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2004
Reactions of organo-metal compounds
O 0350
Low-Valent Titanium-Mediated Cyclopropanation of Vinylogous Esters. —
and intramolecular versions of the title reactions are developed. The products of
44- 067 Interthe intermolecular process are obtained as an inseparable mixture of diastereomers. The
open-chain isomers are formed in several cases as a by-product. The mechanisms of
the reactions are discussed. — (MASALOV, N.; FENG, W.; CHA*, J. K.; Org. Lett. 6
(2004) 14, 2365-2368; Dep. Chem., Wayne State Univ., Detroit, MI 48202, USA;
Eng.) — Steudel
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