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Inside Cover Challenging the Metallocene Dominance in Actinide Chemistry with a Soft PNP Pincer Ligand New Uranium Structures and Reactivity Patterns (Angew. Chem. Int. Ed. 202009)

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A. standing iceberg …
… illustrates how the soft PNP pincer ligand challenges the metallocene dominance
(ship) in actinide chemistry, as described by J. L. Kiplinger and co-workers in their
Communication on page 3681 ff. Replacement of C5Me5 by the PNP ligand is a successful strategy for the promotion of new reactivities and to support new actinide
structures. The specific electronic and steric properties of the PNP ligand enable access
to structures not available for the C5Me5 ligand set and as yet unreported for uranium.
(We thank Mr. Anthony Mancinco for the design of the graphic.)
Inside Cover
Thibault Cantat, Christopher R. Graves, Brian L. Scott, and
Jaqueline L. Kiplinger*
A standing iceberg illustrates how the soft PNP pincer ligand challenges the
metallocene dominance (ship) in actinide chemistry, as described by J. L. Kiplinger
and co-workers in their Communication on page 3681 ff. Replacement of C5Me5 by
the PNP ligand is a successful strategy for the promotion of new reactivities and to
support new actinide structures. The specific electronic and steric properties of the
PNP ligand enable access to structures not available for the C5Me5 ligand set and as
yet unreported for uranium. (We thank Mr. Anthony Mancinco for the design of the
graphic.)
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actinide, dominance, reactivity, uranium, new, ligand, chemistry, pnp, pincer, int, cover, structure, angel, challenging, patterns, chem, metallocene, insider, soft, 202009
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