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2004
Organo-iron compounds
S 7100
Ir-Catalyzed C—H Activation in the Synthesis of Borylated Ferrocenes and Half
Compounds. — The borylation of mono- and disubstituted ferrocenes and
44- 196 Sandwich
half-sandwich compounds, such as (VIII) is achieved using an Ir-catalyst complex. Notable is the functional group tolerance of the present process and the highly regioselective formation of products. The synthetic value of borylated ferrocenes is demonstrated
for the transformation of compound (IIIa) into the corresponding iodo-derivative (VII).
— (DATTA, A.; KOELLHOFER, A.; PLENIO*, H.; Chem. Commun. (Cambridge)
2004, 13, 1508-1509; Inst. Anorg. Chem., TH Darmstadt, D-64287 Darmstadt,
Germany; Eng.) — M. Paetzel
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