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Inside Cover An Isolable and Monomeric Phosphorus Radical That Is Resonance-Stabilized by the Vanadium(IVV) Redox Couple (Angew. Chem. Int. Ed. 172007)

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Inside Cover
Paresh Agarwal, Nicholas A. Piro, Karsten Meyer, Peter Mller, and
Christopher C. Cummins*
Bulky redox-active metalloligands stabilize the phosphorus radical [CP{N¼
V[N(Np)Ar]3}2] (Np=neopentyl) to the extent that it exists as a monomer even in the
solid state. C. C. Cummins and co-workers describe in their Communication on
page 3111 ff. the EPR spectrum of the radical (see picture; P orange, N blue,
V yellow), which reveals delocalization of the unpaired electron onto both vanadium
centers. Radical bond formation at the phosphorus atom leads to diamagnetic
products.
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stabilizer, ivv, radical, isolable, int, cover, angel, monomeric, 172007, chem, redox, insider, resonance, coupled, vanadium, phosphorus
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