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Inside Cover Massadine Chloride A Biosynthetic Precursor of Massadine and Stylissadine (Angew. Chem. Int. Ed. 352007)

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Inside Cover
Achim Grube, Stefan Immel, Phil S. Baran,* and Matthias Kck*
The dimeric pyrrole–imidazole alkaloid massadine chloride was isolated from the
Caribbean sponge Stylissa caribica. M. Kck, P. S. Baran, and co-workers describe in
their Communication on page 6721 ff. how they were able to elucidate the structure
of this natural product. The compound was unambiguously demonstrated to be the
biosynthetic precursor of massadine. Results of experiments and calculations give
evidence that the biosynthesis of other complex pyrrole–imidazole alkaloids run
through a common intermediate.
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int, biosynthetical, cover, angel, chem, stylissadine, 352007, massadine, insider, precursors, chloride
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