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Inside Cover Control of Intramolecular Orbital Alignment in the Photodissociation of Thiophenol Conformational Manipulation by Chemical Substitution (Angew. Chem. Int. Ed. 102008)

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Conformational
control by chemical substitution …
… influences the content of the wavepacket propagating along the S H coordinate of
thiophenol. The wide spread of the wavepacket at the conical intersection, induced by
the conformation of the S H torsional angle, diminishes the probability of diabatic
passage, thus giving control over the branching ratio of excited and ground states of
product. In the Communication on page 1853 ff., S. K. Kim and co-workers describe this
approach to control intramolecular orbital alignment for the phenylthiyl radical.
Inside Cover
Jeong Sik Lim, Yoon Sup Lee, and Sang Kyu Kim*
Conformational control by chemical substitution influences the content of the
wavepacket propagating along the S H coordinate of thiophenol. The wide spread of
the wavepacket at the conical intersection, induced by the conformation of the S H
torsional angle, diminishes the probability of diabatic passage, thus giving control over
the branching ratio of excited and ground states of product. In the Communication on
page 1853 ff., S. K. Kim and co-workers describe this approach to control
intramolecular orbital alignment for the phenylthiyl radical.
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substitution, intramolecular, alignment, photodissociation, manipulation, orbital, control, conformational, int, cover, angel, chemical, 102008, chem, thiophene, insider
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