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Back Cover Double Switching of a Magnetic Coordination Framework through Intraskeletal Molecular Rearrangement (Angew. Chem. Int. Ed. 172011)

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The
reversible removal …
… of guest molecules in Mn2Nb magnetic coordination framework materials, as
described by D. Pinkowicz, B. Sieklucka et al. in their Communication on page 3973 ff.,
causes a spectacular two-step molecular rearrangement of their skeleton involving the
topotactic formation of an additional molecular bridge and the translocation of the
incorporated organic ligand. These structural changes impact the magnetic ordering
temperature and allow for its switching between 43, 68, and 100 K.
Back Cover
Dawid Pinkowicz,* Robert Podgajny, Bartłomiej Gaweł,
Wojciech Nitek, Wiesław Łasocha, Marcin Oszajca, Mariusz Czapla,
Magdalena Makarewicz, Maria Bałanda, and Barbara Sieklucka*
The reversible removal of guest molecules in Mn2Nb magnetic coordination
framework materials, as described by D. Pinkowicz, B. Sieklucka et al. in their
Communication on page 3973 ff., causes a spectacular two-step molecular
rearrangement of their skeleton involving the topotactic formation of an additional
molecular bridge and the translocation of the incorporated organic ligand. These
structural changes impact the magnetic ordering temperature and allow for its
switching between 43, 68, and 100 K.
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molecular, coordination, double, switching, int, framework, cover, angel, rearrangements, chem, magnetic, intraskeletal, 172011, back
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