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Inside Cover УConformationalФ Solvatochromism Spatial Discrimination of Nonpolar Solvents by Using a Supramolecular Box of a -Conjugated Zinc Bisporphyrin Rotamer (Angew. Chem. Int. Ed. 282008)

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Conformational
solvatochromism …
… has been used to discriminate nonpolar solvents by using a self-assembled chromophoric molecule. A. Tsuda, T. Aida, and co-workers describe in their Communication on
page 5153 ff. the self-assembly of a bis(zinc pyridylporphyrin) rotamer with a p-conjugated linker to give a mixture of supramolecular boxes composed of planar and perpendicular conformers. The ratio of the two boxes changes depending on the solvent,
and leads to a solvatochromic response.
Inside Cover
Junko Aimi, Yuka Nagamine, Akihiko Tsuda,* Atsuya Muranaka,
Masanobu Uchiyama, and Takuzo Aida*
Conformational solvatochromism has been used to discriminate nonpolar solvents by
using a self-assembled chromophoric molecule. A. Tsuda, T. Aida, and co-workers
describe in their Communication on page 5153 ff. the self-assembly of a bis(zinc
pyridylporphyrin) rotamer with a p-conjugated linker to give a mixture of
supramolecular boxes composed of planar and perpendicular conformers. The ratio of
the two boxes changes depending on the solvent, and leads to a solvatochromic
response.
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using, box, solvatochromie, 282008, bisporphyrin, zinc, spatial, уconformationalф, int, cover, angel, discrimination, chem, supramolecular, conjugate, solvents, insider, rotamer, nonpolar
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