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Back Cover Diatomic [CuO]+ and Its Role in the Spin-Selective Hydrogen- and Oxygen-Atom Transfers in the Thermal Activation of Methane (Angew. Chem. Int. Ed. 212011)

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The
final puzzle piece …
… of the first-row transition-metal oxides has been found. In their Communication on
page 4966 ff., H. Schwarz et al. describe how more than ten years after its theoretical
prediction to serve as a powerful methane!methanol converter, the bare [CuO]+ cation
has been successfully generated in the gas phase. The crucial role of two-state reactivity
and the importance of oxygen-centered radicals for selectivity in the oxidation of
methane have been revealed by a combination of mass spectrometry and DFT
calculations.
Back Cover
Nicolas Dietl, Christian van der Linde, Maria Schlangen,
Martin K. Beyer, and Helmut Schwarz*
The final puzzle piece of the first-row transition-metal oxides has been found. In their
Communication on page 4966 ff., H. Schwarz et al. describe how more than ten years
after its theoretical prediction to serve as a powerful methane!methanol converter,
the bare [CuO]þ cation has been successfully generated in the gas phase. The crucial
role of two-state reactivity and the importance of oxygen-centered radicals for
selectivity in the oxidation of methane have been revealed by a combination of mass
spectrometry and DFT calculations.
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hydrogen, spina, thermal, selective, 212011, cuo, activation, diatomic, int, cover, angel, chem, atom, transfer, role, back, oxygen, methane
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