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2004
Aziridine derivatives
R 0040
A Facile Reaction of Imines with Telluronium Allylide. Highly Stereoselective Synof Vinylaziridines. — Title compounds (I) react with N-phenylimines (II) with44- 115 thesis
out activating agents to afford aryl-substituted vinyl aziridines (III) with high trans-selectivity, complementary to the selectivity in the similar aziridination of sulfur ylide in
the presence of Lewis acid. Interestingly, in the analogous reaction N-Boc-imines (IV)
affords selectively cis-aziridines (V). — (LIAO, W.-W.; DENG, X.-M.; TANG*, Y.;
Chem. Commun. (Cambridge) 2004, 13, 1516-1517; State Key Lab. Organomet.
Chem., Shanghai Inst. Org. Chem., Chin. Acad. Sci., Shanghai 200032, Peop. Rep.
China; Eng.) — M. Paetzel
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