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2004
Dioxole derivatives
R 0170
Chiral (Salen)CoIII Catalyst for the Synthesis of Cyclic Carbonates. — A catalyst
system comprised of a chiral (salen)CoIII complex and a Lewis acid is investigated for
47- 113 the reaction of CO2 (II) and a variety of epoxides, such as (I) and (IV). In addition, initial
investigations into the kinetic resolution of propylene oxide (Ia) with (II) in the presence of the chiral Co(salen) complex show encouraging results. — (PADDOCK, R.
L.; NGUYEN*, S. T.; Chem. Commun. (Cambridge) 2004, 14, 1622-1623; Dep.
Chem., Northwest. Univ., Evanston, IL 60208, USA; Eng.) — M. Paetzel
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