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Cover Picture Lock-and-Key Principle on a Microscopic Scale The Case of the Propylene OxideEthanol Complex (Angew. Chem. Int. Ed. 132007)

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Cover Picture
Nicole Borho and Yunjie Xu*
The lock-and-key principle is illustrated on a microscopic scale by the binding
between propylene oxide (PO) and ethanol. PO acts as a rigid lock and EtOH offers
keys in the form of the gauche, gauche þ , and trans conformers. In their
Communication on page 2276 ff., N. Borho and Y. Xu use rotational spectroscopy and
ab initio calculations to analyze the six possible hydrogen-bonded conformers (three
of which are shown in the cover picture) of the 1:1 PO···EtOH molecular complex.
Magnetic Materials
In the Review on page 2152 ff., O. Sato et al. give an overview of magnetic
materials whose properties can be switched through external stimuli. The principal
focus is on valence-tautomeric compounds, molecular magnets, and spin-crossover
complexes.
Silver(I) Complexes
A silver(I) ethylene complex and the first classical silver(I) carbonyl adduct have
been isolated using a scorpionate ligand as described by H. V. Rasika Dias and M.
Fianchini in their Communication on page 2188 ff.
Drug Delivery
The photodynamic therapy agent mTHPC is encapsulated in polyacrylamide-based
nanoparticles. The phototoxicity of the free and nanoparticle-encapsulated mTHPC
on cancer cells is evaluated by R. Kopelman and co-workers in their
Communication on page 2224 ff.
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oxideethanol, lock, complex, propylene, 132007, scala, int, cover, angel, chem, microscopy, key, case, picture, principles
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