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2004
Pyrimidine derivatives
R 0510
A Simple and Convenient Synthesis of HEPT Analogues via a One-Pot ReducReaction. — An efficient and convenient one-pot procedure for
45- 174 tion—Sulfenylation
the synthesis of C-6 arylthio analogues [cf. (III), (V)] of 1-[(2-hydroxyethoxy)methyl]-6-(phenylthio)thymine (HEPT), a non-nucleoside inhibitor of HIV-1 reverse transcriptase, is developed. Some functional groups such as C=C double bonds, amide etc.
are compatible, however, the acetoxy group is not compatible with the reaction conditions. — (SUN, G.; KUANG, Y.; WANG, S.; CHEN*, F.; Synth. Commun. 34 (2004)
12, 2229-2235; Dep. Chem., Fudan Univ., Shanghai 200433, Peop. Rep. China; Eng.)
— H. Toeppel
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