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2004
Condensation reactions
O 0120
A New Lewis Acid System Palladium/TMSCl for Catalytic Aldol Condensation
Aldehydes with Ketones. — Palladium on charcoal effectively catalyzes the aldol
45- 035 of
condensation reaction of different kind of ketones with aldehydes in the presence of
Tms-Cl. The following reactions are investigated: (i) aromatic aldehydes with cycloalkanones; (ii) aromatic aldehydes with aromatic ketones; (iii) cycloalkanones with
aliphatic aldehydes, and (iiii) the self-condensation reactions of aliphatic aldehydes and
cycloalkanones. — (ZHU, Y.; PAN*, Y.; Chem. Lett. 33 (2004) 6, 668-669; Dep.
Chem., Zhejiang Univ., Hangzhou 310027, Peop. Rep. China; Eng.) — M. Paetzel
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