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2004
C-C bond formation
O 0282
Cross-Coupling of Alkyl Halides with Aryl Grignard Reagents Catalyzed by a
Iron Complex. — The cross-coupling of a wide variety of alkyl halides
45- 055 Low-Valent
with arylmagnesium bromides in the presence of 5 mol% of a tetrakis(ethylene)ferrate
complex proceeds with exceptional ease, unprecedented reaction rate, and excellent
chemoselectivity. Coupling of cyclohexyl bromide (I) with PhLi under these conditions
is also successfully accomplished. — (MARTIN, R.; FUERSTNER*, A.; Angew.
Chem., Int. Ed. 43 (2004) 30, 3955-3957; MPI Kohlenforsch., D-45470 Muelheim/
Ruhr, Germany; Eng.) — Klein
2004
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