Cover Picture Supramolecular Coordination Assemblies of Dinuclear FeIII Complexes (Angew. Chem. Int. Ed. 272005)код для вставкиСкачать
Cover Picture Wolfgang Schmitt,* Jonathan P. Hill, M. Paula Juanico, Andrea Caneschi, Ferdinando Costantino, Christopher E. Anson, and Annie K. Powell* Busy bees may also find the honeycomb networks shown in the cover picture attractive. The networks are based on dinuclear FeIII subunits, aminocarboxylic acid ligands, and potassium counterions. The properties of the hydrophobic organic ligands strongly influence the structure of the hydrophilic inorganic zone which in turn affects the overall structure of the supramolecular assemblies. For more information on this approach see the Communication by W. Schmitt, A. K. Powell, and co-workers on page 4187 ff. Inhibitor Design Modulators of protein–protein interactions are promising drug candidates in pharmaceutical research. In their Review on pp. 4130 ff., A. D. Hamilton and H. Yin discuss current strategies in combinatorial searches and in the rational design of such compounds. Conducting Materials In their Communication on page 4164 ff. M. Mitsumi, K. Toriumi, et al. report the spectroscopic and crystallographic properties of a highly conductive mixed-valence rhodium(i,ii) semiquinonato/catecholato complex. Molecular Motors Synthetic DNA-based molecules based on the example of Kinesin are capable of moving across a surface in a particular direction. This topic is explored in the Highlight by T. R. Kelly on page 4124 ff.