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2004
Reduction
O 0220
44- 058
Selective Reduction of Carbonyl Compounds with B-Cyclohexoxydiisopinocampheylborane. — The new B-cyclohexoxydiisopinocampheylborane is described
as one of the Meerwein—Ponndorf—Verley type reducing agents, which reacts chemoselectively only with aldehydes. Other functional groups such as ketones, esters, epoxides, and acid chlorides are not affected. Thus the title borane can be used for the
selective reduction of aldehydes in the presence of these functionalities. — (CHA*, J.
S.; JANG, S. H.; KWON, S. Y.; KWON, O. O.; Bull. Korean Chem. Soc. 25 (2004) 5,
603-604; Dep. Chem., Yeungnam Univ., Kyongsan 712-749, S. Korea; Eng.) —
H. Haber
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