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2004
Oxidation
O 0212
47- 038
A Heterobimetallic Rhodium(I)—Ruthenium(II) Catalyst for the Oppenauer-Type Oxidation of Primary and Secondary Alcohols under Mild Conditions.
— The catalyst is generated in situ by metathesis reaction of a chloro-bridged rhodium
complex with a ruthenium phosphine complex. It is used for the Oppenauer-type oxidation of primary and secondary alcohols under mild conditions. For aliphatic primary
alcohols, low conversions are observed as a result of their unfavorable redox potential.
— (GAUTHIER, S.; SCOPELLITI, R.; SEVERIN*, K.; Organometallics 23 (2004)
16, 3769-3771; Swiss Fed. Inst. Technol., CH-1015 Lausanne, Switz.; Eng.) — S.
Adam
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