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2004
Structure
D 2000
48- 010
Crystal Structure of the Bis[zinc(II)-hydroxide-(µ-perchlorate)-triaqua] Complex. — Single crystals of the title compound are obtained from the reaction of
Zn(ClO4)2·6H2O with p-sulfophenylalanine in MeOH/H2O (60 °C, 2 h) followed by
slow evaporation of the mother liquid. [Zn(OH)(µ-ClO4)(H2O)3]2 crystallizes in the
monoclinic space group P21/c with Z = 4. The structure contains discrete dinuclear
[Zn(OH)(µ-ClO4)(H2O)3]2 units in which each perchlorate anion acts as a bidentate
bridge between two Zn atoms whereas the hydroxy group is a terminal group. The local
surrounding around the zinc atom is a slightly distorted octahedron. — (LI, Y.-H.; YE,
Q.; TANG, Y.-Z.; XIONG*, R.-G.; Z. Anorg. Allg. Chem. 630 (2004) 11, 1553-1554;
Coord. Chem. Inst., Nanjing Univ., Nanjing 210093, Peop. Rep. China; Eng.) —
Schramke
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