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Back Cover Halogen-Bond-Induced Activation of a CarbonЦHeteroatom Bond (Angew. Chem. Int. Ed. 312011)

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Strong
halogen-bond donors …
… can be used to activate carbon–halogen bonds, and in the extreme case heterolytic
cleavage of the C X bond results. In their Communication on page 7187 ff., S. M. Huber
and co-workers report that activated benzhydryl bromide undergoes a Ritter-like
reaction with acetonitrile to give N-benzhydryl acetamide.
Back Cover
Sebastian M. Walter, Florian Kniep, Eberhardt Herdtweck, and
Stefan M. Huber*
Strong halogen-bond donors can be used to activate carbon–halogen bonds, and in the
extreme case heterolytic cleavage of the C X bond results. In their Communication
on page 7187 ff., S. M. Huber and co-workers report that activated benzhydryl
bromide undergoes a Ritter-like reaction with acetonitrile to give N-benzhydryl
acetamide.
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int, bond, cover, angel, induced, halogen, chem, activation, back, 312011, carbonцheteroatom
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