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Inside Cover A Synthetic Analogue of Rieske-Type [2Fe-2S] Clusters (Angew. Chem. Int. Ed. 492008)

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Iron–sulfur
proteins …
… of the Rieske type contain a redox-active [2Fe-2S] site that can be described as a
variant of the related ferredoxins, but with unsymmetrical Cys2His2 coordination. This
unusual Fe/S cluster could now be emulated in a synthetic model for the first time, using
relatively simple ligands. In their Communication on page 9537 ff., F. Meyer and coworkers report the successful synthesis as well as the spectroscopic and structural characterization of the biomimetic analogue, which was also analyzed by DFT calculations.
Inside Cover
Joachim Ballmann, Antonia Albers, Serhiy Demeshko,
Sebastian Dechert, Eckhard Bill, Eberhard Bothe, Ulf Ryde, and
Franc Meyer*
Iron–sulfur proteins of the Rieske type contain a redox-active [2Fe-2S] site that can
be described as a variant of the related ferredoxins, but with unsymmetrical Cys2His2
coordination. This unusual Fe/S cluster could now be emulated in a synthetic model
for the first time, using relatively simple ligands. In their Communication on
page 9537 ff., F. Meyer and co-workers report the successful synthesis as well as the
spectroscopic and structural characterization of the biomimetic analogue, which was
also analyzed by DFT calculations.
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synthetic, int, cover, angel, clusters, chem, 2fe, rieske, 492008, insider, typed, analogues
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