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2004
Multi-membered N-heterocycles
R 0690
Functionalized 2,5-Disubstituted Benzazepines: Stereoselective Synthesis of 3-Meand
45- 187 thyl-5-phenyl-2,3,4,5-tetrahydro-1H-3-benzazepine-2-carbonitrile
Related Derivatives. — A novel route to the biologically interesting scaffold (IX)
is detailed. Key transformation is the highly trans-selective generation of carbonitrile
(VII) which complements previously reported cis-selective routes. — (COBB, J. E.;
NANTHAKUMAR, S. S.; RUTKOWSKE, R.; UEHLING*, D. E.; Synlett 2004, 8,
Special Issue, 1394-1398; GlaxoSmithKline Res. Dev., Research Triangle Park,
NC 27709, USA; Eng.) — Mais
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