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2004
Fused pyrrole derivatives
R 0160
Combined Directed ortho and Remote Metalation—Cross-Coupling Strategies.
Method for Benzo[a]carbazoles and the Synthesis of an Unnamed Indo45- 133 General
lo[2,3-a]carbazole Alkaloid. — The title protocol is developed for the synthesis of
benzo[a]carbazoles (IV), (VII) and (X). With variation to the Stille cross-coupling reaction, the developed method is applied to the synthesis of the antiviral and antitumor
alkaloid (XX), isolated from blue-green alga Nostoc sphaericum. — (CAI, X.;
SNIECKUS*, V.; Org. Lett. 6 (2004) 14, 2293-2295; Dep. Chem., Queen's Univ.,
Kingston, Ont. K7L 3N6, Can.; Eng.) — Steudel
2004
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