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2004
Reactions of organo-metal compounds
O 0350
Reaction of Silyldihalomethyllithiums with Nitriles: Formation of α-Keto Acylsilanes via Azirines and 1,3-Rearrangement of Silyl Group from C to N. —
45- 062 During
studies on the aza-Brook rearrangement formation of title compounds (III) and
(V) is observed. The reaction proceeds via azirine intermediates and can be extended
to the preparation of azirine derivatives. A novel silyl 1,3-rearrangement from carbon
to nitrogen is discovered in the reaction of silyldichloromethane (VI). — (YAGI, K.;
TSURITANI, T.; TAKAMI, K.; SHINOKUBO, H.; OSHIMA*, K.; J. Am. Chem.
Soc. 126 (2004) 28, 8618-8619; Dep. Mater. Chem., Grad. Sch. Eng., Kyoto Univ.,
Nishikyo, Kyoto 615, Japan; Eng.) — Nuesgen
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