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Inside Cover Lewis Base Induced Reductions in Organolanthanide Chemistry (Angew. Chem. Int. Ed. 142010)

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C. H activation and reduction …
… are both apparent in the reaction of [SmIII(AlMe4)3] with the heterocycle (CyNCH2)3
(Cy = cyclohexyl). As shown by N. W. Mitzel and co-workers in their Communication on
page 2611 ff., C H bonds of methyl groups are activated to form a carbyne complex with
an {(HC)Al3Sm} unit, and spontaneous reduction to samarium(II) by methyl groups can
also be observed.
Inside Cover
Daniel Bojer, Ajay Venugopal, Beate Neumann, Hans-Georg Stammler,
and Norbert W. Mitzel*
CH activation and reduction are both apparent in the reaction of [SmIII(AlMe4)3]
with the heterocycle (CyNCH2)3 (Cy ¼ cyclohexyl). As shown by N. W. Mitzel and coworkers in their Communication on page 2611 ff., CH bonds of methyl groups are
activated to form a carbyne complex with an {(HC)Al3Sm} unit, and spontaneous
reduction to samarium(II) by methyl groups can also be observed.
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base, chemistry, int, cover, angel, induced, organolanthanoid, chem, 142010, reduction, insider, lewis
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