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Subject Index 1985.

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SUBJECT I N D E X
(R)
=
Review Article (C)
=
Short Communication
(B)
=
Book Review
dation of anthracene and 9,9’-bianthryl to
ABSOLUTE CONFIGURATION, On the Alkylbis(cyclopentadienyl)lanthanides, The
the respective dication and tetracation (C)
absolute configuration of (+)-tartaric
cleavage of tris(cyclopentadieny1)lantha508
acid (C) 513
nide complexes with alkyllithium comAnthracenides, Synthesis and structure of
ACC, Cyclopropyl-substituted aminocyclopounds-a new route to alkylbis(cyc1o1,4-dimethylanthracenemagnesium~3 thf
propane carboxyIic acid (cyclopropyl
pentadieny1)lanthanides ( C ) 225
and
p-trichlorodimagnesium ‘6thf( I + )
ACC)-an investigation of the mecha- Alkyl sulfides A novel rearrangement in
anthracenide (C) 960
nism of ethylene biosynthesis (C) 1044
(R2S...SR2)d-radical cations with a 3eAntibiotics, Molecular mechanism of action
Acetal reduction, Catalyzed acetal reduction
bond (C) 73
of the antibiotic rifampicin (R) 1009
with >BH boranes- 1-0-alkyl(ary1)aldi- Alkyl transition-metal compounds, OxidaRecent developments in the field of p-lactols, anhydroalditols, and 1-0-alditylaldition of organometallic compounds (R)
tam antibiotics (R) 180
tols from 0-glycopyranosides (C) 519
274
Antibodies, Increased production of specific
Acetals, Bicyclic acetals from oxacarbenes Alkynylcyclopropanes, New donor-substituantibodies by presentation of the antigen
(C) 1043
ted vinyl- and alkynylcyclopropanes as
determinants with covalently coupled lipoAcetylene-oxo complexes of tungsten, Nisynthetic building blocks (C) 770
peptide mitogens (C) 872
trogen monoxide as a source for 0x0 Allene Claisen rearrangement with 1,CchiralMonoclonal antibodies: their chemistry,
ligands-acetylene-oxo
complexes of
ity transfer (C) 700
functions, and possible uses (R) 139
Allene isoester, 9-Fluorenylidene-2,2,6,6-te- Antibody structure, From the structure of
tungsten (C) 497
Acetylneuraminic acid, Preparation of an Ntramethylpiperidinoborane: an allene isoantibodies to the diversification of the imester with two-coordinated boron and
acetylneuraminic acid-containing trisacmune response (Nobel lecture) (R) 816
B = C double bond (C) 416
charide and its use in oligosaccharide synAnticancer target enzyme, Chemical basis of
Allenes in organic syntheses (B) 1074
theses (C) 128
the action of glyoxalase I, an anticancer
Novel retro-ene reactions of P-hydroxyAcrylamides, CC Bond formation of alkenes
target enzyme (R) 31
acetylenes (C) 783
with isocyanates on Nio complexes-a
Antigens, Synthesis of the immunologically
Allylamines, Bis[(R)-(+)-binap]rhodium(~)
new synthesis of acrylamides (C) 325
essential saccharide sequence of the “entperchlorate, a highly efficient catalyst for
Acycloguanosine, A nucleolipid with antivierobacterial common antigen” (C) 773
the asymmetric isomerization of allylamiral acycloguanosine as head group-synAntipyrine, Electrochemical methoxylation
nes (C) 217
thesis and liposome formation (C) 501
of antipyrine (C) 864
Acylsilanes via oxidation of phosphonium Allylation of aldehydes with etherification
Arenes, Arene complexes of univalent galliby dialkoxydichlorotitanium/allyltrimethylides: the first synthesis of bis(trimethy1um, indium, and thallium (R) 893
ylsilane; an asymmetric variant of the Sasily1)ketone and its use as an equivalent of
A three-blade propeller compound with
kurai reaction (C) 765
the dianion COZe (C) 1068
seven bracketed benzene rings (C) 222
Addition, 1,4-Addition of dihalocarbenes to Allyl bridges, Dinuclear nickel complexes
(Arene)thallium
complex,
[(1,3,5with bridging allyl ligands (C) 704
1,3-dienes (C) 585
(CH3)3H3C6)6T14][GaBr4]4-~ynthe~i~
and
Allyl moieties, Cationic allylruthenium com1.4-Additions of dihalocarbenes (C) 579
structure of a mixed mono- and bis(areplexes via interchange of allyl moieties
2,3-Dilithio- 1,3-butadienes via addition of
ne)thallium complex (C) 414
(C) 347
lithium to butatrienes (C) 571
Synthesis of the first linear (o-phenylPhotochemical synthesis of an L-erythrose q3-Allylpalladium compounds (R) 283
eno)naphthalenes; a new class of benzenoid aromatics (C) 114
building block and its use in the prep- Allylruthenium complexes, Cationic allylruthenium complexes via interchange of
Arenium ions, Proton exchange between
aration of methyl 2,3, O-isopropylidene-pallyl moieties (C) 347
arenium ions and arenes in the gas phase
L-apio-L-furanoside (C) 877
(C) 693
Reaction of small molecules with the binu- Ambident anions (B) 234
Aromaticity, Synthesis of cyclohepta[a]pheclear complex [(p-C5H5)(p-Br)Pd2(PR3)2]: Ambident ligands, d6-Metal complexes of
4,4’-bipyrimidine, an ambident ligand
nalene-6,12-dione (C) 757
addition without cleavage of the metalSynthesis of dipleiadiene by “serendipity”
with high n-acceptor ability (C) 430
metal bond (C) 516
(C) 1046
Stereoselective nucleophilic additions to a Amino acids, Chiral copper(I1) complexes
Arsacyclopropanes, The first arsirane (C)
for the enantioselective resolution of DLbicyclic ketone controlled by a remote tri419
dansyl-amino acids by HPLC (C) 336
carbonyl(diene)iron moiety (C) 787
Arsanetriyl compounds, Synthesis and strucAggregation, On the aggregation of lithiated Aminocyclopropane carboxylic acid, Cyclopropyl-substituted
aminocyclopropane
ture O f [(C,H,)3M,(CO)6(~3,-As)](M = Mo,
bicyclobutane derivatives in solution (C)
W), transition-metal-stabilized arsanetriyl
carboxylic acid (cyclopropyl ACC)-an
404
investigation of the mechanism of ethylcompounds (C) 66
Alditols, Catalyzed acetal reduction with
ene biosynthesis (C) 1044
Synthesis and structure of the spirocluster
>BH
boranes- 1-0-alkyl(aryl)alditols,
anhydroalditols, and 1-0-alditylalditols Amino(imin0)phosphanes as face-bridging
[(r15-C,H5)3M03AS(C0)6(CHP(CsHs),tl
(c)
702
complex ligands (C) 115
from 0-glycopyranosides (C) 519
Arsenic-sulfur
ligands,
Synthesis
of
Chelate ligand-controlled q’-q2 change of
Aldol additions, Enantio- and nnti-diaste[(C5Me5)2M02XS3Co(CO)2]
clusters (X =
coordination in amino(imino)phosphane
reoselective aldol additions of acetates
ligands and their conversion into a nickelP,As) and structural characterization of a
and propionates via 0-silyl ketene acetals
aazadiphosphetidine (C) 525
k2,q2-AsSligand (C) 132
(C) 874
Arsirane, The first arsirane (C) 419
Aldosterone, “Dimers” of aldosterone (C) a-Amino phosphonic acids, Asymmetric adArynezirconocene, Reaction of thermally
dition of a chiral cyclic phosphite to a cy130
generated (q2-aryne)zirconocene with
Alkali metal/aluminum oxide, Catalytic
clic imine-synthesis of a phosphonic
W(CO),, a novel route to carbene comtransformations of sesquiterpene hydroacid analogue of D- and L-penicillamine
plexes (C) 584
carbons on alkali metal/aluminum oxide
(C) 1067
Asa, Asymmetric synthesis of (R)-p-(AlkoxyAnalytical chemistry, Great fear of small
(C) 320
carhony1)aspartic diesters (derivatives of
amounts of elements-the significance of
Al koxy-1,6-methano[ I OJannulenes, Coup(R)-asa) with a chiral cationic amino acid
analytical chemistry in our modern induling of
3-diazo-3H-pyrazoles
with
synthon (C) 1066
strialized community as exemplified by
2-alkoxy-1,6-methano[lO]annulenes and
Aspartic diesters, Asymmetric synthesis of
trace element analysis (R) 485
oxidative cyclization to pyrazolotriazines
Analytical methods, Combination of chro( R)-p-(A1koxycarbonyl)asparticdiesters (de(C) 346
matographic separation methods with
rivatives of (R)-asa) with a chiral cationic
Alkylation, Regiospecific a-alkylation of amass spectrometry-a modern technique
amino acid synthon (C) 1066
haloalkylidenamines (“a-haloketimines”)
Aspicilin, The structure of the lichen macro( C ) 881
for studying metabolism (R) 451
lide (+)-aspicilin (C) 987
Strongly preferential alkylation and car- Anodic oxidation, Oxidation of 2-propanol
at Ti/Cr2O3 anodes (C) 1049
Association, Crystal and solution structures
bonyl olefination of a-and P-hydroxycarSelectivity
of
the
anodic
oxidation
of
of [tBu2C= NLi .O = P(NMe2),]. (C) 328
CHbonyl compounds by organo-transition
and CH,-Groups: selective oxidation of
Pentamethyldiethylenetriamine(phenyl)limetal reagents in competition experithium, a monomeric organolithium comsteroids at C-6 (C) 1055
ments with the corresponding deoxy comAnthracene dication, Electrochemical oxipound (C) 215
pounds (C) 348
1080
Angew. Chem. Int. Ed. Engl. 24 (19XSJ No. I 2
with activated C-H
bonds: building
blocks for multilayered sandwich compounds (R) 943
Boron-nitrogen double bond, Hydroboration and hydrozirconation of tert-butylimino-2,2,6,6-tetramethylpiperidinoborane (C) 998
Boron-nitrogen stannocene, Bis(dihydr01,2-azaboroly1)tin-a novel boron-nitrogen stannocene (C) 602
Branched-chain sugars, Synthesis of 3’-Cmethyl-2‘-deoxyribonucleoside with methylmagnesium iodide (C) 52
Bridge-formation, First sixfold bridge-formation in one step (C) 794
Bridge ligands, Amino(imin0)phosphanes as
1
face-bridging complex ligands (C) 115
Cyanogen as a bridging ligand-preparaAsymmetric synthesis of (R)-P-(Alkoxycartion and crystal structure of polymeric
bony1)aspartic diesters (derivatives of ( R ) asa) with a chiral cationic amino acid syn[Ag((CN)&],[AsF6], with an undulating
square cationic network (C) 417
thon (C) 1066
Dinuclear nickel complexes with bridging
Atomic absorption spectroscopy, Atomabally1 ligands (C) 704
sorptionsspektrometrie (B) 137
Pentacarbonylolefin- and pentacarbonylAzaallenium salts, A new, facile route to 2diolefinrhenium complex cations; syntheazaallenium salts-bis(2-adamanty1idene)sis and structure of the 2-butene-1,4-diylammonium hexachloroantimonate (C)
bridged
carbonyldirhenium
complex
340
Azaallenylidene complexes, Cationic 2-azatrans-[(OC),ReCH,CH = CHCH2Re(C0)5]
allenylidene complexes, novel com(C) 505
pounds with unusual photochemical proPreparation, magnetism, and crystal strucperties (C) 121
tures of the tautomers [LCu(pzAzaallylmolybdenum complexes Synthesis,
OH),CuL](CIO,), (blue) and [LCu(p2anti-bis-2,3-diazabicyclo[2.2.l]hept-2-ene
structure, and reactivity of $-l-azaallylOH2)(pz-O)CuL](C104)2,(green): p-aqua(C) 421
molybdenum complexes (C) 422
p-0x0 vs. di-p-hydroxo linkage (C) 57
Azaborolyl compounds, Bis(dihydro-1,2- Bis(diisopropy1amino)-1,2-dihydro-1,2-diStepwise formation of a dinuclear p-amiazaboroly1)tin-a
novel boron-nitrogen
borete, 1,2-Bis(diisopropylamino)-1,2-dinocarbyne- and a p-formimidoyl-metal
stannocene (C) 602
hydro-1,2-diborete (C) 759
complex by insertion of methyl isocyAzahexamethineneutrocyanines from a N- Bishomoperylene, syn- and anti-bishomoanide into an MHM bridge (C) 577
Sulfur monoxide as 4-electron bridge-liperylene (C) 590
(tetramethy1formamidinio)pyridinium salt
Bis-lactonization, Pd“-catalyzed stereoselec(C) 511
gand in the complex [{($-C,H,)Azido-3-methyl-l,2-butadiene,Synthesis and
tive bis-lactonization (C) 1045
(CO)2Mn),SO] (C) 228
tetrafluoroborate,
reactions of 4-azido-3-methyl-l,2-butadi-Bis(pyridine)iodine(r)
Synthesis and structure of [Pt2(p-H)(pI ( P ~ ) ~ B Fa, , new reagent in organic synene (C) 216
C H C H , P ~ ) ( ~ ~ ~ ~ O S )(C)
~ ] [ 120
BF~],
thesis: general method for the 1,2-iodoAzoalkanes, Sensitized UVAaser photolysis
Synthesis, structure, and ligand motion of
functionalization of olefins (C) 319
of azoalkanes: conformational influences
[Cr(C0)2(P(OCH3)3J(q4-2,4-dimethyl-1,3on intersystem-crossing and lifetimes of Bis(tricarbony1iron)-para-quinodimethanes :
pentadiene)], a complex with a C-H-Cr
triplet diradicals (C) 1071
preparation and molecular structure (C)
bridge (C) 502
Azo ligands, Extremely long-wavelength
52 1
Butatrienecarboxylic acid derivatives, On
charge-transfer absorptions of binuclear Bis(trimethylsilyl)ketone, Acylsilanes via
the thermal behavior of butatrienecarboxcomplexes with azo-modified 2,2’-bipyrioxidation of phosphonium ylides: the first
ylic acid derivatives: crystal and molecudyl ligands (C) 684
synthesis of bis(trimethylsily1)ketone and
lar structure of a [4]radialene tetracarbAzulene derivatives, A novel transformation
its use as an equivalent of the dianion
oxylic ester (C) 852
of a calicene to an azulenofulvene (C) 60
COZe (C) 1068
Butatrienecarboxylic acids, Synthesis of
Bis(trimethylsi1yl) telluride, Novel reactions
1,2,3-butatrienecarboxylicacids (C) 85 1
of acyl halides with bis(trimethylsily1) telButterfly molecule, (i-C3H,SGaI,),, the first
luride: C,Te and C,C bond formation (C)
BARBARALANES, Reaction of homobenz“butterfly” molecule with tetracoordin1041
valene with tetracyanoethylene; formaated gallium (C) 970
tion of a tetracyanodihydrobarbaralane Bituminous coal, Reductive alkylation of
rert-Butylimino-2,2,6,6-tetramethylpiperidinbituminous coal: coal-propanesulfonic
derivative and a tetracyanocyclopropane
oborane, Hydroboration and hydroziracids having remarkable solub
derivative (C) 61 1
conation of rert-butylimino-2,2,6,6-tetra342
Beckmann rearrangement, Selective reacmethylpiperidinoborane(C) 998
tions using organoaluminum reagents (R) Bond cleavage, Cleavage of a C-C bond in
Butyrolactones, Synthesis and biological acthe catalytic hydrosilylation of camphor
668
tivity of a-methylene-y-butyrolactones(R)
oxime (C) 703
Beilstein handbook of organic chemistry (B)
94
Methyl migration and transannular 1,5890
hydride shift on oxidative cleavage of
Benzene dimers, 0.p’-Dibenzene (C) 1059
CALICENE, A novel transformation of a
C-Pd bonds with CuCI2 (C) 207
Benzo[bc]naphtho[2,1,8-gh~~oxecine,
The first
calicene to an azulenofulvene (C) 60
[2.l]phane: a new helical molecular skele- Bond shift, Synthesis and dynamic properCamphor oxime, Cleavage of a C-C bond
ties of chiral heptalenes (C) 212
ton (C) 885
in the catalytic hydrosilylation of camphor oxime (C) 703
Benzosemibultvalene, Intramolecular 14+ 31- Bonellin dimethyl ester, Total synthesis of
(&)-bonellin dimethyl ester (C) 775
Captodative substituent effects, 1,4-Photocycloaddition to 5-diazomethyl-5H-benzdcycloaddition of a-morpholinoacrylonicycloheptenes-a step in a new benzo- Boraethenes, Simply substituted boraethenes (C) 1065
trile to I-acylnaphthalenes (C) 1048
semibullvalene synthesis (C) 597
Carbaboranes, Dimerization of a C2B3-c/osoBergmeyer, Methods of enzymatic analysis. Boranes, Catalyzed acetal reduction with
>BH
boranes- 1- 0-alkyl(aryl)alditols,
carbaborane(5) to the C4B6-adamantane
Vol. 2. Samples, reagents, assessment of
results (B) 797
anhydroalditols, and I - 0-alditylalditols
and its 22/32 valence isomerization to the
Methods of enzymatic analysis. Vol. 3:
from 0-glycopyranosides (C) 519
C,B,-nido-carbaborane( 10) (C) 326
Enzymes 1. Oxidoreductases, transferases Boron compounds, An organoboron model
o-Carbamoylnickel complex, The first isosystem for the Fischer-Tropsch synthesis
(B) 888
lated carbonylation-active o-carbamoyl(C)
572
Bianthryl tetracation, Electrochemical oxinickel complex ( C ) 325
9-Fluorenylidene-2,2,6,6-tetramethylpidation of anthracene and 9,9‘-bianthryl to
Carbanions, New bicyclic ketones and the
the respective dication and tetracation (C)
stereochemistry of their reaction with carperidinoborane: an allene isoester with
508
banions (C) 972
two-coordinated boron and B = C double
Bicyclobutane derivatives, On the aggregabond(C)416
Synthesis of a novel stable carbanion:
tion of lithiated bicyclobutane derivatives
Simple synthesis of stable iminoboranes
1,1,2-tricyano-2-(3,4-dicyano-5-imino-2,5in solution (C) 404
(C) 324
dihydro-1H-pyrrol-2-y1idene)ethanide by
Boron heterocycles, 1,2-Bis(diisopropylamireduction of tetracyanoethylene with
Bicyclo[3.2.0]heptaphosphane, P,rBu,-the
no)-1,2-dihydro-1,2-diborete(C) 759
first bicyclo[3.2.0]heptaphosphane (C)
tris(2,2’-bipyridine)titanium (C) 426
504
X-ray structure determination of [a2,3-Dihydro- 1,3-diborole-metal complexes
Asymmetric addition of a chiral cyclic phosDhite to a cvclic imine-svnthesis of a
bhosphonic acid analogue -of D- and Lpenicillamine (C) 1067
Asymmetric Diels-Alder reaction, Concerning the mechanism of the asymmetric
Diels-Alder reaction: first crystal structure analysis of a Lewis acid complex of a
chiral dienophile (C) 112
Asymmetric isomerization, Bis[(R)-( +)-binap]rhodium(~)perchlorate, a highly efficient catalyst for the asymmetric isomerization of allylamines (C) 217
Asymmetric synthesis, Double asymmetric
synthesis and a new strategy for stereochemical control in organic synthesis (R)
Angew, (‘hem. Inr. Ed. Engl. 24 11985) No. 12
Bicyclotetraphosphane, Bis(2,4,6-tri-rerr-buty1phenyl)bicyclotetraphosphane (C) 1056
Binudea;complexes, Reactibn of small molecules with the binuclear complex [(pC5H5)(p-Br)Pd2(PR3),]: addition without
cleavage of the metal-metal bond (C) 516
Biotechnology. A comprehensive treatise in
8 volumes. Vol. 5: Food.and feed production with microorganisms (B) 436
Chiral compounds synthesized by biocatalytic reductions (R) 539
Bipyridyl ligands, Extremely long-wavelength charge-transfer absorptions of binuclear complexes with azo-modified
2,2’-bipyridyl ligands (C) 684
4,4’-Bipyrimidine, d6-Metal complexes of
4,4’-bipyrimidine, an ambident ligand
with high n-acceptor ability (C) 430
Bis(2-adamanty1idene)ammoniumhexachloroantimonate, A new, facile route to
2-azaallenium salts-bis(2-adamantylidene)ammonium hexachloroantimonate (C)
340
Bis(tert-buty1)diphosphene as building block
of a trichromium cluster. A novel type of
coordination of diphosphenes (C) 1069
Biscarbyne cluster, Nonacarbonylbis(p3fluoromethy1idyne)triiron: formation of a
biscarbyne cluster from carbonyliron and
tribromofluoromethane (C) 119
Bis-2,3-diazabicyclo[2.2.l]hept-2-ene,
Laser
photolysis of the bisazoalkane 7-syn,7‘-
I081
(phenylsulfonyl)benzyllithium-tetramethylethylenediamineI2: chirality of an a-sulfonyl “carbanion” (C) 573
Carbene complexes, Reaction of thermally
generated (q’-aryne)zirconocene
with
W(CO)6, a novel route to carbene complexes (C) 584
Transition metal carbene complexes (B)
137
Carbene (carbenoid) insertion reaction, Spiroacetal formation by carbene (carbenoid)
insertion reaction: synthesis of the major
constituent of the sex attractant of the
olive fly (Dacus oleae) (C) 230
Carbon disulfide, Fragmentation and recombination of CS2 and CSSe in the coordination sphere of platinum metals (C)
5 I8
Carbon monoxide coupling, Monomeric,
mononuclear enediolate complexes of zirconium: molecular geometry and electronic structure of the products of reductive
C O coupling on the metal (C) 712
Carbon selenide sulfide, Fragmentation and
recombination of CS2 and CSSe in the coordination sphere of platinum metals (C)
518
Carbon tetrachloride, C12C-CI-C100,
C12C-CI-BroB,
and Br2C-Br-Cl0@
by
gas-ghase
decarbonylation
of
CX,COY. @ (C) 869
Carbonylation, Reductive carbonvlation of
vnitrophenol with a Fe-Pd c l k r - d e r i ved heterogeneous catalyst; C O migration
in [FePdPt(C0)4(PhzPCH2PPh2)2]
(C) 768
Carbonylcyclopropane dimers, Novel carbonylcyclopropane dimers and trimersfree ketenes or organometallic intermediates? (C) 605
Carbonylcyclopropane trimers, Novel carbonylcyclopropane dimers and trimersfree ketenes or organometallic intermediates? (C) 605
Trispiro[2. 1.2.1.2. I]dodecane-4,8,12-trione
(C) 607
Carbonyl olefination, Strongly preferential
alkylation and carbonyl olefination of aand p-hydroxycarbonyl compounds by organo-transition metal reagents in competition experiments with the corresponding
deoxy compounds (C) 348
Carbyne cluster, Nonacarbonylbis(p,-fluoromethy1idyne)triiron: formation of a biscarbyne cluster from carbonyliron and
tribromofluoromethane (C) 119
Carbynemetal complex,
Synthesis of
[Et2N-C = W(CO)2(p-PPh2)2Mo(CO)4]e,
the first anionic carbynemetal complex:
addition of C 0 2 to the W - C bond (C)
203
Carcinogens, Environmental carcinogens:
polycyclic aromatic hydrocarbons (B)
235
Catalysis, 3-Aminoindoles, imidazolidines,
and oxazolidines from isocyanides and
carbene complexes by metal-induced
[4+2]- and [3 +2]-cycloadditions (C) 978
An intermediate and its secondary products in a nickel-catalyzed synthesis of
[4]-radialenes (C) 496
Carbonyliron-assisted coupling of cyclopolyenes with methyl acrylate (C) 353
Catalytic hydroboration with rhodium
complexes (C) 878
Catalyzed acetal reduction with >BH boranes-- I - 0-alkyl(aryl)alditols, anhydroalditols, and I-0-alditylalditols from O-glycopyranosides (C) 5 19
C C Bond formation of alkenes with isocyanates on Ni” complexes-a new synthesis of acrylamides (C) 325
Cleavage of a C-C bond in the catalytic
hydrosilylation of camphor oxime ( C )
703
Ethynebis(triphenylphosphane)nickel(O)
(C) 323
Nickel-catalyzed cyclodimerization of 2tert-butyl- and 2-trimethylsilyl-1,3-butadiene (C) 313
1082
Nickel(0)-catalyzed synthesis of sorbanilide from 1,3-pentadiene and phenyl isocyanate (C) 961
Novel polymerization of a-olefins with
the catalyst system nickel/aminobis(imino)phosphorane (C) 1001
Organocobalt compounds in the synthesis
of pyridines-an example of structureeffectivity relationships in homogeneous
catalysis (R) 248
Pd”-catalyzed stereoselective bis-lactonization (C) 1045
Selectivity and mechanism of diene cyclodimerization on iron@) complexes (C)
781
The first isolated carbonylation-active 0carbamoylnickel complex (C) 325
Catalysts, q3-Allylpalladium compounds (R)
283
Bis[( R)-( + )-binap]rhodium(~)perchlorate,
a highly efficient catalyst for the asymmetric isomerization of allylamines (C) 217
Catalytic transformations of sesquiterpene hydrocarbons on alkali metal/aluminum oxide (C) 320
Cationic allylruthenium complexes via interchange of ally1 moieties (C) 347
Highly active ylide-nickel catalysts for the
polymerization of ethylene (C) 599
Novel trimerization of cyclopentadiene
with a homogeneous, bifunctional palladium-acid catalyst system (C) 314
Polymerization of propene and butene
with a chiral zirconocene and methylalumoxane as cocatalyst (C) 507
Reductive carbonylation of vnitrophenol
with a Fe-Pd cluster-derived heterogeneous
catalyst;
CO
migration
in
[ Fe Pd Pt(CO),( PhzPCH ,PPh,),] (C) 768
Cation effect, Reduction of ketones by alkali metals in tertiary alcohols: unexpected cation effect on the stereochemistry
(C) 499
Cations, Electrochemical oxidation of anthracene and 9,9’-bianthryl to the respective dication and tetracation (C) 508
C C Bond formation of alkenes with isocyanates on Nio complexes-a new synthesis of acrylamides (C) 325
Carbonyliron-assisted coupling of cyclopolyenes with methyl acrylate (C) 353
Novel reactions of acyl halides with
bis(trimethylsily1) telluride: C,Te and C,C
bond formation (C) 1041
Syntheses with radicals-C-C bond formation via organotin and organomercury
compounds (R) 553
The first isolated carbonylation-active 0carbamoylnickel complex (C) 325
CC bonding, Misinterpretation of CC bonding through unusually large ’JCC values-a caveat for the use of INADEQUATE”C-NMR spectroscopy (C) 854
Ceramic, Radwaste immobilization by structural modification-the crystallochemical
properties of SYNROC, a titanate ceramic (R) 357
Cerebrosides, Short synthesis of cerebrosides (C) 65
Chain-lengthening difunctionalization of
Grignard compounds by reaction with ketenylidenetriphenylphosphorane (C) 405
Chaksine, The revised structure and absolute configuration of chaksine (C) 959
Charge distribution, Calculation of the
charge distribution in conjugated systems
by a quantification of the resonance concept (C) 687
Charge-transfer absorptions, Extremely
long-wavelength charge-transfer absorptions of binuclear complexes with azomodified 2,2’-bipyridyl ligands (C) 684
Charge-transfer interaction, The synthesis of
porphyrins doubly linked to quinones by
hydrocarbon chains ( C ) 1003
Chelate ligands, Chelate ligand-controlled
qI-7’ change of coordination in
amino(imino)phosphane ligands and their
conversion into a nickelaazadiDhosDhetidine (C) 525.
Chelate-stabilized diphosDhene and diphosphorus complex& of nickel (C) 522
Transition metal polysulfides: coordination compounds with purely inorganic
chelate ligands (R) 742
:helation control, Chelation-controlled stereoselective synthesis of cyanohydrins (C)
.
&
989
,_,
Chemical bonds, High-resolution X-ray crystallography-an
experimental method
for the description of chemical bonds (R)
237
Cherry crystallites, Synthesis and structure
of the [Ni18Pt,(CO),,H,_,J”( n = 5 , 4)
ions: Ni-Pt clusters as models for “cherry” crystallites (C) 697
Chiral compounds synthesized by biocatalytic reductions (R) 539
Chiral heptalenes, Synthesis and dynamic
properties of chiral heptalenes (C) 212
Chiral homoallylic ethers, Allylation of aldehydes with etherification by dialkoxydichlorotitanium/allyltrimethylsilane;an
asymmetric variant of the Sakurai reaction (C) 765
Chirality, Axial chirality can lead to chiral
smectic and cholesteric liquid crystals (C)
64
Chirality Transfer, Allene Claisen rearrangement with I,4-chirality transfer (C) 700
Chlorophilic attack, Reactions of per(ch1oro,fluoro)ethanes with aryloxide and alkoxide ions-evidence for chlorophilic attack on C-CI bonds (C) 871
Chromatography, Combination of chromatographic separation methods with mass
spectrometry-a
modern technique for
studying metabolism (R) 451
The analysis of gases by chromatography
(B) 136
Chromium cluster, Bis(tert-buty1)diphosphene as building block of a trichromium
cluster. A novel type of coordination of
diphosphenes (C) 1069
Chromium(v) compounds, [(qs-CSMes)CrO2l2--a dinuclear 0x0-complex of
chromium(v) (C) 601
Chrysanthemic acid methyl esters, Stereoand enantioselective synthesis of both
cis-chrysanthemic acid methyl esters in
high optical purity (C) 996
Claisen rearrangement, Allene Claisen rearrangement with 1,4-chirality transfer (C)
700
Clathrates, Host/guest chemistry of organic
onium compounds-clathrates, crystalline
complexes, and molecular inclusion compounds in aqueous solution (R) 727
Clusters, Cluster expansion with Cp(C0)Rh
fragments (C) 424
closo-Clusters, Synthesis and structure of a
thallium complex with an anionic sandwich complex ligand (C) 71
Nonacarbonylbis(p,-fluorometh ylidyne)triiron: formation of a biscarbyne cluster
from carbonyliron and tribromofluoromethane (C) I19
Novel
MoFeS
clusters
from
[(CsMes)2M~2S4] and
Fe(CO),
or
FedC0)9 (C) 133,
Skeletal isomerization of the [Pt!(pPPh,),Ph(PPh,),] cluster by recrystallization in various solvents (C) 861
Synthesis and structure of [(CSHs)$M3(CO),(p,-As)] ( M = Mo, ,W), transitionmetal-stabilized arsanetriyl compounds
(C) 66
Synthesis and structure of the spirocluster
[(~s-CsHs),Mo,A~(CO),(CHP(C,HS)311(C)
702
Synthesis of [(C5Me5)2MozXS3Co(CO)2]
clusters ( X = P, As) and structural characterization of a k2,q2-AsSligand (C) 132
C-Methyl-2’-deoxyribonucleoside, 3’-C-Methyl-2‘-deoxyribonucleoside, Synthesis of
3’-C-methyl-2’-deoxyribonucleoside
with
methylmagnesium iodide ( C ) 52
Anyew. Chem. lnl. Ed. Engl. 24 119851 No. 12
ylenecyclopropanes and alkynyltrimethnylsu1fonyl)benzyllithium-tetramethylC-NMR Spectroscopy, "C-NMR Spectrosylsilanes (C) 316
copy of mixed dialkylzinc compounds
ethylenediamine],: chirality of an a-sulfoNovel C - 0 bond formation via [3+2]
nyl "carbanion" (C) 573
with prochiral alkyl residues (C) 335
cycloaddition of diphenylketene to a
Coal-propanesulfonic acids, Reductive al- Coordination tautomerism, Preparation,
dioxo metal moiety (C) 860
magnetism, and crystal structures of
kylation of bituminous coal: coal-prothe tautomers [ L C U ( ~ ~ - O H ) ~ C U L ] ( C I O ~On
) ~ the role of radical ion pairs in [4+2]
panesulfonic acids having remarkable socycloadditions (C) 337
lubilities (C) 342
(blue) and [LCu(p2-OH2)(p2-O)CuL]On the thermal behavior of butatrienecarCobalt clusters, New Co and Ni clusters
(C104), (green): p-aqua-p-oxo versus
boxylic acid derivatives: crystal and
with Se and PPh3 as ligands: [Co4(p3di-p-hydroxo linkage (C) 57
molecular structure of a [4]radialene tetraCorrinoids, Complete signal assignment of
Se)dPPhd,l, [Co,(~~-Se),(pPh,),l,[Co&carboxylic ester (C) 852
Se),(~,-Se),(PPh,),l, and (Ni34(ps-Se)2(~4- the "C-NMR spectra and structure deterSynthesis of 1,4-dihydropyridine nucleomination of corrinoids by 2D-INADESe)zdPPh3)llll(C) 993
sides by photochemical cycloaddition (C)
Cobalt compounds, Cofacial dimer of a diQUATE and 2 D "C,'H-NMR chemical
127
iminosuccinonitrile complex containing a
shift correlation using "J(C,H) (C) 333
Synthesis of seven-membered rings by
Co"--Co" bond and its reduction to the
The first chemical partial synthesis of the
[(,2 + .2) + n2] cycloaddition to homodimonomeric Co' complex (C) 210
nickel complex of a cobyrinic acid derivaenes (C) 594
Cobalt-rhodium compounds, Tridentate
tive (C) 867
Cycloalkylation, 1,l- and 1,o-dilithioallyl
oxygen ligands as cyclopentadienyl equiv- Coupling constants, Complete signal assignphenyl sulfone: synthesis, geminal cycloalents: structure and properties of
ment of the "C-NMR spectra and strucalkylation, and lithium-titanium exchange
[LRh(pl-CO),RhL],
L - =[(CSHs)Coture determination of corrinoids by 2D(0610
INADEQUATE and 2D I3C,'H-NMR
{P(O)KLIII-(c)683
Cycloalkynes, New silacycloalkynes with up
Cobalt-sulfur clusters, Novel cobalt- and
chemical shift correlation using "J(C,H)
to four 1,4-disila-2-alkyne units in the ring
nickel-clusters with S and PPh3 as ligands;
(C) 333
(C) 565
crystal structures of [Co,S,(PPh,),CI2],
Misinterpretation of C C bonding through
Cycloarsanes, AsI2fBu8-a tricyc10[6.4.0.0'~~]unusually large 'Jcc values-a caveat for
[Co,S,(PPh,),]+[CoCI,(TH~F)]-,
and of
dodecaarsane (C) 991
the use of INADEQUATE-"C-NMR
"i,S,SL(PPh,),l,
and "l&(PPh3)71
(C)
spectroscopy (C) 854
Cyclodextrins as second sphere ligands for
706
"N-"Si coupling constants and "N isotransition metal complexes-the
X-ray
C O bond formation, Novel C-0 bond fortope effect on '9Si chemical shifts in comcrystal structure of [Rh(cod)(NH3),-a-cymation via [3 + 21 cycloaddition of diphepounds with natural isotopic abundance
clodextrin][PF,].6 H,O (C) 786
nylketene to a dioxo metal moiety (C)
Cyclodimerization, Nickel-catalyzed cyclo(C) 568
860
Simplification of spectra for the determidimerization of 2-[err-butyl- and 2-trimeCobyrinic acid derivatives, The first chemination of coupling constants from homothylsilyl-1,3-butadiene (C) 3 13
cal partial synthesis of the nickel complex
nuclear correlated 2 D N M R spectra (C)
Selectivity and mechanism of diene cycloof a cobyrinic acid derivative (C) 867
dimerization on iron(0) complexes (C)
690
Competition experiments, Strongly prefe- Crinipellins, the first natural products with a
78 1
rential alkylation and carbonyl olefinatetraquinane skeleton (C) 709
Cyclohepta[a]phenalene-6,12-dione,Synthetion of a- and /&hydroxycarbonyI com- Crown ethers, A photochemically "switchsis of cyclohepta[u]phenalene-6,12-dione
pounds by organo-transition metal reaed-on" crown ether containing an intra(C) 757
gents in competition experiments with the
annular 4-methoxyphenylazo substituent
Cycloheptenes, Synthesis of seven-membercorresponding deoxy compounds (C) 348
(C) 866
ed rings by [(,2 + J ) .2] cycloaddition to
Complexation, A photochemically "switchChiral poly(9,9'-spirobifluorene) crown
homodienes (C) 594
ed-on" crown ether containing an intraethers (C) 792
Cyclohexastibane, (C,H,Sb),.( 1,4-dioxane),
annular 4-methoxyphenylazo substituent
Reactions in the ligand sphere of iron(ii):
the first cyclohexastibane (C) 72
(C) 866
synthesis of crown ethers (C) 858
Cyclohexene derivatives, Nickel-catalyzed
Computer-controlled precipitation of metal Crystal morphology, Growth and dissolucyclodimerization of 2-rert-butyl- and
hydroxides and hydrous oxides-preparation of organic crystals with "tailor-made"
2-trimethylsilyl- 1,3-butadiene (C) 3 13
tion of manganese dioxide having uniinhibitors-implications in stereochemisCyclooligomerization, Ethynebis(tripheny1form particle sizes (C) 1057
try and materials science (R) 466
phosphane)nickel(O) (C) 323
Conformation, Consequences of strain for Crystal structures, Distortional isomers of
New silacycloalkynes with up to four 1,4the structure of aliphatic molecules (R)
[LWOCI,]+ in the solid state and in soludisila-2-alkyne units in the ring (C) 565
529
tion: crystal structures of the blue and
Reaction of ethylene oxide with sulfur
green forms of [LWOC12]PF6(C) 777
Coordination, A dithioester as allylic-type
dioxide in the presence of cesium ions:
NaGe-high-pressure formation of the
4e ligand (C) 97 I
synthesis of 1 ,3,6,9,2h4-tetraoxathia-2-cyNaPb-type structure (C) 500
cloundecanone (C). 695
Bis(rcrr-buty1)diphosphene as building
Preparation,
magnetism,
and
crystal
strucblock of a trichromium cluster. A novel
Cyclopentadienide ions, Donor-acceptor
tures of the tautomers [LCu(p,type of coordination of diphosphenes (C)
substituted anions and cations in the cyclopentadienyl system (C) 982
OH)2CuL](C104)2 (blue) and [LCu(p,1069
OHZ)(p2-O)CuL](CI04)2(green): p-aquaCyclopentadienyl equivalents, Tridentate
Chelate ligand-controlled q'-q2 change of
p-0x0
vs.
di-p-hydroxo
linkage
(C)
57
oxygen
ligands as cyclopentadienyl equivcoordination in amino(imino)phosphane
alents: structure and properties of [LRhligands and their conversion into a nickel- C,Te bond formation, Novel reactions of
acyl halides with bis(trimethylsily1) tellu(p-CO),RhL], where the ligand L - =
aazadiphosphetidine (C) 525
ride: C,Te and C,C bond formation (C)
[ C ~ C o ( C O ) ~ ] ~ - c r y s t astructure
l
of a po[(C,HS)CO{P(O),R~J~I~
(C) 683
1041
Cyclopentadienylium ions, Donor-acceptor
lymer with a one-dimensional, infinite
Cumulenes, Synthesis of 1,2,3-butatrienecarcopper-cobalt bonding system (C) 70
substituted anions and cations in the cyboxylic acids (C) 85 I
clopentadienyl system (C) 982
Cyclodextrins as second sphere ligands
for transition metal complexes-the X-ray Cyanogen as a bridging ligand-preparation
Cyclopeptides, Total synthesis of ulicyclaand crystal structure of polymeric
crystal structure of [Rh(cod)(NH,),.a-cymide (C) 569
clodextrin][PF,].6 H 2 0 (C) 786
Cyclophanes, Vols. 1 and 2 (B) 435
[Ag((CN),JZ],,[AsF6],with an undulating
Cyclophosphanes, A novel type of cyclotriDiamminebis( 1,5-cyclooctadiene)(p-1,4,10, square cationic network (C) 417
Cyanohydrins, Chelation-controlled stereophosphane complex: synthesis and strucI3-tetraoxa-7,16-diazacyclooctadecaneN7 ,"" )dirhodiumbis(hexafluorophosselective synthesis of cyanohydrins (C)
ture of [Ni&-P3iPr3)z(C0).,] (C) 415
989
Bis(2,4,6-tri-terr-butylphenyl)bicyclotetraphate): an example of simultaneous first
Cyclization, Non-induced, highly diastereophosphane(C) 1056
and second sphere coordination (C) 135
selective intramolecular ene reactions of
[Mn(S2C6H3Me)2]n-: mononuclear manP7rBus-the first bicyclo[3.2.0]heptaphos1,7-dienes to trans-1,2-disubstituted cycloganese complexes with square-planar
phane (C) 504
h e x a n p (C) 1042
(n = 1) and distorted tetrahedral (n = 2)
Cyclopolyenes, Carbonyliron-assisted coupsulfur coordination (C) 117
Cycloadditions, 3-Aminoindoles, imidazoliling of cyclopolyenes with methyl acrylate
Novel aspects of the coordination chedines, and oxazolidines from isocyanides
( C ) 353
mistry of phosphane (C) 68
and carbene complexes by metal-induced
Cyclopropanecarboxylates, Thiophene deriPhosphorus, arsenic, antimony, and bis[4+ 21- and [3 21-cycloadditions (C) 978
vatives by novel rearrangements of siloxymuth multiply bonded systems with low
Intramolecular [4 + 31-cycloaddition to 5substituted
cyclopropanecarboxylates
coordination number-their role as comdiazomethyl-5H-benzocycloheptenes-a
(C) 588
plex ligands (R) 924
Cyclopropane cleavage, Photochemistry of
step in a new benzosemibullvalene synSynthesis and structure of trunsthesis (C) 597
l-methoxybicyclo[2.2.2]octenones;photo[MCI( = C = CHR)(PPr,),] (M = Rh, Ir):
Light-induced [2 21 cycloaddition reaclytic cyclopropane cleavage of the initially
the first square-planar vinylidenemetal
tions of nonconjugated dienes-the effect
formed tricyclo[3.3.0.02~8]octan-3-ones
(C)
complexes (C) 406
of through-bond interaction (C) 566
163
X-ray structure determination of [a-(phe4-Methylene- I-cyclopentenes from methCyclopropenyl complexes, Dicarbonyl-q'-cy-
+
+
+
Anyen. Client. lnr. Ed. Engl. 24 iiY8S) N o . 12
I083
clopentadienyl(1 -cyclopropenyl)iron complexes-a new class of o-cyclopropenyl
complexes (C) 209
Cycloreversion, Intramolecular [4 + 21-cycloreversion of the two symmetrical homobasketenes (C) 331
Cyclosporine, Synthesis of cyclosporine and
analogues: structural requirements for immunosuppressive activity (R) 77
Cyclotriphosphane complex, A novel type
of cyclotriphosphane complex: synthesis
and structure of [Niz(p-P3iPr3)2(C0)4](C)
415
Diels-Alder reactions, Chemoselective muldiphosphene and diphosphorus complexticomponent synthesis of a,B-unsaturated
es of nickel (C) 522
esters and lactones and of their DielsDiphosphenyl
complexes, [(qs-CsMe5)Alder adducts (C) 790
(C0)2M - P= P(2,4,6-fBu3C,H,)] (M = Fe,
Concerning the mechanism of the asymRu), the first diphosphenyl complexes (C)
metric Diels-Alder reaction: first crystal
865
structure analysis of a Lewis acid complex
Diphosphorus complexes, Chelate-stabiliof a chiral dienophile (C) 112
zed diphosphene and diphosphorus comHighly enantioselective intramolecular
plexes of nickel (C) 522
hetero Diels-Alder reactions for the synDiphosphorus dications, Preparation and
thesis of enantiomerically pure tricyclic
structure of a diphosphorus compound
lactones (C) 784
with positive charges o n the two directly
Photochemically initiated, electron-transbonded phosphorus atoms (C) 975
fer-catalyzed Diels-Alder reactions of
Dipleiadiene, Synthesis of dipleiadiene by
electron-rich dienophiles (C) 412
"serendipity" (C) 1046
DAMAGE TO FORESTS, Photosignal I1 as
Primary adduct, y-ketoketene, and some
Dipolar cycloadditions, 1,4-Dipolar cycloan indicator for damage to forests - EPR
subsequent products of the reaction of
additions, First 1,4-dipolar cycloadditions
spectroscopic investigation of spruce
methyl 6-oxo-5-phenyl-1,3,4-oxadiazine- of 6-0~0-3,6-dihydro-l-pyrimidinium4needles (C) 425
carboxylate with norbornene (C) 886
olates to ketenes and other carbonyl comDL-Dansyl-amino acids, Chiral copper(I1) Diethyl thioxomalonate S-oxide; a sulfine
pounds (C) 608
complexes for the enantioselective resoluas reactive intermediate (C) 855
Di@tolyl)- 1,4-pentaazadien-3-ide, 1,5-Di@
tion of DL-dansyl-amino acids by HPLC Dihalocarbenes, 1,4-Addition of dihalocartolyl)-1,4-pentaazadien-3-ide,Complexes
(C) 336
benes to 1,3-dienes (C) 585
of l,S-di@toIyl)-l,4-pentaazadien-3-ide,
Decabenzylgermanocene: synthesis and
1,4-Additions of dihalocarbenes (C) 579
crystal structures of [Cu(tolylNNNNNstructure of a monomeric, air-stable ger- Dihydro-1,3-diborole-metalcomplexes, 2,3tolyl)13 and [ N i ( t o l y l N N N N N t ~ I y l ) (C)
~]~
manocene (C) 773
Dihydro-1,3-diborole-metal complexes
409
Decamethyl-7-thiahexasilanorbornane
with activated C-H
bonds: building
Diquat dication, A macrobicyclic receptor
blocks for multilayered sandwich com(CH,),,Si,S (C) 992
molecule for the diquat dication (C) 581
Deformation, Consequences of strain for
pounds (R) 943
Distortional isomerism, Distortional isomers
the structure of aliphatic molecules (R) Dihydropyridine nucleosides, 1,4-Dihydroof [LWOC12]+in the solid state and in sopyridine nucleosides, Synthesis of 1,4-di529
lution; crystal structures of the blue and
hydropyridine nucleosides by photocheDeformation densities, Comparison of theogreen forms of [LWOCI2]PF, (C) 777
mical cycloaddition (C) 127
retical and experimental deformation
Disulfido ligands, (q5-CSMe5),FeZS4 and
densities in S - 0 bonds (C) 509
Diiminosuccinonitrile complex, Cofacial di(q5-C5Me5),Co2S4,two novel bis(pentaDelocalized ground states, Cofacial dimer
mer of a diiminosuccinonitrile complex
methylcyclopentadienylmetal) complexes
of a diiminosuccinonitrile complex concontaining a Co"-Co" bond and its rerich in sulfur (C) 1060
taining a Co"-Co" bond and its reducduction to the monomeric Co' complex
Disulfur monoxide as complex ligandtion to the monomeric Col complex (C)
(C) 210
preparation and molecular structure of
Diiron
compounds,
The
compound
210
[(rl -C;iMe5)Mn(CO)z(S20)1(C) 5 15
Deoxyhemerythrin, [L,Fe:'(p-OH)(pDitellunum, On the transformation of
[L2Fe~'(~-OH)(~t-CH3CO2)2l(c!o,)~
HzO,
CH,COz)2](C104),~Hz0, a model coma model compound for the diiron centers
[~(CO)5w13Snlinto [KCO)5W,Tezl, a compound for the diiron centers in deoxyhein deoxyhemerythrin (C) 778
pound containing unusually bonded ditelmerythrin (C) 778
Dilithioalkyl sulfones, Dilithio(phenylsu1folurium (CI 428
Dialkylzinc compounds, "C-NMR Specnyl)trimethylsilylmethane: synthesis, I3C/
Dithioesters; A dithioester as allylic-type 4e
troscopy of mixed dialkylzinc compounds
ligand (C) 971
'H-NMR characterization, and lithiumwith prochiral alkyl residues (C) 335
titanium exchange (C) 696
Dithiolanes, Photoreaction of thiones with
Diastereoselectivity, Non-induced, highly
Dilithioallyl phenyl sulfone, 1,1- and I p d i bromoketene acetals (C) 976
diastereoselective intramolecular ene reaclithioallyl phenyl sulfone: synthesis, gemiD-NMR spectroscopy, 2D-NMR spectrostions of 1,7-dienes to fruns-1,2-disubstitunal cycloalkylation, and lithium-titanium
copy, Simplification of spectra for the deted cyclohexanes (C) 1042
exchange(C)610
termination of coupling constants from
anti-Diastereoselective
aldol additions, Dilithio-1,3-butadienes, 2,3-Dilithio-1,3-buhomonuclear correlated 2 D N M R spectra
Enantio- and anri-diastereoselective aldol
tadienes via addition of lithium to buta(C) 690
trienes (C) 57 1
additions of acetates and propionates via
2D-NMR-spectroscopy, The first applicaDilithio(phenylsulfony1 tnmethylsilylmeth0-silyl ketene acetals (C) 874
tion of 2D-NMR to the spectral analysis
Diazadiphospholes,
1,2,3,S-Diazadiphosane: synthesis, ''C/ H-NMR characteriof a paramagnetic complex. Example:
zation, and lithium-titanium exchange (C)
pholes-the first 1,3-diphospha-1,3-diene
bis[R-( )-P,P-diethylthiophosphinic
system (C) 124
696
acid- N-a-methylbenzylamido]nickel(~~)
Diaza-hz-phosphanylia-hs-stannatacyclobu- Dimerization, "Dimers" of aldosterone (C)
(C) 231
130
Donor-acceptor substitution, Donor-acceptane, Synthesis and structure of a diazator substituted anions and cations in the
h2-phosphanylia-h5-stannatacyclobutane Dimethylanthracenemagnesium. 3 thf, Synthesis and structure of 1,4-dimethylan(C) 999
cyclopentadienyl system (C) 982
thracenemagnesium '3 thf and p-trichloroDiaza-1,3-dienes, Selectivity and mechanism
Double asymmetric synthesis and a new
dimagnesium ' 6 thf( 1 + ) anthracenide (C)
strategy for stereochemical control in orof diene cyclodimerization on iron(0)
960
ganic synthesis (R) 1
complexes (C) 78 1
Diazecine derivatives, A triphenylamine 2D-INADEQUATE I3C-NMR spectrum,
Double bond, Isolation and structure of a
Complete signal assignment of the I3Cstable molecule containing a silicon-cardouble-decker (C) 596
NMR spectra and structure determination
Diazene complexes, The first diazene combon double bond (C) 229
of corrinoids by 2D-INADEQUATE and
9-Fluorenylidene-2,2,6,6-tetramethylpiperplex with sulfur-coordinated transition
2D "C,'H-NMR chemical shift correlaidinoborane: an allene isoester with twometal centers, [p-NzHz(Ru(PPh3)dttd)z],
coordinated boron and B = C double
tion using "J(C,H) (C) 333
(dttd2- = 2,3,8,9-dibenzo-1,4,7,lO-tetrabond (C) 416
Dinickel compounds, Dinuclear nickel comthiadecane( - 2) (C) 981
Phosphaalkenylrhenium
complexes-a
plexes with bridging ally1 ligands (C) 704
Diazepines, Photoreactions of N-( l-pyridinnovel class of substances with P = C bonDinuclear complexes with predictable magio)amidates in monolayers and liposomes
netic properties (R) 834
ding (C) 53
(C) 882
Phosphorus, arsenic, antimony, and bisDiphenylketene, Novel C - 0 bond formaDiazocines, 1,s-Diazocines (C) 576
muth multiply bonded systems with low
tion via [3 21 cycloaddition of diphenylDiazo-3H-pyrazoles, Coupling of 3-diazocoordination number-their role as comketene to a dioxo metal moiety (C) 860
3H-pyrazoles with 2-alkoxy-1,6-methaplex ligands (R) 924
Diphosphaallylcobalt, Tricarbonyl(l,3-dino[lO]annulenes and oxidative cyclization
Dyestuffs, Organic chemistry in colour (B)
phosphaallyl)cobalt, a phosphorus anato pyrazolotriazines (C) 346
logue of (q3-allyl)tricarbonylcobalt (C)
75
o,p'-Dibenzene (C) 1059
420
Diboraallyl system, Diboriranides and a 1,3ELECTROCHEMISTRY, Electrochemical
diboraallyl system with B-H-B bridge (C) Diphosphene, Bis(ter/-buty1)diphospheneas
methoxylation of antipyrine ( C ) 864
building block of a trichromium cluster. A
788
novel type of coordination of diphosphElectrochemical oxidation of anthracene
Diboroles, Synthesis and structure of a thaland 9,9'-bianthryl to the respective dicatenes ( C ) 1069
lium complex with an anionic sandwich
E-Z-Photoisomerization of a diohosuhion and tetracation (C) 508
complex ligand (C) 71
Heterogeneous redox catalysis on Ti/
ene on carbonylmetal complexes (M = Cr,
Dichlorosilanediyl, SiCI,: photoelectron
TiOz
cathodes-reduction
Mo,
w
)
(C)
21
1
of nitrobenspectroscopic optimization of various synDiphosphene
complexes,
Chelate-stabilized
zene
(C) 77 1
theses (C) 205
2
+
+
1
I084
r
Angew. Chem. Int. Ed. Engl. 24 (1985)Nn. 12
Oxidation of 2-propanol at Ti/Crz03
anodes (C) 1049
Electron impact ionization, CIzC-CI-CIoo
C12C- CI -Bra @,and BrzC- Br- CI
by
gas-ghase
decarbonylation
of
CX,COY
(C) 869
Electron microscopy, Practical analytical
electron microscopy in materials science
(B) 890
Electron-transfer catalysis, Photochemically
initiated, electron-transfer-catalyzed DielsAlder reactions of electron-rich dienophiles (C) 412
Elimination, Cleavage of an ether bond via
b-elimination
of
ethanol
from
[(H20)5CrCH2CHZOCZHs]2+~
in aqueous
solutions; a pulse radiolysis study ( C )
779
Enantiomeric excess, A new method for determining enantiomeric excess, where the
sample serves as its own reference (C)
315
Enantiomer resolution, Direct enantiomer
resolution of hydroxy and carbonyl compounds by gas chromatography on Chirasil-Val (C) 48
Enantioselective aldol additions, Enantioand anfi-diastereoselective aldol additions
of acetates and propionates via 0-silyl ketene acetals (C) 874
Enantioselective hydrosilylation of prochiral 3,4-dihydro-2H-pyrrole derivatives (C)
995
Enantioselective resolution, Chiral copper(i1) complexes for the enantioselective
resolution of DL-dansyl-amino acids by
HPLC (C) 336
Enediolate Complexes, Monomeric, mononuclear enediolate complexes of zirconium: molecular geometry and electronic
structure of the products of reductive CO
coupling on the metal (C) 712
Ene reaction, First a-methylene-b-peroxylactone-regiospecific ene reaction of ‘Oz
with a$-unsaturated carboxylic acids (C)
1070
Non-induced, highly diastereoselective
intramolecular ene reactions of 1,7-dienes
to trans- 1,2-disubstituted cyclohexanes
(C) 1042
(Q-Enols, isolation of the (4-enols of 8-ketocarboxylic acid derivatives (C) 350
Enterobacterial common antigen, Synthesis
of the immunologically essential saccharide sequence of the “enterobacterial
common antigen” (C) 773
Environmental chemistry, Photosignal I1 as
an indicator for damage to forests - EPR
spectroscopic investigation of spruce
needles (C) 425
Enzymatic analysis, Methods of enzymatic
analysis. Vol. 2. Samples, reagents, assessment of results (B) 797
Methods of enzymatic analysis. Vol. 3:
Enzymes I. Oxidoreductases, transferases
(B) 888
Enzymes as catalysts in synthetic organic
chemistry (R) 617
Chemical basis of the action of glyoxalase
I , an anticancer target enzyme (R) 31
Enzymes hosted in reverse micelles in hydrocarbon solution (R) 439
The construction of new proteins and enzymes-a prospect for the future? (R)
639
Epidermin, Elucidation of the structure of
epidermin, a ribosomally synthesized, tetracyclic heterodetic polypeptide antibiotic (C) 1051
EPR spectroscorw. Photosignal I 1 as an indicator for, damage to forests - EPR
spectroscopic investigation of spruce
needles (C) 425
Error rates of the replication and expression
of genetic information (R) 1015
Esters, Chemoselective multicomponent
synthesis of a,B-unsaturated esters and
lactones and of their Diels-Alder adducts
(C) 790
’
Angew Chrni Inr. Ed. Engl. 24 (198s) Nu. 12
Oxidation of a$-unsaturated esters and
lactones with selenium dioxide to y-0x0
or y-hydroxy derivatives; synthesis of
(+)-A 26771 B and norpyrenophorin (C)
79 1
Ethylene, Highly active ylide-nickel catalysts for the polymerization of ethylene
(C) 599
Ethylene biosynthesis, Cyclopropyl-substituted aminocyclopropane carboxylic acid
(cyclopropyl ACC)-an investigation of
the mechanism of ethylene biosynthesis
(C) 1044
Ethynebis(triphenylphosphane)nickel(O) (C)
323
Grignard compounds, Chain-lengthening
difunctionalization of Grignard compounds by reaction with ketenylidenetriphenylphosphorane (C) 405
Guanosine, A nucleolipid with antiviral
acycloguanosine as head group-synthesis and liposome formation (C) 501
Guest selectivity, “In-out”-isomeric large
cavities and their differing guest selectivity (C) 219
HALF-SANDWICH COMPLEX, Reductive trimerization of the trioxo half-sandwich complex [(q5-C5Me5)Re03]with deoxygenation: the electron-deficient cluster
ion [(q5-CsMe5)3Re3(v-O)6]2+
(C) 50
FAB MASS SPECTROMETRY, SequenHaloalkylidenamines, Regiospecific a-alkylcing of short peptides using FAB mass
ation of a-haloalkylidenamines (“a-halospectrometry-increased information via
ketimines”) (C) 881
derivatization (C) 408
Haloketimines, Regiospecific a-alkylation
Fischer-Tropsch synthesis, An organoboron
of a-haloalkylidenamines (“a-haloketimmodel system for the Fischer-Tropsch
ines”) (C) 881
synthesis (C) 572
H-Azepine synthesis, 1 H-Azepine synthesis,
Fluctuating structure, 2,5,7,10-Tetrakis(triA previously unrecognized 1H-azepine
methylsilyl)-1,6-methano[lO]annulene, a
synthesis (C) 875
fluxional valence tautomer with cycloHelical molecules, The first [Z.l]phane: a
polyolefin structure (C) 587
9-Fluorenylidene-2,2,6,6-tetramethylpiperidin- new helical molecular skeleton (C) 885
oborane: an allene isoester with two-coor- Hemoglobin: structure, function, evolution
and pathology (B) 717
dinated boron and B = C double bond (C)
Heptalenes, Synthesis and dynamic proper416
ties of chiral heptalenes (C) 212
Fluorine chemistry, Hexafluoropropene oxHeteroallenes, Diethyl thioxomalonate 9
ide-a key compound in organofluorine
oxide; a sulfine as reactive intermediate
chemistry (R)ilbl,
(C) 855
Folding, The construction of new proteins
and enzymes-a prospect for the future? ’Heterocycles, 3-Aminoindoles, imidazolidines, and oxazolidines from isocyanides
(R) 639
and carbene complexes by metal-induced
Formaldehyde complex, Synthesis of [(q5[4+ 21- and [3 21-cycloadditions (C) 978
C5Hs)2Mo(qZ-CHZO)]: a formaldehyde
Comprehensive heterocyclic chemistry.
complex of molybdenum (C) 402
The structure, reactions, synthesis and
Fulvene, A novel transformation of a caliuses of heterocyclic compounds (B) 1005
cene to an azulenofulvene (C) 60
Synthesis and structure of a diaza-h2phosphanylia-h’-stannatacyclobutane (C)
GALLIUM COMPOUNDS, Arene com999
plexes of univalent gallium, indium, and
Hetero Diels-Alder reaction, Highly enanthallium (R) 893
tioselective intramolecular hetero Diels(i-C3H7SGa12)Z,the first “butterfly” moleAlder reactions for the synthesis of enancule with tetracoordinated gallium (C)
tiomerically pure tricyclic lactones (C)
970
784
Gas chromatography, Direct enantiomer
Hexacyanocobaltate(iil), Polymeric tris[triresolution of hydroxy and carbonyl commethyltin(~v)]hexacyanocobaltate(iii), a
pounds by gas chromatography on Chiracompound non-analogous to “super prussil-Val (C) 48
sian blue”, and its tris[tricyclopentadienGas-phase reactions of organic compounds
yluranium(iv)] homologue (C) 879
on Raney nickel (C) 418
Hexafluoropropene oxide-a
key comGene technology, Gene und Klone. Eine
pound in organofluorine chemistry (R)
Einfuhrung in die Gentechnologie (B)
161
1006
Hexahydroindane derivatives, StereospecifGenetic information, Error rates of the repic synthesis of 3-substituted hexahydroinlication and expression of genetic infordane derivatives (C) 131
mation (R) 1015
Hexaphosphabenzene as complex ligand
Germanocene,
Decabenzylgermanocene:
(C) 351
synthesis and structure of a monomeric,
History of science, Theoriewandel in der
air-stable germanocene (C) 773
Wissenschaftsgeschichte. Chemie im 18.
Glycine receptor, The glycine receptor of rat
Jahrhundert (B) 234
spinal cord: exploring the site of action of
Homoallylic ethers, Allylation of aldehydes
the plant alkaloid strychnine (R) 365
with etherification by dialkoxydichloroGlycopeptides, Construction of disacchatitanium/allyltrimethylsilane; an asymride N-glycopeptides-synthesis
of the
metric variant of the Sakurai reaction (C)
linkage region of the transmembrane-neu765
raminidase of an influenza virus (C) 883
Homobasketenes, Intramolecular [4 21-c~Glycopyranosides, Catalyzed acetal reduccloreversion of the two symmetrical hotion with >BH
boranes- I-0-alkylmobasketenes ( C ) 33 I
(aryl)alditols, anhydroalditols, and 1Homobenzvalene,
Reaction of homobenzvaU-alditylalditols from U-glycopyranosidlene with tetracyanoethylene; formation
es (C) 519
of a tetracyanodihydrobarbaralane derivGlycosphingolipids, Short synthesis of cereative and a tetracyanocyclopropane derivbrosides (C) 65
ative (C) 611
Glyoxalase I, Chemical basis of the action
Homoisoquinoline, 3,8-Methanoaza[ I Olanof glyoxalase I, an anticancer target ennulene (homoisoquinoline) (C) 592
zyme (R) 31
Gold compounds, Synthesis and structure of
Homothiopyrylium ion, The homothiopyrylnew
potassium- old-tellurium
pofgium ion; generation and characterization
anions: [ICAu9Te,l$” [K2Au,Te, en
(C) 214
and [K2Au,Te4(dmfjz(CH,0H)2$’Q) {Ci
Host/guest chemistry of organic onium
432
compounds-clathrates, crystalline comGrammar, The generative grammar of the
plexes, and molecular inclusion comimmune system (Nobel lecture) (R) 810
pounds in aqueous solution (R) 727
+
+
1085
HPLC analysis, Quantitative HPLC analysis
and thermodynamics of sulfur melts (C)
59
Hydrazine and its derivatives. Preparation,
properties, applications (B) 1006
Hydride shift, Methyl migration and transannular 1,5-hydride shift on oxidative
cleavage of C-Pd bonds with CuCI, (C)
207
Hydrido bridges, Diboriranides and a 1.3diboraallyl system with B-H-B bridge (C)
7 8_8-
Stepwise formation of a dinuclear p-aminocarbyne- and a p-formimidoyl-metal
complex by insertion of methyl isocyanide into an MHM bridge (C) 577
Synthesis, structure, and ligand motion of
[Cr(C0,)z(P(OCH3)3J(q4-2,4-dimethyl1,3pentadiene)], a complex with a C-H-Cr
bridge (C) 502
idroboration, Catalytic hydroboration
with rhodium complexes (C) 878
ydrogenobyrinic acid and vitamin B,, (C)
46
Hydrogen storage, Catalytic synthesis of organolithium and organomagnesium compounds and of lithium and magnesium
hydrides-applications in organic synthesis and hydrogen storage (R) 262
Hydroperoxide, Photooxidation of chloroform: isolation and characterization of trichloromethyl hydroperoxide (C) 50
Hydrosilylation, Cleavage of a C-C bond
in the catalytic hydrosilylation of camphor oxime (C) 703
Enantioselective hydrosilylation of prochiral 3,4-dihydro-2H-pyrrole derivatives
(C) 995
Hydrothermal synthesis, The role of hydrothermal synthesis in preparative chemistry
(R) 1026
Hydroxyacetylenes, Novel retro-ene reactions of B-hydroxyacetylenes (C) 783
Hydroxybenzo[u]pyrene 4,5-oxide, Reactive
metabolites of carcinogenic polycyclic hydrocarbons: synthesis and trapping reaction of 9-hydroxybenzo(u)pyrene 4 5 oxide (C) 699
erconjugation, Hyperfine coupling to
nuclei in alkyl substituents-a Contribution to the problem of C-C and C-H
hyperconjugation (C) 495
Hyperfine
coupling, to ”C nuclei in alkyl
_.
substituentsla contribution to the problem of C-C and C-H hyperconjuga\ion (C) 495
H, ”C-NOE difference spectroscopy, Selective ‘H,”C-NOE difference spectroscopy for the elucidation of structures (C)
705
”%
MINOBORANES, Hydroboration and hydrozirconation of tert-butylimino-2,2,6,6tetramethylpiperidinoborane(C) 998
Simple synthesis of stable iminoboranes
(C) 324
mmune response, From the structure of antibodies to the diversification of the immune response (Nobel lecture) (R) 816
Immune system, The generative grammar of
the immune system (Nobel lecture) (R)
810
Immuno enzyme techniques in cytochemistry (B) 614
Immunosuppressive drugs, Synthesis of cyclosporine and analogues: structural requirements for immunosuppressive activity (R) 77
INADEQUATE- “C-NMR
spectroscopy,
Misinterpretation of CC bonding through
unusually large ’JCc values-a caveat for
the use of INADEQUATE-13C-NMR
spectroscopy (C) 854
Inclusion compounds, Host/guest chemistry
of organic onium compounds-clathrates,
crystalline complexes, and molecular inclusion compounds in aqueous solution
(R) 727
1086
lndane derivatives, Stereospecific synthesis
of 3-substituted hexahydroindane derivatives (C) 131
Indium compounds, Arene complexes of
univalent gallium, indium, and thallium
(R) 893
Inorganic polymers, [CuCo(CO),],-crystal
structure of a polymer with a one-dimensional, infinite copper-cobalt bonding
system (C) 70
Cyanogen as a bridging ligand-preparation and crystal structure of polymeric
[Ag((CN)2]~],[AsF6]. with an undulating
square cationic network (C) 417
Synthesis and structure of new Hg-Te
polyanions: [Hg,Te,2]40, a cluster containing Tezo, TelQ, and Te:O ligands and
[HgtTes]’o, a new one-dimensional inorganic polymer (C) 433
Insertion, Monomeric, mononuclear enediolate complexes of zirconium: molecular
geometry and electronic structure of the
products of reductive CO coupling on the
metal (C) 712
Spiroacetal formation by carbene (carbenoid) insertion reaction: synthesis of the
major constituent of the sex attractant of
the olive fly (Dams oleue) (C) 230
Stepwise formation of a dinuclear p-aminocarbyne- and a p-formimidoyl-metal
complex by insertion of methyl isocyanide into an MHM bridge (C) 577
Intercalation compound, (Te2),(I2)-an unusual intercalation compound (C) 393
Iodofunctionalization, I(py),BF,, a new reagent in organic synthesis: general method
for the 1,2-iodofunctionalizationof olefins (C) 319
Ion transport, Mechanisms of biological ion
transport-carriers, channels, and pumps
in artificial lipid membranes (R) 905
Iron clusters, Nonacarbonylbis(p,-fluoromethy1idyne)triiron: formation of a biscarbyne cluster from carbonyliron and
tribromofluoromethane (C) 119
Iron compounds, Dicarbonyl-q’-cyilopentadienyl( 1-cyclopropenyl)iron complexesa new class of o-cyclopropenyl complexes
(C) 209
Reactions of tricarbonyl(sorba1dehyde)iron with carbanions: a repeatable organometallic reaction with Fe(CO)@gration (C) 126
Iron-palladium clusters, Reductive carbonylation of o-nitrophenol with a Fe-Pd
cluster-derived heterogeneous catalyst :
CO migration in the iron-palladium cluster
[FePdPt(CO),(Ph,PCH,PPh,),] (C) 768
lsocyanomethylenetriphenylphosphorane
(C) 979
Isornerization, A photochemically “switched-on” crown ether containing an intraannular 4-methoxyphenylazo substituent
(C) 866
Skeletal isomerization of the [Pt,(pPPh,),Ph(PPh,),] cluster by recrystallization in various solvents (C) 861
Isotope Effect, 15N-29Sicoupling constants
and 15N isotope effect on ”Si chemical
shifts in compounds with natural isotopic
abundance (C) 568
KETENES, First 1,4-dipolar cycloadditions
4of 6-0~0-3,6-dihydro-l-pyrimidinium
olates to ketenes and other carbonyl compounds (C) 608
Novel carbonylcyclopropane dimers and
trimers-free ketenes or organometallic
intermediates? (C) 605
Ketenylidenetriphenylphosphorane, Chainlengthening difunctionalization of Grignard compounds by reaction with ketenylidenetriphenylphosphorane (C) 405
Ketocarboxylic acid derivatives, Isolation of
the (Q-enols of P-ketocarboxylic acid derivatives (C) 350
Ketoketene, Primary adduct, y-ketoketene,
and some subsequent products of the reac-
tion of methyl 6-0x0-5-phenyl- 1,3,4-oxadiazinecarboxylate with norbornene (C)
886
Ketones, New bicyclic ketones and the stereochemistry of their reaction with carbanions (C) 972
Kinetics, Solvent exchange on magnesium([l5]crown-5) complexes-a first- and
second-order reaction (C) 575
P-LACTAM antibiotics, Recent developments in the field of p-lactam antibiotics
(R) 180
Lactones, Chemoselective multicomponent
synthesis of a$-unsaturated esters and
lactones and of their Diels-Alder adducts
(C) 790
First a-methylene-P-peroxylactone-regiospecific ene reaction of ‘0, with a,P-unsaturated carboxylic acids (C) 1070
Highly enantioselective intramolecular
hetero Diels-Alder reactions for the synthesis of enantiomerically pure tricyclic
lactones (C) 784
Oxidation of a,B-unsaturated esters and
lactones with selenium dioxide to y-0x0
or y-hydroxy derivatives; synthesis of
(+_)-A26771 B and norpyrenophorin (C)
79 1
Pd”-catalyzed stereoselective bis-lactonization (C) 1045
Lanthanide compounds, Cleavage of tris(cyclopentadieny1)lanthanide complexes
with alkyllithium compounds-a
new
route to alkylbis(cyclopentadienyl)lanthanides (C) 225
Lanthanum compounds, cis-Triaza-tris-ohomobenzene as tridentate ligand
[La(C,H,N,),~CH3CN~(C10,),]:
LaNi2
complex with icosahedral coordination
(C) 318
Large cavities, “In-out“-isomeric large cavities and their differing guest selectivity
(C) 219
Large carbocyclic cavities for the selective
inclusion of organic guest molecules in
aqueous solution (C) 221
Laser photolysis, Sensitized UVAaser photolysis of azoalkanes: conformational influences on intersystem-crossing and lifetimes of triplet diradicals (C) 1071
Layer structure, (Te2),(lz)-an unusual intercalation compound (C) 393
Lead compounds, Multiple bonds between
“naked” lead and transition metals-the
first example (C) 1062
Lead-manganese double bond, Multiple
bonds between “naked” lead and transition metals-the first example (C) 1062
Ligands, A dithioester as allylic-type 4e ligand(C)971
Cyclodextrins as second sphere ligands
for transition metal complexes-the X-ray
crystal structure of [Rh(cod)(NH,)Z.a-cyclodextrin][PF6].6 H 2 0 (C) 786
Disulfur monoxide as complex ligandpreparation and molecular structure of
[(II-C,Me5)Mn(CO),(S,0)1 (C) 515
Fragmentation and recombination of CS,
and CSSe in the coordination sphere of
platinum metals (C) 5 18
Hexaphosphabenzene as complex ligand
( C i 351
[La(C,H,N,),.CH,CN .(CIO4),]: LaN,,
comdex with icosahedral coordination
(C)3’18
d6-Metal complexes of 4,4‘-bipyrimidine,
an ambident ligand with high n-acceptor
ability (C) 430
Phosphorus, arsenic, antimony, and bismuth multiply bonded systems with low
coordination number-their role as complex ligands (R) 924
Synthesis, structure, and reactivity of q31 -azaallylmolybdenum complexes (C)
422
Transformation of [{(CO),W),Sn] into
[((CO)5W)3Te2],a compound containing
unusually bonded ditellurium (C) 428
Angeu,.
Cliem. Inr. Ed. Engl. 24 i l Y H S J No. 12
inclusion of organic guest molecules in
aqueous solution (C) 221
Macrolide antibiotics, Oxidation of a,p-unsaturated esters and lactones with selenium dioxide to y-0x0 or y-hydroxy derivatives; synthesis of (?)-A 26771 B and
norpyrenophorin (C) 791
Macrolides, The structure of the lichen macrolide (+)-aspicilin (C) 987
Magic-angle-spinning N M R spectroscopy,
Probing the structure and crystallinity of a
lithium silicate glass by "Si magic-anglespinning N M R spectroscopy (C) 61
Magnesium-anthracene systems, Synthesis
and structure of 1,4-dimethylanthracenemagnesium. 3 thf and k-trichlorodimagnesium.6 thf(1 +) anthracenide (C) 960
Magnesium hydride, Catalytic synthesis of
organolithium and organomagnesium
compounds and of lithium and magnesium hydrides-applications
in organic
synthesis and hydrogen storage (R) 262
Magnesium([l5]crown-5) complexes, Solvent exchange on magnesium([ 1 51crown5) complexes-a first- and second-order
reaction (C) 575
Magnetic properties, Dinuclear complexes
with predictable magnetic properties (R)
834
Manganese dioxide, Computer-controlled
precipitation of metal hydroxides and hydrous oxides-preparation of manganese
dioxide having uniform particle sizes (C)
1057
Manganese-sulfur compounds, The species
[Mn(S2C6H,Me),]"- : mononuclear manganese complexes with square-planar
(n = I ) and distorted tetrahedral ( n = 2)
sulfur coordination (C) 117
MAS NMR spectroscopy, Phosphorus-substituted thioformamides and thioformimidates: molecular structure and solid state
"C-NMR spectra (C) 715
Probing the structure and crystallinity of a
lithium silicate glass by 29Si magic-anglespinning N M R spectroscopy (C) 61
Mass
spectrometry,
CI2C-CI-CIo',
Cl,C-CI-BraQ,
and Br,C-Br-CI0'
by
gas-ghase
decarbonylation
of
CX,COY
(C) 869
Combination of chromatographic separation methods with mass spectrometry-a
modern technique for studying metabolism (R) 45 I
Materials science, Growth and dissolution
of organic crystals with "tailor-made" inhibitors-implications in stereochemistry
and materials sciene ( R ) 466
Membrane electrodes, Bioelektrochemische
Membranelektroden (B) 355
Membranes, Mechanisms of biological ion
transport-carriers, channels, and pumps
in artificial lipid membranes (R) 905
Sealing and opening porous monolayer
vesicle membranes (C) 339
Mercury compounds, Synthesis and structure of new Hg-Te
polyanions:
[ H P T ~ , , ] ~ " ,a cluster containing TeZQ,
TeZe, and Te:" ligands and [Hg,Tej]", a
MACROCYCLES, A macrobicyclic recepnew one-dimensional inorganic polymer
tor molecule for the diquat dication (C)
58 I
(C) 433
Merrifield synthesis, Solid phase synthesis
Cyclodextrins as second sphere ligands
(Nobel lecture) (R) 799
for transition metal complexes-the X-ray
Metabolism, Combination of chromatogracrystal structure of [Rh(cod)(NH,), 'a-cyclodextrin][PF,].6 H 2 0 (C) 786
phic separation methods with mass specDiamminebis( 1,5-cyclooctadiene)(pL-1,4,10,
trometry-a modern technique for study13-tetraoxa-7,16-diazacyclooctadecaneing metabolism (R) 451
N', N ")dirhodiumbis(hexafluorophosMetabolites, Reactive metabolites of carciphate): an example of simultaneous first
nogenic polycyclic hydrocarbons: syntheand second sphere coordination (C) 135
sis and trapping reaction of 9-hydroxybenzo(n)pyrene 4,5-oxide (C) 699
First sixfold bridge-formation in one step
Metallocenes, Reactive organometallic com(C) 794
pounds obtained from metallocenes and
Hostiguest chemistry of organic onium
related compounds and their synthetic apcompounds-clathrates, crystalline complications (R) 295
plexes, and molecular inclusion comTorsional isomerism in metallocenes: hinpounds in aqueous solution (R) 727
dered Cp-rotation in (s-cis-q-butadiene).
"In-out"-isomeric large cavities and their
differing guest selectivity (C) 219
bis(q-/err-butylcyclopentadieny1)zirconium
Large carbocyclic cavities for the selective
(C) 321
cis-Triaza-tris-c3-homobenzeneas tridentate ligand Tricarbonyl( 1,3-diphosphaall I)cobalt, a phosphorus analogue of
(q~ally1)tricarbonylcobalt(C) 420
Tridentate oxygen ligands as cyclopentadienyl equivalents: structure and properties of [LRh(p-CO),RhL], L- =[(CjH5)Co
U'(O)R,JJ (C) 683
Ligand sphere, Reactions in the ligand
sphere of iron(]]): synthesis of crown
ethers (C) 858
.ipid membranes, Mechanisms of biological
ion transport-carriers,
channels, and
pumps in artificial lipid membranes (R)
905
ipopeptide mitogens, Increased production
of specific antibodies by presentation of
the antigen determinants with covalently
coupled lipopeptide mitogens (C) 872
.iposomes, Photoreactions of N-( l-pyridinio)amidates in monolayers and liposomes (C) 882
.iposome formation, A nucleolipid with
antiviral
acycloguanosine as head
group-synthesis and liposome formation
(C) 501
.iquid crystals, Axial chirality can lead to
chiral smectic and cholesteric liquid crystals (C) 64
Smectic liquid crystals, textures and structures (B) 891
.ithiurn alkylsulfones, Lithium-coordinated
a-sulfonyl carbanions: synthesis and
X-ray
structure
determination
of
I ( C H Z ( S O , C , H S ) J L ~ ( ~(C)
~ ~859
~~)~Z
,ithiurn compounds, Pentamethyldiethylenetriamine(phenyl)lithium, a monomeric
organolithium compound (C) 2 15
.ithiurn hydride, Catalytic synthesis of organolithium and organomagnesium compounds and of lithium and magnesium
hydrides-applications in organic synthesis and hydrogen storage (R) 262
.ithium methyleneamides, The crystal and
solution structures of the complexes
[rBuzC=NLi.0=P(NMe2),], (C) 328
Lithium silicate glass, Probing the structure
and crystallinity of a lithium silicate glass
by '9Si magic-angle-spinning NMR spectroscopy (C) 61
Lithium-titanium exchange, Dilithio(phenylsulfonyl)trimethylsilylmethane: synthesis, "C/'H-NMR characterization, and
lithium-titanium exchange (C) 696
1,l- and I,o-dilithioallyl phenyl sulfone:
synthesis, geminal cycloalkylation, and lithium-titanium exchange (C) 610
Lone pair of electrons, "Stereochemical activity" of a lone pair of electrons o n low
valent elements of the 4th main group:
(GeNrBu),. 2 AICI, and (SnNrBu),. 2AlCll
(C) 223
Lutetium compounds, A novel route to pentamethylcyclopentadienyllutetium alkoxides and thiolates (C) 985
A n g e ~ ' .Chem. I n r . Ed. Engl. 24 119851 No. I 2
@
Metal-metal bond, (NEt4)2[CI3Mo(p-Sz)(pCl),MoCI,], a paramagnetic molybdenum(1v) compound with a metal-metal
bond(C)689
Reaction of small molecules with the binuclear complex [(p-CjHs)(p-Br)Pd2(PR&1:
addition without cleavage of the metalmetal bond (C) 516
Methanoaza[lO]annulene, 3,8-Methanoaza[lO]annulene (homoisoquinoline) (C) 592
Methemerythrin model compounds, Reactivity of the [Fe2(p2-O)(p-acetato)2]unit in
methemerythrin model compounds towards NY and NCS" (C) 392
Methoxybicyclo[2.2.2]octenones, Photochemistry of I-methoxybicyclo[2.2.2]octenones:
photolytic cyclopropane cleava e of the
initially formed tricyclo[3.3.O.Oz5]octan-3ones (C) 763
Methoxylation, Electrochemical methoxylation of antipyrine (C) 864
Methyl
acrylate,
Carbonyliron-assisted
coupling of cyclopolyenes with methyl
acrylate (C) 353
Methylalumoxane, Polymerization of propene and butene with a chiral zirconocene
and methylalumoxane as cocatalyst (C)
507
a-Methylene-y-butyrolactones,
Synthesis
and biological activity of a-methylene-ybutyrolactones (R) 94
Methylene-I-cyclopentenes,4-Methylene-lcyclopentenes from methylenecyclopropanes and alkynyltrimethylsilanes (C)
316
a-Methylene-B-peroxylactone, First a-methylene-P-peroxylactone- regiospecific
ene reaction of '0, with a$-unsaturated
carboxylic acids (C) 1070
Methyl migration and transannular 1,5-hydride shift on oxidative cleavage of C-Pd
bonds with CuCl, (C) 207
Methyl 2,3,O-isopropylidene-B-~-apio-L-f~ranoside, Photochemical synthesis of an
L-erythrose building block and its use in
the preparation of methyl 2,3,0-isopropylidene-P-L-apio-L-furanoside
(C) 877
Micelles, Enzymes hosted in reverse micelles in hydrocarbon solution (R) 439
Microemulsions, Phase behavior of ternary
systems of the type H,O-oil-nonionic
amphiphile (microemulsions) (R) 654
Minisci reaction, Marked increase in the
regioselectivity of radical substitution:
Minisci reaction in a two-phase system
(C) 692
Model systems, An organoboron model
system for the Fischer-Tropsch synthesis
(C) 572
Modern synthetic methods 1983. Vol. 3:
Transition metals in organic synthesis (B)
233
Modification, c-Ti&, a new modification of
titanium disulfide with cubic structure (C)
67
Molybdenum compounds, Synthesis of [(qJCSHS)ZM~(qZ-CH20)]:
a formaldehyde
complex of molybdenum (C) 402
Molybdenum(1v) compounds, The complex
(NE~~)Z~CI,MO(~-SZ)(~-CI),M
a ~paCI,],
ramagnetic molybdenum (IV) compound
with a metal-metal bond (C) 689
Molybdenum-sulfur compounds, Novel
MoFeS clusters from [(CsMeJ)2MoSS,I
and Fe(CO)s or Fez(C0)9 (C) 133
Synthesis of [(CSMeS)zMoZXS,Co(CO)zl
clusters (X = P, As) and structural characterization of a pLz,q2-AsS
ligand (C) 132
Monoclonal antibodies, Derivation and diversification of monoclonal antibodies
(Nobel lecture) (R) 827
Monoclonal antibodies, their chemistry,
functions, and possible uses (R) 139
Monolayer vesicle membranes, Sealing and
opening porous monolayer vesicle membranes (C) 339
Multicomponent synthesis, Chemoselective
multicomponent synthesis of n,p-unsatu-
1087
rated esters and lactones and of their
Diels-Alder adducts (C) 790
Multicomponent systems, Phase behavior of
ternary systems of the type HzO-oilnonionic amphiphile (microemulsions)
(R) 654
Multiple bonds between "naked" lead and
transition metals-the first example (C)
1062
butadienediide . 2 tetramethylethylenediamine (C) 863
Organomercury hydrides, Syntheses with radicals-C-C bond formation via organotin
and organomercury compounds (R) 553
Organometallic compounds, Oxidation of organometallic compounds (R) 274
Reactive organometallic compounds obtained from metallocenes and related
compounds and their synthetic applications (R) 295
The chemistry of the metal-carbon bond.
Vol. I : The structure, preparation, thermochemistry and characterization of organometallic compounds (B) 75
Organostibanes, (C6H5Sb)6.(1,4-dioxane), the
first cyclohexastibane (C) 72
Organotin hydrides, Syntheses with radicals-C-C bond formation via organotin
and organomercury compounds (R) 553
Oxacarbenes, Bicyclic acetals from oxacarbenes (C) 1043
Oxadiazole, Can 1,2,3-oxadiazole be stable?
(C) 713
Oxidation of a,p-unsaturated esters and lactones with selenium dioxide to y-0x0 or y-hydroxy derivatives; synthesis of (+)-A 26771
B and norpyrenophorin (C) 791
Oxidation of organometallic compounds (R)
274
0 x 0 bridges, [(qS-C5Me5)Cr02]z-a dinuclear
0x0-complex of chromium(v) (C) 601
0 x 0 ligands, Nitrogen monoxide as a source
for 0x0 ligands-acetylene-oxo complexes
of tungsten (C) 497
Oxygen ligands, Tridentate oxygen ligands as
cyclopentadienyl equivalents: structure
and properties of [ L I U I ( ~ - C O ) ~ R ~ L ] ,
L- =[(C,H,)Co!P(O)R,lsI- ,(C) 683
OCTABISVALENE derivatives, an octabisOxygen-sulfur anions, Reactivity of bis(q6valene derivative, (Z)-3,7-Bis(ghenylsuIbenzene)chromium(O) toward sulfur dioxSynthesis
and
structure
of
the
fonyl)pentacyclo[5. 1.0.02~4.03~5.0
,S]octane
ide: formation and structure of [($[Ni38Pt6(C0)48H6-n]n- ( n = 5, 4) ions: Ni(C) 41 1
C6H6)2Cr]2S4010,
a salt containing the anPt clusters as models for "cherry" crystal- Octaphenyldiazahexaphosphocine, Octaphion [SZO6.2SO2lzQ
(C) 967
lites (C) 697
enyl- 1,5,2hs,3,4h5,6h5,7,8~5-diazahexaphos- Ozonides, Crystal structures of potassium
Nitrile imines: thermal generation, direct
phocine (C) 580
ozonide and rubidium ozonide (C) 54
observation, and subsequent trapping (C)
a-Olefins, Novel polymerization of a-olefins
56
with the catalyst- system nickel/aminoNitrogen fixation, [p-NZHz(Ru(PPh3)dttdJ~], bis(imino)phosphorane (C) 1001
PARAMAGNETIC transition-metal comthe first diazene complex with sulfur-coplexes, The first application of 2D-NMR
Oligonucleotides, Three-phase synthesis of
ordinated transition
metal
centers
to the spectral analysis of a paramagnetic
oligonucleotides (C) 685
(dttdz- = 2,3,8,9-dibenzo-1,4,7,lO-tetrathi- Oligosaccharide syntheses, Preparation of an
complex. Example: bis[R-( +)-P,P-diethadecane( -2) (C) 981
ylthiophosphinic acid-Ka-methylbenzN-acetylneuraminic acid-containing trisacNitrogen homocycles, Direct structural
ylamido]nickel(~~)
(C) 23 1
charide and its use in oligosaccharide synproof for the pentazole ring system in soPaterno-Biichi reaction, Photochemical syntheses (C) 128
lution by "N-NMR spectroscopy (C)
thesis of an L-erythrose building block
Olive fly, Spiroacetal formation by carbene
513
and its use in the preparation of meth(carbenoid) insertion reaction: synthesis of
Stable triaziridines (C) 341
yl 2,3,O-isopropylidene-p-L-apio-L-furanothe major constituent of the sex attractant
Nitrogen monoxide as a source for 0x0
side (C) 877
of the olive fly (Dacus oleae) (C) 230
ligands-acetylene-oxo complexes of tungPentaaqua(0-hydroxyaIkyl)chromium(111)
Onium compounds, Host/guest chemistry of
sten (C) 497
complexes, Cleavage of an ether bond via
organic onium compounds-clathrates,
Nitrogen silicon double bond, Isolation of
p-elimination
of
ethanol
from
crystalline complexes, and molecular incluthe stable silaketimine t B u 8 = N-SitBu,
sion compounds in aqueous solution (R)
[(Hz0)5CrCH2CHz0CzHS]z+
in aqueous
(C) 1053
727
solutions; a pulse radiolysis study (C)
Nitrosyl complexes, Cationic thionitrosyl
779
Optimization of syntheses, SiCI2: photoelecand nitrosyl complexes (C) 202
Pentaazadiene, Complexes of 1,5-di(ptolyl)tron spectroscopic optimization of various
N M R Spectroscopy, A new method for desyntheses (C) 205
1,4-pentaazadien-3-ide, crystal structures
termining enantiomeric excess, where the
Organic synthesis, Enzymes as catalysts in
of [Cu(tolylNNNNNtolyl)1, and [Ni(tolsample serves as its own reference (C)
synthetic organic chemistry (R) 617
y l N N N N N t ~ l y l ) (C)
~ ] ~409
315
Pentacoordination, (CH3)2NSFfA~F,e
- the
New pathways for organic synthesis. PracComplete signal assignment of the I3Ctical applications of transition metals (6)
synthesis and stability of a simple pentaNMR spectra and structure determination
coordinated sulfur(v1) cation (C) 344
613
of corrinoids by 2D-INADEQUATE and
PentamethylcyclopentadienyllutetiumalkoxSelectivity-a goal for synthetic efficiency.
2 D "C,'H-NMR chemical shift correlaides, A novel route to pentamethylcycloWorkshop conferences Hoechst. Vol. 14 ( 8 )
tion using "J(C,H) (C) 333
pentadienyllutetium alkoxides and thio614
N M R and chemistry. An introduction to
lates (C) 985
Organoaluminum compounds, Formation of
the Fourier transform-multinuclear era
Pentamethylcyclopentadienylmetalcomplexorganoaluminum compounds in the mix(B) 355
es, (q5-C5Me5)zFezSqand (q5-C5Me5)zture AIC13-TiC14-AI-CzH,
(C). 31 1
5N-29Sicoupling constants and I5N isoOrganoaluminum reagents, Selective reacCo2S4, two novel bis(pentamethylcyc1otope effect on 29Si chemical shifts in compentadienylmetal) complexes rich in sultions using organoaluminum reagents (R)
pounds with natural isotopic abundance
fur (C) 1060
668
(C) 568
Organolithium compounds, On the aggregaPentazole ring system, Direct structural
Selective 'H,"C-NOE difference specproof for the pentazole ring system in sotion of lithiated bicyclobutane derivatives
troscopy for the elucidation of structures
lution by I5N-NMR spectroscopy (C)
in solution (C) 404
Pentamethyldiethylenetriamine(phenyl)lith513
( C ) 705
ium, a monomeric organolithium comPeptide analysis, Sequencing of short pep"N-NMR spectroscopy, Direct structural
tides using FAB mass spectrometry-inpound (C) 215
proof for the pentazole ring system in socreased information via derivatization (C)
Polymorphism
of
an
organolithium
comlution by "N-NMR spectroscopy (C)
pound:
dilithium
1,2-diphenylbenzocyclo408
513
Nobel lectures, Derivation and diversification of monoclonal antibodies (R) 827
From the structure of antibodies to the diversification of the immune response (R)
816
Solid phase synthesis (R) 799
The generative grammar of the immune
system (R) 810
Nomenclature, A simple notation system for
transition-metal clusters (C) 45
Non-benzenoid
conjugated
carbocyclic
NATURAL PRODUCTS, A simple approcompounds (B) 1007
ach to the naphtho[ 1,8-bc]pyrandione syNonclassical cations, Destabilized 2-norborstem (C) 71 1
nyl cations (C) 55
Crinipellins, the first natural products
Norbornyl cations, Destabilized 2-norbornyl
with a tetraquinane skeleton (C) 709
cations (C) 55
Synthesis and biological activity of a-meNorpyrenophorin, Oxidation of a$-unsatuthylene-y-butyrolactones (R) 94
rated esters and lactones with selenium
The chemistry and antibiotic activity of
dioxide to y-0x0 or y-hydroxy derivatives;
the toadstool Agaricus xanthoderma (agasynthesis of (+)-A 26771 B and norpyrricales) (C) 1063
enophorin (C) 791
Neutrocyanines, AzahexamethineneutrocyNucleolipids, A nucleolipid with antiviral
anines from a N-(tetramethylformamidinacycloguanosine as head group-syntheio)pyridinium salt (C) 511
sis and liposome formation (C) 501
Nickelaazadiphos hetidine, Chelate ligandNucleophilic addition, Stereoselective nucontrolled ql-q change of coordination
cleophilic additions to a bicyclic ketone
in amino(imino)phosphane ligands and
controlled by a remote tricarbonyl(ditheir conversion into a nickelaazadiphosene)iron moiety (C,) 787
phetidine (C) 525
Nucleophilic reactions, Reactions of
Nickel clusters, Amino(imino)phosphanes
per(chloro,fluoro)ethanes with aryloxide
as face-bridging complex ligands (C) 115
and alkoxide ions-evidence for chloroNew C o and Ni clusters with Se and PPh3
as ligands: [ C O ~ ( ~ ) - S ~ ) ~ ( P[CO&P ~ ~ ) ~ ] , philic attack on C-CI bonds (C) 871
Nucleosides, Synthesis of I ,4-dihydropyriSe)x(PPh&l, [Cog(p4-Se)3(p3-Se)8(pph3)61,
dine nucleosides by photochemical cycloand (N~~~(p~-Se)~(llq-Se)~a(PPhs)~oI
(C)
addition (C) 127
993
Synthesis of 3'-C-methyl-2'-deoxyribonuNovel cobalt- and nickel-clusters with S
cleoside with methylmagnesium iodide
and PPh3 as ligands; crystal structures of
(C) 52
P
1088
Angen. Chem. Ini. Ed. Engl. 24 (1985) No. 12
Peptides, Applications of synthetic peptides
(R)719
Exhaustive tert-butoxycarbonylation of
peptide nitrogens (C) 510
Peptide synthesis, Basic principles of protease-catalyzed peptide bond formation
(R) 85
Principles of peptide synthesis (B) 527
Solid phase synthesis (Nobel lecture) (R)
799
Per(chloro,fluoro)ethanes, Reactions of per(chloro,fluoro)ethanes with aryloxide and
alkoxide ions-evidence for chlorophilic
attack on C-CI bonds (C) 871
Peroxylactone, First a-methylene-p-peroxyiactone-regiospecific ene reaction of ’02
with a,P-unsaturated carboxylic acids (C)
1070
PE Spectroscopy, SiCIz: photoelectron spectroscopic optimization of various syntheses (C) 205
Phanes, First sixfold bridge-formation in
one step (C) 794
The first [2.1] phane: a new helical molecular skeleton (C) 885
Pharmaceutical chemistry, Einfiihrung in
die Pharmazeutische Chemie (B) 797
Phase behavior of ternary systems of the
type H,O-oil-nonionic
amphiphile
(microemulsions) (R) 654
Phenylcarbene, Reaction of phenylcarbene
with oxygen (C) 988
(o-Phenyleno)naphthalenes, Synthesis of the
first linear (o-pheny1eno)naphthalenes; a
new class of benzenoid aromatics (C)
114
Phenyl silaisocyanide: the first organosilicon compound with a formal Si = N triple
bond (C) 111
Pheromones, Spiroacetal formation by carbene (carbenoid) insertion reaction: synthesis of the major constituent of the sex
attractant of the olive fly (Dacus oleae) (C)
230
Phosphaalkene ligands, Tricarbonyl( 1,3-diphosphaallyl)cobalt, a phosphorus analogue of (q3-allyl)tricarbonylcobalt (C)
420
Phos haalkenyl complexes, The species Z[(q P-CsH5)(CO)zFe- P = C(OSiMe,)(tBy)],
a phosphaalkenyl-complex wlth FeP single bond (C) 604
Phosphaalkenylrhenium
complexes-a
novel class of substances with P = C bonding (C) 53
Phosphaallyl cations, 2-Phosphaallyl cations. How is phosphorus bound in 2phospha- and ’2-“phosphoniaallyl” cations? (C) 764
Phosphane, Novel aspects of the coordination chemistry of phosphane (C) 68
2-“Phosphoniaallyl” cations, How is phosphorus bound in 2-phospha- and 2-“phosphoniaallyl” cations? (C) 764
Phosphonic acids, Asymmetric addition of a
chiral cyclic phosphite to a cyclic iminesynthesis of a phosphonic acid analogue
of D- and L-penicillamine ( c ) 1067
Phosphorus cations, Symmetrical and unsymmetrical triphosphenium ions (C) 226
Phosphorus compounds, Preparation and
structure of a diphosphorus compound
with positive charges on the two directly
bonded phosphorus atoms (C) 975
Phosphorus-nitro en heterocycles, Octaphenyl- I ,5,2hs,3,4h5,6h5,7,8hs-diazahexaphosphocine (C) 580
Phosphorus ylides, Isocyanomethylenetriphenylphosphorane (C) 979
Photochemical initiation, Photochemically
initiated, electron-transfer-catalyzed DielsAlder reactions of electron-rich dienophiles (C) 412
Photochemistry, A photochemically “switched-on” crown ether containing an intraannular 4-methoxyphenylazo substituent ( C ) 866
Cationic 2-azaallenylidene complexes,
Angew. Chrm. Inr. Ed. Engl. 24 11985) N o . 12
novel compounds with unusual photochedoubly linked to quinones by hydrocarmical properties (C) 121
bon chains (C) 1003
Photocycloaddition, 1,4-Photocycloaddition
Total synthesis of (+)-bonellin dimethyl
of a-morpholinoacrylonitrile to I-acylester (C) 775
Potassium ozonide, Crystal structures of ponaphthalenes (C) 1048
tassium ozonide and rubidium ozonide
Photoisomerization, E-t Z-Photoisomerization of a diphosphene on carbonylmetal
(C) 54
complexes (M=Cr, Mo, W) (C) 211
Precipitation, Computer-controlled precipiPhotolysis, Laser photolysis of the bisazotation of metal hydroxides and hydrous
alkane 7-syn,7’-anti-bis-2,3-diazabicyclo- oxides-preparation of manganese dioxide having uniform particle sizes (C)
[2.2.l]hept-2-ene (C) 421
1057
Sensitized UVAaser photolysis of azoalPrimary adduct, y-ketoketene, and some
kanes: conformational influences on insubsequent products of the reaction of
tersystem-crossing and lifetimes of triplet
diradicals (C) 1071
methyl 6-oxo-5-phenyl-1,3,4-oxadiazinePhotooxidation of chloroform: isolation and
carboxylate with norbornene (C) 886
characterization
of
trichloromethyl
Proteases, Basic principles of protease-catahydroperoxide (C) 50
lyzed peptide bond formation (R)85
Photooxygenolysis of vitamin B I Z(C) 62
Protecting groups, Exhaustive tert-butoxyPhotopolymerization, Sources and applicacarbonylation of peptide nitrogens (C)
tions of ultraviolet radiation (B) 796
510
Photoreaction of thiones with bromoketene
Protein biosynthesis, The 3’-end of tRNA
acetals (C) 976
and its role in protein biosynthesis (R)
Physical chemistry, Molekiile und Molekiil37 1
anhaufungen. Eine Einfiihrung in die
Proteins, The construction of new proteins
physikalische Chemie (B) 235
and enzymes-a prospect for the future?
Platinum hvdrides. Svnthesis and structure
(R) 639
of [Pt,(i-H)(p-CHkH2Ph)(diphos),l[BF4] Proton exchange between arenium ions and
(C) 120
arenes in the gas phase (C) 693
Prussian blue, Polymeric tris[trimethylPolyanions, Synthesis and structure of new
tin(~v)]hexacyanocobaltate(~~~),a comHg-Te polyanions: Hp4TelZI4’, a cluster
pound non-analogous to “super prussian
containing TeZe, Tei’, and Te:’ ligands
blue”, and its tris[tricyclopentadienyluraand [HgzTe,lzo, a new one-dimensional
nium(iv)] homologue (C) 879
inorganic polymer (C) 433
Pulse radiolysis study, Cleavage of an ether
Synthesis and structure of new potassiumbond via /%elimination of ethanol from
gold-tellurium ~ ~ l y a n i o n s[KAU~T~,]~’,
:
[(H20)5CrCH2CH,0C2H5]2+.
in aqueous
[KzAu4Te4(en)4] , and [K2Au,Te4(dmf)Zsolutions; a pulse radiolysis study (C)
(CH30H)Z]Z’(C) 432
779
Polycycles, Laser photolysis of the bisazoalkane 7-syn,7’-anti-bis-2,3-diazabicyclo- Purines, Synthesis of 6-substituted purines
[2.2.l]hept-2-ene (C) 421
and ribonucleosides with N-(6-purinyl)New bicyclic ketones and the stereochepyridinium salts (C) 1054
mistry of their reaction with carbanions
Purinylpyridinium salts, Synthesis of 6-sub(C) 972
stituted purines and rihonucleosides with
Polycyclic hydrocarbons, A three-blade proN-(6-purinyl)pyridinium salts (C) 1054
peller compound with seven bracketed
Purpurogallin formation, Mechanism of
benzene rings(C)222
purpurogallin formation: an adduct from
Reactive metabolites of carcinogenic po3-hydroxy-o-benzoquinoneand 4,5-dimelycyclic hydrocarbons: synthesis and trapthyl-o-benzoquinone (C) 224
ping reaction of 9-hydroxybenzo[a]pyrene
Pyrazolotriazines, Coupling of 3-diazo-3H4,5-oxide (C) 699
pyrazoles with 2-alkoxy-1,6-methano[lO]Polycyclic quinones, Synthesis of cyclohepannulenes and oxidative cyclization to pyta[a]phenalene-6,12-dione (C) 757
razolotriazines (C) 346
Polymerization, Highly active ylide-nickel
Pyrazolylium salts, (Bis)dimethylamino-pyrcatalysts for the polymerization of ethylazoles and pyrazolylium salts (C) 984
ene (C) 599
Pyrethroids, Stereo- and enantioselective
Novel polymerization of a-olefins with
synthesis of both cis-chrysanthemic acid
the catalyst system nickel/aminobis(imimethyl esters in high optical purity (C)
no)phosphorane (C) 1001
996
Polymerization of propene and butene
Pyridine synthesis, Organocobalt comwith a chiral zirconocene and methylalupounds in the synthesis of pyridines-an
moxane as cocatalyst (C) 507
example of structure-effectivity relationPolymers, Chemistry and technology of waships in homogeneous catalysis (R) 248
ter-soluble polymers (B) 1073
Pyridi.nioamidates, Photoreactions of N-( 1Properties and applications. Vol. 8 : Polypyridinio)amidates in monolayers and
mer degradation and stabilization (B)
liposomes (C) 882
889
Pyrrole derivatives, Enantioselective hydro4-[Tri(n-butyl)]phosphinio-2,5-diselenoxosilylation of prochiral 3,4-dihydro-2H1,3-diselenacyclopentanide(C) 1058
pyrrole derivatives (C) 995
Polymer spectroscopy, Polymers. Properties
Pyrrolylidene ethanide, Synthesis of a novel
and applications. Vol. 7: Introduction to
stable carbanion: 1,1,2-tricyano-2-(3,4polymer spectroscopy (B) 717
dicyano-5-imino-2,5-dihydro1 H-pyrrolPolymorphism of an organolithium com2-y1idene)ethanide by reduction of tetrapound: dilithium 1,2-diphenylbenzocyclocyanoethylene with tris(2,2’-bipyridine)tibutadienediide . 2 tetramethylethylenediatanium (C) 426
mine (C) 863
Polypeptide antibiotic, Elucidation of the
QUINONES, para-Quinodimethanes, Bisstructure of epidermin, a ribosomally syn(tricarbony1iron)-para-quinodimethanes:
thesized, tetracyclic heterodetic polypeppreparation and molecular structure (C)
tide antibiotic (C) 1051
52 I
Polypeptides, Applications of synthetic pepSynthesis of cyclohepta[a]phenalene-6,12tides (R) 719
dione (C) 757
Polysulfides, Transition metal polysulfides:
The synthesis of porphyrins doubly linked
coordination compounds with purely
to quinones by hydrocarbon chains (C)
inorganic chelate ligands (R) 742
1003
Poly(9,9’-spirobifluorene) crown ethers,
Chiral poly(9,9‘-spirobifluorene) crown
RACEMIZATION, Activation energy of the
racemization of optically active tricarboethers ( C ) 792
Porphyrins, The synthesis of porphyrins
nyl(tropone)iron complexes (C) 329
1089
Radialenes, [4]-Radialenes, An intermediate
and its secondary products in a nickel-catalyzed synthesis of [4]-radialenes (C) 496
Radialene tetracarboxylic ester, [4]Radialene tetracarboxylic ester, On the thermal
behavior of butatrienecarboxylic acid derivatives: crystal and molecular structure
of a [4]radialene tetracarboxylic ester (C)
852
Radical cations, A novel rearrangement in
(R2S...SR,)e-radical cations with a 3ebond (C) 73
CI7C-CI-Cloe.
CI,C-CI-BroG.
and
BriC- Br-CI @b' y $.s-phase decarbonylation of CX,COY
(C) 869
Radical ion pairs, On the role of radical ion
pairs in [4+ 21 cycloadditions (C) 337
Radical ions, Hyperfine coupling to I3C
nuclei in alkyl substituents-a contribution to the problem of C-C and C-H
hyperconjugation (C) 495
Radicals, Do Cp(CO)2Mn fragments stabilize radicals? (C) 856
Sensitized UVAaser photolysis of azoalkanes: conformational influences on
intersystem-crossing and lifetimes of triplet diradicals (C) 1071
Syntheses with radicals-C-C bond formation via organotin and organomercury
compounds (R) 553
Radical substitution, Marked increase in the
regioselectivity of radical substitution:
Minisci reaction in a two-phase system
(C) 692
Radwaste immobilization by structural modification-the
crystallochemical properties of SYNROC, a titanate ceramic (R)
357
Raney nickel, Gas-phase reactions of organic compounds on Raney nickel (C) 418
Reaction control, Stereoselective nucleophilic additions to a bicyclic ketone controlled by a remote tricarbonyl(diene)iron moiety (C) 787
Reaction dynamics, Chemical dynamics via
molecular beam and laser techniques (B)
43 5
Reaction mechanisms, Concerning the mechanism of the asymmetric Diels-Alder
reaction: first crystal structure analysis of
a Lewis acid complex of a chiral dienophile (C) 112
Determination of organic reaction mechanisms (B) 795
Novel carbonylcyclopropane dimers and
trimers-free ketenes or organometallic
intermediates? (C) 605
Novel polymerization of a-olefins with
the catalyst system nickel/aminobis(imino)phosphorane (C) 1001
Reaction of phenylcarbene with oxygen
(C) 988
Rearrangements, A novel rearrangement in
(RZS...SR2)0-radical cations with a 3ebond (C) 73
Dimerization of a C,B,-closo-carbaborane(5) to the C,B,-adamantane and its
22/32 valence isomerization to the CAB6nido-carbaborane(l0) (C) 326
Reactions of tricarbonyl(sorba1dehyde)iron with carbanions: a repeatable organometallic reaction with Fe(CO),-migration (C) 126
Synthesis and reactions of 4-azido-3-methyl-1,2-butadiene (C) 216
Thiophene derivatives by novel rearrangements of siloxy-substituted cyclopropanecarboxylates (C) 588
Walk rearrangement in the 1,2,3,4-tetra[err-butylhydroxycyclobutenyliumion (C)
429
Redox catalysis, Heterogeneous redox catalysis on Ti/TiO, cathodes-reduction of
nitrobenzene (C) 771
Reduction, Chiral compounds synthesized
by biocatalytic reductions (R) 539
Reduction of ketones by alkali metals in tertiary alcohols: unexpected cation effect
o n the stereochemistry (C) 499
1090
Reductive carbonylation of o-nitrophenol
with a Fe-Pd cluster-derived heterogeneous
catalyst;
CO
migration
in
[FePdPt(CO),(Ph,PCH2PPhZ)2](C) 768
Regioselectivity, Marked increase in the
regioselectivity of radical substitution:
Minisci reaction in a two-phase system
(C) 692
Repeatable organometallic reaction, Reactions of tricarbonyl(sorba1dehyde)iron
with carbanions: a repeatable organometallic reaction with Fe(CO),-migration (C)
126
Resolution, C h i d copper(i1) complexes for
the enantioselective resolution of DL-dansyl-amino acids by HPLC (C) 336
Direct enantiomer resolution of hydroxy
and carbonyl compounds by gas chromatography on Chirasil-Val (C) 48
Resonance concept, Calculation of the
charge distribution in conjugated systems
by a quantification of the resonance concept (C) 687
Retinal Schiff base, UV and CD suectroscopic evidence of the self-associdon of
a Schiff base of all-trans-retinal (C) 761
Retro-ene reactions, Novel retro-ene reactions of B-hydroxyacetylenes (C) 783
Reverse micelles, Enzymes hosted in reverse
micelles in hydrocarbon solution (R) 439
Rhenium compounds, Novel C-0 bond
formation via [3 21 cycloaddition of diphenylketene to a dioxo metal moiety (C)
860
Pentacarbonylolefin- and pentacarbonyldiolefinrhenium complex cations; synthesis and structure of the 2-butene-1,4-diylbridged
carbonyldirhenium complex
trans-[(OC)sReCH2CH= CHCH2Re(CO),]
(C) 505
Reductive trimerization of the trioxo halfsandwich complex [(qs-CcMes)ReO,] with
deoxygenation: the electron-deficient cluster ion [(r15-CsMes)3Rei(p-O)']2+ (C) 50
Rhodium complexes, Catalytic hydroboration with rhodium complexes (C) 878
Rhodium compounds, Cluster expansion
with Cp(C0)Rh fragments (C) 424
Ribonucleosides, Synthesis of 6-substituted
purines and ribonucleosides with N-(6puriny1)pyridinium salts (C) 1054
Rifampicin, Molecular mechanism of action
of the antibiotic rifampicin (R) 1009
Ring expansion, Bicyclic acetals from oxacarbenes (C) 1043
4-Methylene- I-cyclopentenes from methylenecyclopropanes and alkynyltrimethylsilanes (C) 3 I6
Ring inversion, Synthesis and dynamic properties of chiral heptalenes (C) 212
Ring opening, Azahexamethineneutrocyanines from a N-(tetramethylformamidini0)pyridinium salt (C) 51 I
RNA synthesis, Molecular mechanism of
action of the antibiotic rifampicin (R)
I009
Rubidium ozonide, Crystal structures of potassium ozonide and rubidium ozonide
(C) 54
Ruthenium-sulfur-diazene complexes, [pN2Hz(Ru(PPh3)dttdJr],the first diazene
complex with sulfur-coordinated transition metal centers (dttd'- =2,3,8,9-dibenzo- 1,4,7,10-tetrathiadecane(- 2)
(C)
98 1
Synthesis and structure of a thallium complex with an anionic sandwich complex ligand (C) 71
Sandwich compounds, 2,3-Dihydro-1,3-diborole-metal complexes with activated
C-H bonds: building blocks for multilayered sandwich compounds (R) 943
Reactions in the ligand sphere of iron(1r):
synthesis of crown ethers (C) 858
Selectivity -a goal for synthetic efficiency.
Workshop conferences Hoechst. Vol. 14
(B) 614
Selenium compounds, 4-[Tri(n-butyl)]phosphinio-2,5-diselenoxo- I ,3-diselenacyclopentanide (C) 1058
Self-association, UV and C D spectroscopic
evidence of the self-association of a Schiff
base of all-trans-retinal (C) 761
Sesquiterpene hydrocarbons, Catalytic
transformations of sesquiterpene hydrocarbons on alkali metal/aluminum oxide
(C) 320
Side chains, Carbonyliron-assisted coupling
of cyclopolyenes with methyl acrylate (C)
353
Silacycloalkynes, New silacycloalkynes with
up to four 1,4-disila-2-alkyne units in the
ring (C) 565
Silaketimine, Isolation of the stable silaketimine tBu,Si=N-SitBu,
(C) 1053
Silicon-carbon double bond, Isolation and
structure of a stable molecule containing
a silicon-carbon double bond (C) 229
Silver oxide, Ag20,, a novel binary silver
oxide (C) 118
Silyl ketene acetals, Enantio- and anti-diastereoselective aldol additions of acetates
and propionates via 0-silyl ketene acetals
(C) 874
Single
bond,
Z-[(q5-CSH5)(C0),FeP = C(OSiMe3)(tBu)], a phosphaalkenylcomplex with FeP single bond (C) 604
Skeletal isomerization of the [Pt&PPh2)3Ph(PPh3)2]cluster by recrystgllization in various solvents (C) 861
Sodium germanide, NaGe-high-pressure
formation of the NaPb-type structure (C)
500
Solid phase synthesis (Nobel lecture) (R)
799
Solid state chemistry, Amorphe und glasartige Festkorper (B) 1073
Solid state chemistry and its applications (B)
1073
Solid-state NMR spectroscopy, Phosphorussubstituted thioformamides and thioformimidates: molecular structure and solid
state "C-NMR spectra (C) 715
Solvates, Reactivity of bis(q'-benzene)chromium(0) toward sulfur dioxide: formation
and structure of [(q'-C,H,),Cr],S,O,,,
a
salt containing the anion [Sz06.2SO,]2e
(C) 967
Solvent exchange on magnesium([l5]crown5) complexes-a first- and second-order
reaction (C) 575
Sorbanilide, Nickel(0)-catalyzed synthesis of
sorbanilide from 1,3-penkidiene and phenyl isocyanate (C) 96 I
Spectral analysis, The first application of
2D-NMR to the spectral analysis of a paramagnetic complex. Example: bis[R-( +)f,f-diethylthiophosphinic acid-N-a-methylbenzylamido]nickel(rr) (C) 23 1
Spiroacetal formation by carbene (carbenoid) insertion reaction: synthesis of the
major constituent of the sex attractant of
the olive fly (Dacus oleae) (C) 230
SAKURAI REACTION, Allylation of aldeSpirobifluorene, Chiral poly(9,9'-spirobifluhydes with etherification by dialkoxyorene) crown ethers (C) 792
dichlorotitanium/allyltrimethylsilane; an
asymmetric variant of the Sakurai reacSpiroclusters, Synthesis and structure of the
spirocluster
[(qS-C5H,),Mo3As(CO)6tion (C) 765
Sandwich complexes, A new type of sand~CHP(C'H5)3lI ( C )702
wich complex formed by Ag and [Pt,(g~- Stabilization of radicals, Do Cp(CO),Mn
fragments stabilize radicals? (C) 856
COMPiPr&l (C) 766
Stannocene analogs, Bis(dihydro-1,2-azaNovel high-nuclearity HgCoRu and
HgCoFe sandwich complexes. Synthesis
borolyl)tin-a novel boron-nitrogen stanand
structure
of
[Hg{RuCo,(pnocene (C) 602
Stereochemical activity, "Stereochemical acCO),(CO)91~l(C) 767
+
Thiepinium ion, The homothiopyrylium
ion: generation and characterization (C)
214
Thiolate complexes, A new class of tantalum(v) dithiolate complexes: synthesis
and
characterization
of
[Ta($CSMe4R)(SCH= CHS)2] (R= Me, Et) and
[Ta(qS-CSMes)(SCH2CHZs),l
(C) 332
1
Stereochemistry, Growth and dissolution of
Thionitrosyl complexes, Cationic thionitrosyl and nitrosyl complexes (C) 202
organic crystals with “tailor-made” inhibiThiophene derivatives by novel rearrangetors-implications in stereochemistry and
ments of siloxy-substituted cyclopropanematerials sciene (R) 466
TARTARIC ACID, On the absolute concarboxylates (C) 588
Reduction of ketones by alkali metals in
figuration of (+)-tartaric acid (C) 513
tertiary alcohols: unexpected cation effect Tellurides, Novel reactions of acyl halides
Photoreaction of thiones with bromokeon the stereochemistry (C) 499
tene acetals (C) 976
with bis(trimethylsilyl) telluride: C,Te and
C,C bond formation (C) 1041
Stereoselective nucleophilic additions to a
Three-phase synthesis of oligonucleotides
bicyclic ketone controlled by a remote Tellurium compounds, Synthesis and struc(C) 685
ture of new Hg-Te
polyanions:
tricarbonyl(diene)iron moiety (C) 787
Through-bond interaction, Light-induced
[H&Te1z]4Q, a cluster containing TezQ,
Stereoselective synthesis, Chelation-control[2 +2] cycloaddition reactions of nonconTe2 , and Te:’ ligands and [Hg,Tes]2e, a
led stereoselective synthesis of cyanohyjugated dienes-the
effect of throughnew one-dimensional inorganic polymer
drins (C) 989
bond interaction (C) 566
(C) 433
Stereospecific synthesis of 3-substituted
Tin compounds, Synthesis, dynamic behaSynthesis and structure of new potassiumhexahydroindane derivatives (C) 131
vior, and structure of [Sn(C(PMez)3)z]-a
gold-tellurium Feolyanions: [ K A U ~ T ~ , ] ~ ~ homoleptic
,
Steroids, Selectivity of the anodic oxidation
tetraphosphanetin(I1) com[K,Au4Te,(en),] , and [KzAu4Te4(dmf)zof CH- and CH,-Groups; selective oxidaplex with pseudo trigonal bipyramidal
( C H , O H ) Z ] ~(C)
~ 432
tion of steroids at C-6 (C) 1055
structure (C) 402
(Te2)&,)--an unusual intercalation comStibanes, (C6HSSb),.(l,4-dioxane), the first
Titanate ceramic, Radwaste immobilization
pound (C) 393
cyclohexastibane (C) 72
by structural modification-the crystalloStrain, Consequences of strain for the struc- Tellurium-tungsten compounds, Transforchemical properties of SYNROC, a titamation
of
[{(CO),w,Sn]
into
ture of aliphatic molecules (R) 529
nate ceramic (R) 357
[((CO)s~3Te2],
a compound containing
Structure-effectivity relationships, OrganoTitanium cathodes, Heterogeneous redox
unusually bonded ditellurium (C) 428
cobalt compounds in the synthesis of
catalysis on Ti/Ti02 cathodes-reduction
pyridines-an example of structure-effec- Terpenes, Catalytic transformations of sesof nitrobenzene (C) 771
quiterpene hydrocarbons on alkali metal/
tivity relationships in homogeneous caTitanium disulfide, c-TiS,, a new modificaaluminum oxide (C) 320
talysis (R) 248
tion of titanium disulfide with cubic strucTetra-tert-butylhydroxycyclobutenyliumion,
S t i ucture revision, The revised structure and
ture (C) 67
Walk rearrangement in the 1,2,3,4-teabsolute configuration of chaksine (C)
Titanocene derivatives, [Cp2Ti(PMe&],-a
tra-tert-butylhydroxycyclobutenyliumion
959
versatile source of titanocene derivatives
(C) 429
Strychnine, The glycine receptor of rat spi(C) 394
nal cord: exploring the site of action of Tetracyanocyclopropane derivative, ReacToadstool, The chemistry and antibiotic action of homobenzvalene with tetracyanothe plant alkaloid strychnine (R) 365
tivity of the toadstool Agaricus xanthoethylene; formation of a tetracyanodihySulfine, Diethyl thioxomalonate S-oxide; a
derma (agaricales) (C) 1063
drobarbaralane derivative and a tetracysulfine as reactive intermediate (C) 855
Torsional isomerism in metallocenes: hinanocyclopropane derivative (C) 61 1
a-Sulfonyl carbanions, Lithium-coordinated
dered Cp-rotation in (s-cis-n-butadiene)a-sulfonyl carbanions: synthesis and X- Tetracyanodihydrobarbaralane derivative,
bis(q-&butylcyclopentadienyl)zircon’
Reaction of homobenzvalene with
ray
structure
determination
of
ium (C) 321
tetracyanoethylene; formation of a tetra[(CH~(S0~C,H,)~Li(tmeda)],
(c)859
Toxicology, Die Bleibelastung des Mencyanodihydrobarbaralane derivative and
X-ray structure determination of [a-(phenylschen (B) 614
a tetracyanocyclopropane derivative (C)
Trace analysis, Great fear of small amounts
su1fonyl)benzyllithium-tetramethylethy611
of elements-the significance of analytilenediamine],: chirality of an a-sulfonyl
Tetracyanoethylene, Synthesis of a novel
cal chemistry in our modern industriali“carbanion” (C) 573
stable carbanion: 1,1,2-tricyano-2-(3,4-dized community as exemplified by trace
Sulfur melts, Quantitative HPLC analysis
cyano-5-imino-2,5-dihydro1H-pyrrol-2element analysis (R) 485
and thermodynamics of sulfur melts (C)
y1idene)ethanide by reduction of tetracyTransition metal polysulfides: coordination
59
anoethylene with tris(2,2’-bipyridine)titaSulfur monoxide as 4-electron bridge-ligand
compounds with purely inorganic chelate
nium (C) 426
in the complex [((qs-CsHs)(CO),Mn)2SO] Tetrakis(trimethylsilyl)-l,6-methano[IOIanligands (R) 742
(C) 228
nulene, 2,5,7,10-Tetrakis(trimethylsilyl)- Transmembrane-neuraminidase, ConstrucSulfur-nitrogen rings, The X-ray crystal
tion of disaccharide N-glycopeptides1,6-methano[lO]annuIene,a fluxional vastructures of two 1,2,4,5-tetrathia-3,6-di- lence tautomer with cyclopolyolefin strucsynthesis of the linkage region of the
azacyclohexanes (C) 760
transmembrane-neuraminidase of an inture (C) 587
Sulfur-oxygen bonds, Comparison of theo- Tetraoxathia-2-cycloundecanone, Reaction
fluenza virus (C) 883
retical and experimental deformation
Triaza-tris-o-homobenzene, cis-Triaza-trisof ethylene oxide with sulfur dioxide in
densities in S - 0 bonds (C) 509
0-homobenzene as tridentate ligand
the presence of cesium ions: synthesis
Sulfur-silicon heterocycles, Decamethyl-7[La(C6H9N3)4.CH,CN .(C104)3]: LaN I
of 1,3,6,9,2h4-tetraoxathia-2-cycloundecacomplex with icosahedral coordination
thiahexasilanorbornane (CH3)loSi6S ( c )
none (C) 695
(C) 318
992
Tetraphosphanetin(I1) complex, Synthesis,
Triaziridines, Stable triaziridines (C) 341
Sulfur(v1) cation, (CH,),NSFyASF:-syndynamic behavior, and structure of
thesis and stability of a simple pentacoorTricarbonyl(sorbaldehyde)iron, Reactions of
[Sn(C(PMe2)3}2]-a homoleptic tetraphosdinated sulfur(v1) cation (C) 344
tricarbonyl(sorba1dehyde)iron with carbphanetin(l1) complex with pseudo trigonanions: a repeatable organometallic reacSuperconduction, fb(ET),Au12: an organic.
al bipyramidal structure (C) 402
tion with Fe(CO),-migration (C) 126
volume superconductor with T,=3.2 K at Tetraqulnanes, Crinipellins, the first natural
ambient pressure (C) 968
products with a tetraquinane skeleton (C) Tricarbonyltroponeiron complexes, Activation energy of the racemization of optiSurface antigens, Synthesis of the immuno709
cally active tricarbonyl(tropone)iron comlogically essential saccharide sequence of Tetrathia-3,6-diazacyclohexanes,
The X-ray
the “enterobacterial common antigen” (C)
plexes (C) 329
crystal structures of two 1,2,4,5-tetrathiaTrichlorodimagnesium.6 thf(1 +) anthracen773
3,6-diazacyclohexanes (C) 760
SYNROC, Radwaste immobilization by Thallium complexes, Synthesis and structure
ide, Synthesis and structure of 1,4-dimestructural modification-the crystallochethylanthracenemagnesium. 3 thf and p-triof a thallium complex with an anionic
mica1 properties of SYNROC, a titanate
chlorodimagnesium.6thf(1 + ) anthracensandwich complex ligand ( C ) 71
ceramic (R) 357
ide (C) 960
Arene complexes of univalent gallium, inTrichloromethyl hydroperoxide, PhotooxiSynthetic methods, Chiral compounds syndium, and thallium (R) 893
dation of chloroform: isolation and chathesized by biocatalytic reductions (R)
1 I,)[GaBr,L-synthe[{l,3,5-(CH3)lti.C
racterization of trichloromethyl
539
sis and structure of a mixed mono- and
. hydroper.
.
Enzymes as catalysts in synthetic organic
oxide (C) 50
bis(arene)thallium complex (C) 414
chemistry (R) 617
Tricobalt ligands, Novel high-nuclearity
Thiahexasilanorbornane, Decamethyl-7-thiaModern synthetic methods 1983. Vol. 3:
HgCoRu and HgCoFe sandwich comhexasilanorbornane (CH3),,,Si,S (C) 992
Transition metals in organic synthesis (B) Thiazaphospholes, 1,3,4-Thiazaphospholes
233
(C) 123
tivity” of a lone pair of electrons on low
valent elements of the 4th main group:
(GeNtBu), . 2AIC1, and (SnNtBu),. 2AIC13
(C) 223
Stereochemical control, Double asymmetric
synthesis and a new strategy for stereochemical control in organic synthesis (R)
Selective reactions using organoaluminum reagents (R) 668
Selenium in natural products synthesis
(B) 1007
Syntheses with radicals-C-C bond formation via organotin and organomercury
compounds (R) 553
,
J(,
Angen’ Chem Int Ed. Engl. 24 (1985)
No. I2
1091
TricycIo[6.4.O.O2~"]dodecaarsane,As,2fBu8a tricyclo[6.4.0.0z~6]dodecaarsane(C) 99 I
tial saccharide sequence of the "enterobacterial common antigen" (C) 773
Tricyclooctanone concept, Extensions of the Tris(cyclopentadieny1)lanthanide complextricyclooctanone concept. A general prines, Cleavage of tris(cyclopentadieny1)ciple for the synthesis of linearly and anlanthanide complexes with alkyllithium
gularly annelated triquinanes (C) 973
compounds-a new route to alkylbis(cyTricycl0[3.3.0.O~~~]octan-3-ones,
Photocheclopentadienyl)lanthanide,s (C) 225
mistry of I-methoxybicyclo[2.2.2]octen- Tris(methy1ene)phosphate ion, The first
ones; photolytic cyclopropane cleavage of
tris(methy1ene)phosphate ion [P( =C<),]the initially formed tricycl0[3.3.0.0~.~]- (C) 589
octan-3-ones (C) 763
Trispiro[2.1.2.1.2.l]dodecane-4,8,12-trione
Trimerization, Novel trimerization of cyclo(C) 607
pentadiene with a homogeneous, bifunc- tRNA, The 3'-end of tRNA and its role in
tional palladium-acid catalyst system (C)
protein biosynthesis (R) 371
314
Troponeiron complexes, Activation energy
Trioxo half-sandwich complex, Reductive
of the racemization of optically active
trimerization of the trioxo half-sandwich
tricarbonyl(tropone)iron complexes (C)
complex [(qJ-C5Me5)Re03] with deoxy329
genation: the electron-deficient cluster Tungsten compounds, Synthesis of [Et,Nion I ( ~ i - C ~ M e ~ ) 3 R e 3 ( ~ - 0 (C)
) h l Z50
C 5 W(C0)2(p-PPh2)2Mo(C0)4]Q,the first
Triphenylamine double-decker, A tnphenanionic carbynemetal complex; addition
ylamine double-decker (C) 596
of CO, to the W = C bond (C) 203
Triphosphenium ions, Symmetrical and unsymmetrical triphosphenium ions (C) 226 ULICYCLAMIDE, Total synthesis of uliTriplatinum ligands, A new type of sandcyclamide (C) 569
wich complex formed by Ag' and [Pt3(p,- Uranium compounds, Polymeric tris[trimethyItin(~v)]hexacyanocobaltate(~~~),
a comCO)dPzFr3)31 (C) 766
Triple bond, Phenyl silaisocyanide: the first
pound non-analogous to ''super prussian
organosilicon compound with a formal
blue", and its tris[tricyclopentadienylSi = N triple bond (C) 1 1 1
uranium(~v)]homologue (C) 879
Phosphorus, arsenic, antimony, and bismuth multiply bonded systems with low VALENCE
TAUTOMER, 2,5,7,10-Tecoordination number-their role as comtrakis(trimethylsilyI)- 16-methano[IOIannuplex ligands (R) 924
lene, a fluxional valence tautomer with
cyclopolyolefin structure (C) 587
Triplet diradicals, Sensitized UV/laser photolysis of azoalkanes: conformational in- Vesicle membranes, Sealing and opening
fluences o n intersystem-crossing and
porous monolayer vesicle membranes (C)
lifetimes of triplet radicals (C) 1071
339
Triquinanes, Extensions of the tricycloocta- Vinyl azides, Synthesis and reactions of 4none concept. A general principle for the
azido-3-methyl-1,2-butadiene(C) 216
synthesis of linearly and angularly anne- Vinylcyclopropanes, New donor-substituted
lated triquinanes (C) 973
vinyl- and alkynylcyclopropanes as synNew donor-substituted vinyl- and alkynthetic building blocks (C) 770
ylcyclopropanes as synthetic building
1,4-Addition of dihalocarbenes to 1,3-dieblocks (C) 770
nes (C) 585
Trisaccharides, Preparation of an N-acetylt,CAdditions of dihalocarbenes (C) 579
neuraminic acid-containing trisaccharide
Vinylidenemetal complexes, Synthesis and
and its use in oligosaccharide syntheses
structure of fruns-[MCI( = C = CHR)(C) 128
(Pz'F'~~)~]
(M = Rh, Ir): the first square-plaSynthesis of the immunologically essennar vinylidenemetal complexes (C) 406
+
1092
Vitamin BIZ, Hydrogenobyrinic acid and
vitamin B1, (C) 46
Photooxygenolysis of vitamin B,, (C) 62
Volume superconductor, P-(ET),AuI2: an
organic volume superconductor with
T,= 3.2 K at ambient pressure (C) 968
WALK REARRANGEMENT in the
1,2,3,4-tetra-fert-butylhydroxycyclobutenylium ion (C) 429
Wood chemistry, ultrastructure, reactions
(B) 527
X-RAY CRYSTALLOGRAPHY, High-resolution X-ray crystallography-an experimental method for the description of
chemical bonds (R) 237
YLIDE-NICKEL catalysts, Highly active
ylide-nickel catalysts for the polymerization of ethylene (C) 599
Ylides, Acylsilanes via oxidation of phosphonium ylides: the first synthesis of
bis(trimethylsilyl)ketone and its use as an
equivalent of the dianion CO'" (C) 1068
4-[Tri( n-butyl)]phosphinio-2,5-diselenoxo1,3-diselenacyclopentanide(C) 1058
ZIEGLER CATALYSTS. Formation of organoaluminum compounds in the mixture
AICI,-TiCI,-AI-C,H,
(C) 31 1
Zirconocene, Polymerization of propene
and butene with a chiral zirconocene and
methylalumoxane as cocatalyst (C) 507
Zirconocene derivatives, Monomeric, mononuclear enediolate complexes of zirconium: molecular geometry and electronic
structure of the products of reductive C O
coupling on the metal (C) 712
Torsional isomerism in metallocenes: hindered Cp-rotation in (s-cis-q-butadiene).
bis(q-tert-butylcyclopentadienyl)zirconium (C) 321
Zwitter ions, First 1,4-dipolar cycloadditions of 6-0~0-3,6-dihydro-l-pyrimidinium 4-olates to ketenes and other carbonyl compounds (C) 608
Synthesis and structure of a diaza-h2phosphanylia-h5-stannatacyclobutane(C)
999
Anyew. Chem. I n t . Ed. Engl. 24 09851 No. I2
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