Nanometer Large Cavitv for Anions
-
- New Directions in Polyvanadate Chemistry: From Cages and Clusters to Baskets. Belts. Bowls, and Barrels (H) 49
- (0rganoarsonato)polyoxovanadium
Clusters: Properties and Structures of
the V' Cluster [V,,0,,~03AsC,H,-4NH,),14- and the V' /Vv Cluster
[H,f~~O,,(O,AsC,H,),}]~-(C) 1197
- Pyridine-2-thiolato Comolexes of V".
V"', and V'" with Unusual Structural
Features (C) 1253
Structurc of the Tunichrome of Tunicates and its Role in Concentrating
Vanadium (C) 52
The First Complex with a 0*7c4 Triple
Bond between Vanadium Atoms in a
Ligand Framework of Fourfold Symmetry -[V,{(p-CH,C,H,)NC(H)N@-C,H,CHd;,l (C) 737
The First Structural Characterization of
a Metal-Entcrobactin Complex:
[V(enterobactin)]' (C) 466
~
~
~
Angel,.. Chwi. l i l t . Ed. EngI. 1992. 31. No. 12
Tris(cyc1opentanolato)oxovanadium(v): a Model for the Transition State
of Enzymatic Phosphoester Cleavage
(C) 447
- [V(SNC9H6),I and [V(SNH2C6H4)2(SNHC,H,)]-,
Homoleptic Vanadium(rrr) Complexes with Sulfur-Nitrogen
Donor Ligdnds, and [V(SNC,H,)J,
the First Thiolatovanadium(II) Complex
(C) 1366
Vinyldiazonium ions
- Origin of the Stabilization of Vinyldiazonium Ions by /I-Substitution; First
Crystal Structure of an Aliphatic Diazonium Ion: /I$-Diethoxyethenediazonium Hexachloroantimonate (C)
740
Vitamin B,,
- Radical Intermediates in the Coenzyme
B,, Dependent Methylmalonyl-CoA
Mutase Reaction Shown by ESR Spectroscopy (C) 215
Vitamin C
- Vitamin C : Its Chemistry and Biochemistry (B) 802
Changes in the Molecular Geometry on
Rotation about the Phosphorus-Carbon Ylide Bond (C) 99
-
Water
- The Structure of Water-A Mixture of
Cubes and Planar Four-Membered
Rings? (H) 1577
Wittig rearrangements
- [2,3] Wittig Rearrangements of Nonconjugated Secondary a-Lithioethers: Proof
of Stereospecificity and Inversion of the
Configuration of the Carbanion C
Atom (C) 647
Wood
- Wood and Cellulosic Chemistry (B) 801
Ylides
A Simple Method for the Replacement
of the OH Grouo in Free Carboxvlic
Acids by the Phosphonium Ylide Group
(C) 1064
- The Phosphorus Ylide CH,PH3 is
Stable in the Gas Phase (C) 86
- Three Independent Molecules in the
Unit Cell of a Phosphorus Ylide;
-
Zeolites
Introduction to Zeolite Science and
Practice (B) 661
- Solid-state NMR Soectroscooic and XRay Diffraction Siudies of the LowTemperature Structural Transformation
of Hvdrated Porous AluminoDhosDhate
VPI-3 (C) 610
- Zn,[PI2N,,]CI,-A
Sodalite with a
Phosphorus-Nitrogen Framework (C)
21 3
Zinc compounds
- A Phenoxy-Bridged Homodinuclear Zn
Complex with an Unusual Coordination
Sphere; Model Compound for the Active Site of Phospholipase C (C) 1647
- C-C Coupling with NOJAlkyl Substitution at the Vinylic Carbon by Reaction of 2-Aryl-I-nitro-1-alkeneswith
Dialkylzinc Compounds- A Novel Reaction (C) 1587
- Palladium(o)-Catalyzed Three-Component Coupling Reaction of Ally1 Benzoates, Carbon Monoxide, and Zincioesters (C) 645
- Zinc Pyrazolylborate Complexes Relevant to the Biological Function of Carbonic Anhydrase (C) 92
Zirconium compounds
A Structurally Distorted Ligand in an
Electron-Deficient Dizirconocene
Cation: Unusual 1,2- and 1,l-Dimetallioalkenes (C) 876
Cationic Metallocene Polymerization
Catalysts. Synthesis and Prooerties of
the First Base-Free Zirconoccne Hydride (C) 1375
Empty Octahedral
Hexazirconium
Clusters with Only Ten Electrons,
lZr,X,,(PR,),I (C) 1050
High Molecular Weight Polypropylene
through Specifically Designed Zirconocene Catalysts (C) 1347
~
I
1
1
1693
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