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Book Review Bindung Struktur und Reaktionsmechanismen in der organischen Chemie (Bonding Structure and Reaction Mechanisms in Organic Chemistry).

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The classification of individual substances as carcinogens,
mutagens, and/or teratogens appears somewhat questionable.
N o indication is given of the criteria for this classification in the
form of tables, though there are copious literature references.
However. a clear definition of such criteria is just what the
chemist needs ; for example, reference should have been
made to the ambiguity of mutagenicity tests in microorganisms. Formaldehyde is thus classified as a carcinogen,
which will hardly be subscribed to by an expert in chemical
carcinogenesis. The cytostatic Endoxan, on the other hand,
though undoubtedly carcinogenic, appears only as a mutagen
and teratogen. Nor does it seem consistent to exclude from
this volume the important class of carcinogenic polycyclic
hydrocarbons of the 3,4-benzpyrene type; these were left for
Volume 2.
Despite these minor defects the publication of this book should
be welcomed, since it makes the chemist familiar with toxic
pollutants and gives the biologist and the doctor an introduction to and directions for the determination of these substances.
It i s therefore hoped that the work will find widespread distribution.
Separation and Purification Methods, Vol. 2. Edited by E.
S. PKfTy, C. J . can Oss, and E. Grushka. Marcel Dekker,
New York 1974. xi, 466 pp., bound, 8 22.50.
Rudolf Preussrnnnn [NB 2231
Problems in Chemistry-Revised and Expanded. By H . 0.
Dakj., J r . and R. F. O’Malk!,. From the series “Undergraduate Chemistry”. Edited by J . J . Lagowski. Marcel Dekker,
New York 1974. xvii, 490 pp., stitched % 7.95.
Bindung, Struktur und Reaktionsmechanismen in der
organischen Chemie (Bonding, Structure and Reaction
SprinMechanisms in Organic Chemistry). By I L Ernest.
ger-Verlag, Vienna-New York 1972. 1st edit., x, 389 pp.,
6 figures, bound D M 98.-.
This work represents an attempt at summarizing the evergrowing field of physical organic chemistry. As a result
of its limited size some of the aspects are discussed in insufficient detail, but each chapter gives numerous refetences to
original papers, review articles, and monographs.
The book contains a brief introduction to the fundamental
concepts of molecular orbital theory, of the types of bonds
and stereochemistry, as well as a discussion of the charackristics and classification of organic reactions. Current methods
of investigation are cited. The core of the book consists of
the treatment of polar, radical, and orbital symmetry-controlled reactions: particularly the first two are discussed critically and in great detail. Recent views on reaction mechanisms,
K. $1. on Sh2 reactions, are also included. The chapter on multicenter reactions was deliberately kept brief by the author,
since several monographs have recently appeared on this subject.
The reviewer considers this to be a clear and didactically
well-written work. Only a few errors or obscurities have crept
in, as e.g. in the discussion on the resonance forms of
( , i s and rtans-butadiene (p. 22). Its study is specially recommended to undergraduates. In view of its high price, an inexpensive paperback edition would be welcome.
M . ?: Rerr.z [NB 226 IE]
Advances in Structure Research by Diffraction MethodsFortschritte der Strukturforschung mit Beugungsmethoden,
Vol. 5. Edited by W Hoppr and R. Mason. Pergamon Press,
New York/Friedr. Vieweg and Sohn, Braunschweig 1974.
120 pp., bound, DM 36.-.
Emulsions and Emulsion Technology, Part 1. Edited by K .
J . Lissattr. Vol. 6 of the series “Surfactant Science Series”.
Edited by M . J . Schick and F. M . Fowkes. Marcel Dekker,
New York 1974. xii, 440 pp., bound, 8 39.50.
Fluorocarbonand Related Chemistry, Vol. 2. Senior Reporters:
R. E. Bunkand M . G . Barlow. The Chemical Society, London
1974. viii, 491 pp., bound, .€16.00.-A volume of the series
“Specialist Periodical Reports”.
Synthetic Methods of Organic Chemistry, Vol. 28; Yearbook
1974. Edited by W Theilhrirnrr. S. Karger, Basel 1974.
xx.652 pp.,bound,DM 466.--.
Regulation of Porphyrin and Heme Biosynthesis. Edited by
M . Doss. Proceedings of the International Research Conference on Regulation of Porphyrin and Heme Biosynthesis,
Marburg 1973. S. Karger, Basel 1973. xv, 508 pp., DM
Functional Monomers, Vol. 2. Edited by R. H . Rxtrtrt and
E. B. N y p i s r . Marcel Dekker, New York 1974. x, 817
pp., bound, f 25.50.
Raman/IR Atlas organischer Verbindungen, Vol. 1. Published
under the auspices of the Institut fur Spektrochemie und
Angewandte Spektroskopie, Dortmund. Edited by B.
Schradrr and W Meier. Verlag Chemie, Weinheim 1974.
xvii, xxxi pp.. 300 Spectra, loose-leaf. Subscription price:
DM 690.--, final price: DM 795.-.
Gmelins Handbuch der anorganischen Chemie. Supplemented
8. Edition. Vol. 14: Eisen-organische Verbindungen, Part
A: Ferrocen 1. Springer-Verlag, Berlin 1974. vi, 395 pp.,
bound, DM 516.--.
’ ‘C-NMR
Spectroscopy. Methods and Applications. By E.
Breitmairr and W Voelter, Vol. 5 of the series “Monographs
in ModernChemistry”. Edited by H . F. E h d Verlag Chemie,
Weinheim 1974. xiii, 303 pp., bound, DM 98.-.
Methoden der Analytischen Chemie. Eine Einfuhrung. Vol. 1 :
Trennungsmethoden. By R. Bock. Verlag Chemie, Weinheim
1974. 362 pp., bound, DM 42.-.
Angrw. Chem inrrmar. Edit.
1 Vol 13 (1974) 1 No. / I
Stromung und Stoffaustausch in Fiillkorperapparaten bei Gegenstrom einer fliissigen und einer gasformigen Phase. By
W Rrichrlf. From the series “Reprotext”-spezielle naturwissenschaftliche und technische Texte in Direktreproduktion. Verlag Chemie, Weinheim 1974. 261 pp., stitched, DM
Plutonium-A General Survey. By M . Tatrbe. Vol. 4 of the
series “Kernchemie in Einzeldarstellungen”. Verlag Chemie,
Weinheim 1974. xii, 242 pp., bound, DM 88.-.
Reactive Intermediates in Organic Chemistry. By N . S. Isaacs.
John Wiley & Sons, London 1974. xiii, 550 pp., bound,
E 12.00.
Lehrhuch der Organischen Chemie. By R . 7: Morrison and
R. N . B o ~ d .Verlag Chemie, Weinheim 1974. xxviii, 1349
pp., bound, DM 78.--.
Polymer Synthesis, Vol. 1. By S. R . Sandler and W Karo.
Vol. 29-1 ofthe series “Organic Chemistry”. Academic Press,
New York 1974, x, 572 pp., bound, S 39.50.
The Organic Chemistry of Nickel. Vol. I : Organonickel Complexes. By P . W Jollj. and G . Wilke. Academic Press, New
York 1974. xiv, 517 pp., bound, f6 58.00.
An IntrUduction to X-Ray Spectrometry. By R . Jenkins. Heyden
& Son, London 1974. xi, 163 pp., bound, f 5.00.
Photochemistry.An Introduction. By D. R . Arnold, N . C. Baird,
J . R . Bolton, J . C. D. Brand, P . W M . Jacobs, P . d e Mayo,
and W R . Ware. Academic Press, New York 1974. vii, 283
pp.. bound, $ 15.00.
NMR Basic Principles and Progress. Grundlagen und Fortschritte. Edited by P . Diehl, E. Fluck, and R . Kosjeld. Vol.
8 : “Chemically Induced Dynamic Nuclear and Electron
Polarizations-CIDNP and CIDEP’. By C. Richard and
P . G r a n p r . Springer-Verlag, Berlin 1974. II, 127 pp., bound,
DM 58.--.
Anwendung von Isotopen in der Organischen Chemie und Biochemie. Edited by H. Simon. Vol. 11: Messung von radioaktiven und stabilen Isotopen. By P . Ruuschenbach, H.-L.
Schmidt, H. Simon, R . Tykca, and M . Wenzel. Springer-Verlag, Berlin 1974. xii, 430 pp., bound, DM 98.--.
Neuere Fortschritte der Fliissig-Fliissig-Extraktion. Edited by
C. Hanson. From the series “Grundlagen der chemischen
Technik”. Edited by H. Mohier, 0. Fuchs, H . Kraussold,
and K . Dialer. Verlag Sauerliinder, Aarau 1974. 576 pp.,
bound, DM 160.--.
Handbuch der Spurenanalyse. Die Anreicherung und Bestimmung von Spurenelementen unter Anwendung chemischer,
physikalischer und mikrobiologischer Verfahren. In two
parts. By 0. G. Koch and G . A. Koch-Dedic. Springer-Verlag,
Berlin 1974. 2., completely revised and supplemented edit.
xxiv, xiii, 1597 pp., bound, DM 498.--.
Die Evolution des Menschen. By E. Steitz. Vol. 16 of the
series “Taschentext”. Verlag Chemie/Physik-Verlag, Weinheim 1974. xi, 221 pp., stitched, DM 19.80.
RPebtandsanalytik von Pflanzenschutzmitteln. Mitteilung VI
der Kommission fur Pflanzenschutz-, Pflanzenbehandlungsund Vorratsschutzmittel der Deutschen Forschungsgemeinschaft. 3. instalment 1974. Verlag Chemie, Weinheim. xliii,
164 pp., Loose-leaf collection, DM 68.--.
Electronic Structure and Magnetism of Inorganic Compounds,
Vol. 3. Senior Reporter: P . Day. The Chemical Society,
London 1974. xi, 433 pp., bound, E 14.00.-A volume of
the series “Specialist Periodical Reports”.
An Introduction to Biochemical Reaction Mechanisms. By J .
N . Lowe and L. L. Ingraham. From the series “Foundations
of Modern Biochemistry Series”. Prentice-Hall, Inc., Englewood Cliffs 1974. xiv, 145 pp., bound, E 5.20.
Advances in Chromatography, Vol. 10. Edited by J . Calcin
Giddings and R . A. Keller. Marcel Dekker, Inc., New York
1974. xi, 246 pp., bound, % 19.75.
Ammonia, Part 11. Edited by A. 1/: Slack and G. R . James.
From the series “Fertilizer Science and Technology Series”.
Edited by A . P! Slack. Marcel Dekker, Inc., New York
1974. xiii, 354 pp., bound, 8 37.50.
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Angew. Chem. internat. Edit. 1 Vol. 13 ( 1 9 7 4 ) No. I1
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