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2001
diastereoselective syntheses, enantioselective syntheses
diastereoselective syntheses, enantioselective syntheses (incl. cis/trans-isomerism)
O 0031
3,3’-Bis(diphenylphosphino)-1,1’-disubstituted-2,2’-biindoles: Easily
16 - 031 Accessible, Electron-Rich, Chiral Diphosphine Ligands for Homogeneous Enantioselective Hydrogenation of Oxoesters.
— Title
phosphines are efficient ligands for enantioselective hydrogenation of oxoesters.
It is found that electronic properties of phosphorus determine the hydrogenation
rate and that electron-rich diphosphines facilitate the reaction. — (BENINCORI, TIZIANA; PICCOLO, ORESTE; RIZZO, SIMONA; SANNICOLO,
FRANCO; J. Org. Chem. 65 (2000) 24, 8340-8347; Dip. Sci. Chim., Fis. Mat.,
Univ. Insubria, I-22100 Como, Italy; EN)
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