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2004
Ring closure reactions
O 0130
A Silver-Catalyzed Intramolecular Amidation of Saturated C—H Bonds. —
efficient intramolecular amidation of various amidates and sulfamates catalyzed by
48- 034 An
a unique disilver(I) complex, generated in situ from AgNO3 and tBu3-terpy, furnishing
five- or six-membered insertion products is described. The reaction appears to be
stereospecific and seems to involve the intermediacy of a silver-nitrene type oxidant.
— (CUI, Y.; HE*, C.; Angew. Chem., Int. Ed. 43 (2004) 32, 4210-4212; Dep. Chem.,
Univ. Chicago, Chicago, IL 60637, USA; Eng.) — Koehler
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