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Cover Picture Wacker-Type Oxidation of Internal Olefins Using a PdCl2N N-Dimethylacetamide Catalyst System under Copper-Free Reaction Conditions (Angew. Chem. Int. Ed

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D 3461
DNA---Protein Conjugates
C. M. Niemeyer
Enantioselective Conjugate Borylation
M. Oestreich et al.
RNA Sequencing
S. Müller
ACIEFS 49 (7) 1169–1332 (2010) · ISSN 1433–7851 · Vol. 49 · No. 7
Cover Picture
Takato Mitsudome, Keiichi Mizumoto, Tomoo Mizugaki,
Koichiro Jitsukawa, and Kiyotomi Kaneda*
A Wacker-type oxidation of internal olefins into ketones is described by K. Kaneda
and co-workers in their Communication on page 1238 ff. The reaction proceeds under
an atmosphere of O2 in the presence of a homogeneous palladium catalyst with water
as the oxygen source. Artistically, the reaction is depicted as moving through an hour
glass as the reactants are transformed into product.
DNA–Protein Conjugates
DNA–protein conjugates combine the self-assembly properties of nucleic acids with
the large repertoire of protein functionality. C. M. Niemeyer describes in his
Review on page 1200 ff. how such conjugates can be prepared and what
applications they have.
In their Communication on page 1218 ff., M. E. van der Boom et al. report the
assembly of gold nanoparticles with a series of pyridyl-containing linkers. The
molecular geometries of the linkers are expressed in the structural and optical
properties of the AuNP assemblies.
Chemical Dynamics
S. Lee, Y. S. Choi, S. K. Kim et al. describe in their Communication on page 1244 ff.
the photodissociation of diazirine in the S1 state in which the two C N bonds of the
excited diazirine break in a stepwise manner.
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using, reaction, typed, system, interna, int, oxidation, cover, angel, chem, free, pdcl2n, dimethylacetamide, olefin, wacker, picture, conditions, coppel, catalyst
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