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2004
Hydrogenation
O 0220
Development of a Continuous-Flow System for Catalysis with Palladium(0) Par— Continuous-flow applications of palladium(0) catalysts are studied by use of
48- 042 ticles.
the ionic exchange functionality of reactors with a monolithic glass/polymer composite
interior for specifically positioning the catalyst inside the reactor. Palladium(0)-loaded
continuous-flow reactors are successfully applied in transfer hydrogenation reactions
of alkenes, alkynes, nitro-substituted aromatic compounds and benzyl ethers, and in
Heck and Sonogashira reactions (to be continued). — (SOLODENKO, W.; WEN, H.;
LEUE, S.; STUHLMANN, F.; SOURKOUNI-ARGIRUSI, G.; JAS, G.;
SCHOENFELD, H.; KUNZ, U.; KIRSCHNING*, A.; Eur. J. Org. Chem. 2004, 17,
3601-3605; Inst. Org. Chem., Univ. Hannover, D-30167 Hannover, Germany; Eng.)
— Klein
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