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2004
Reactions of organo-metal compounds
O 0350
Reaction of Alkene—Zirconocene Complexes and Cyclic Enol Ethers Through
Reaction Pathways. — Cyclic enol ethers (III), (VI), and (X) undergo coupling
46- 061 New
reactions with in situ generated zirconacyclopropanes (II). Depending on the ring size
of the enol ether, five-membered ethers (III) and (VI) give alcohols or phenols containing a (Z)-double bond through an insertion/elimination process. Six-membered ether
(X) affords cyclobutane products through an unprecedented insertion/intramolecular
migratory insertion reaction. — (BARLUENGA*, J.; ALVAREZ-RODRIGO, L.;
RODRIGUEZ, F.; FANANAS, F. J.; Angew. Chem., Int. Ed. 43 (2004) 30, 3932-3935;
Inst. Quim. Organomet. "Enrique Moles", Univ. Oviedo, E-33071 Oviedo, Spain;
Eng.) — Klein
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