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Cover Picture Sensitive and Selective Chromogenic Sensing of Carbon Monoxide by Using Binuclear Rhodium Complexes (Angew. Chem. Int. Ed. 292010)

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D 3461
www.angewandte.org
2010–49/29
Hybrid Nanostructures
U. Banin et al.
Silicon Chemistry
T. Müller and C. Gerdes
Vinylcyclopropane–Cyclopentene Rearrangement
T. Hudlicky and J. W. Reed
ACIEFS 49 (29) 4839–5012 (2010) · ISSN 1433–7851 · Vol. 49 · No. 29
Cover Picture
Julio Esteban, Jos Vicente Ros-Lis, Ramn Martnez-MÇez,*
M. Dolores Marcos, Mara Moragues, Juan Soto, and Flix Sancenn
Like in a collage by Max Ernst, a combination of a known molecular entity (a
binuclear rhodium complex) and suitable bridging ligands can take on a new role as a
chromogenic chemosensor. R. Martnez-MÇez and co-workers describe in their
Communication on page 4934 ff. how the color change these complexes undergo
allows them to act as a carbon monoxide sensor.
Vinylcyclopropane–Cyclopentene Rearrangement
The Essay by T. Hudlicky and J. W. Reed on page 4864 ff. shows the origin of the
vinylcyclopropane–cyclopentene rearrangement. The authors describe from their
experiences the influence of such rearrangements of the development of naturalproduct syntheses.
Colloidal Nanostructures
By combining metallic, semiconducting, and magnetic domains to give hybrid
nanoparticles, nanomaterials with multiple functionalities can be obtained. U. Banin
et al. describe in their Review on page 4878 ff. the synthesis, properties, and
applications of such particles.
Proton Migration
The “catch-and-release” action of a catalytic water molecule in the keto–enol
tautomerization of the acetone cation is described by Y. Matsuda, A. Fujii, and coworkers in their Communication on page 4898 ff.
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using, chromogenic, selective, rhodium, complexes, binucleata, int, cover, angel, monoxide, chem, sensing, 292010, picture, sensitive, carbon
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