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Inside Cover Spirocyclic Oxetanes Synthesis and Properties (Angew. Chem. Int. Ed. 242008)

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.
Star
constellations …
… like atom positions, suggest connectivity; in place of Orion, piperidone is imagined,
and its superimposition with “homospiromorpholine”, described by G. Wuitschik et al.
in their Communication on page 4512 ff., is remarkable. Stimulated by the analogy
between the van't Hoff description of a ketone and an oxetane, spirocyclic oxetane
amines—analogues of ketoamines, lactams, and morpholine with a systematically
reclined polar ether unit—are explored.
Inside Cover
Georg Wuitschik, Mark Rogers-Evans,* Andreas Buckl,
Maurizio Bernasconi, Moritz Mrki, Thierry Godel, Holger Fischer,
Bjçrn Wagner, Isabelle Parrilla, Franz Schuler, Josef Schneider,
Andr* Alker, W. Bernd Schweizer, Klaus M.ller,* and
Erick M. Carreira*
Star constellations like atom positions, suggest connectivity; in place of Orion,
piperidone is imagined, and its superimposition with “homospiromorpholine”,
described by G. Wuitschik et al. in their Communication on page 4512 ff., is
remarkable. Stimulated by the analogy between the van't Hoff description of a ketone
and an oxetane, spirocyclic oxetane amines—analogues of ketoamines, lactams, and
morpholine with a systematically reclined polar ether unit—are explored.
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int, 242008, cover, angel, synthesis, properties, chem, spirocyclic, oxetanes, insider
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