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2004
Protection
O 0345
45- 059
Chemoselective Tetrahydropyranylation of Alcohols and Their Detetrahydropyranylation Using Silicasulfuric Acid as a Reusable Catalyst. — A simple, mild and
efficient method for the chemoselective tetrahydropyranylation of a wide range of alcohols such as primary, secondary, tertiary, benzylic and allylic alcohols as well as their
deprotection is developed. Interestingly, phenols fail to undergo the tetrahydropyranylation under the conditions employed. — (PORE, D. M.; DESAI*, U. V.; MANE, R.
B.; WADGAONKAR, P. P.; Synth. Commun. 34 (2004) 12, 2135-2142; Dep. Chem.,
Shivaji Univ., Kolhapur 416 004, India; Eng.) — H. Toeppel
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