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2004
Quinoline derivatives
R 0410
A New Synthesis of Naphthyridinones and Quinolinones: Palladium-Catalyzed
of o-Carbonyl-Substituted Aryl Halides. — An alternative strategy us45- 164 Amidation
ing a palladium-catalyzed cross-coupling reaction between enolizable primary and
secondary amides and o-carbonyl substituted aryl halides is developed. It has the advantage of being a convergent one-pot cascade sequence rather than one which often
requires multiple steps. Another attractive feature of this methodology is the broader
availability of o-carbonyl-containing aryl halides versus their amino or nitro counterparts. — (MANLEY*, P. J.; BILODEAU, M. T.; Org. Lett. 6 (2004) 14, 2433-2435;
Dep. Med. Chem., Merck & Co., West Point, PA 19486, USA; Eng.) — Steudel
2004
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