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Cover Picture Molecular Mousetraps Gas-Phase Studies of the Covalent Coupling of Noncovalent Complexes Initiated by Reactive Carbenes Formed by Controlled Activation of Diazo Precursors (Angew. Chem. Int. Ed. 92003)

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Cover Picture
Wei Sun, Hongwang Wang, Chungu Xia,* Jingwei Li, and Peiqing Zhao
Molecular mousetraps are an unprecedented class of host–guest reagents. In the
example shown in the cover picture, 18-crown-6 ether is utilized as the “bait” to attract
target molecules with a protonated primary amine functional group. Appropriate
activation of the noncovalent complex springs the diazo “trap”, which leads to covalent
attachment of the two molecules depicted in the reaction scheme. The research is
detailed in the Communication by J. L. Beauchamp, B. M. Stoltz et al. on page 1012 ff.
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mousetraps, 92003, molecular, couplings, activation, gas, former, complexes, reactive, noncovalent, phase, int, cover, angel, chem, controller, covalent, precursors, picture, diaz, carbenes, studies, initiate
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