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Inside Cover Distance-Independent DNA Charge Transport across an Adenine Tract (Angew. Chem. Int. Ed. 302007)

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Inside Cover
Katherine E. Augustyn, Joseph C. Genereux, and Jacqueline K. Barton*
DNA-mediated charge transport across adenine tracts was monitored by using a fast
radical probe that is part of the bridge (N6-cyclopropyladenine, blue). As described by
J. K. Barton and co-workers in their Communication on page 5731 ff., this trap,
placed at each base across the A tract, is oxidized by the distal rhodium photooxidant
(orange) with equal yield over a distance of 5 nm. These results are consistent with
complete charge delocalization across the DNA bridge.
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302007, adenine, acros, dna, independence, distance, int, cover, angel, chem, transport, trace, insider, charge
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