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2004
Cyanation
O 0273
48- 045
Palladium-Catalyzed Cyanation of Aryl Bromides Promoted by Low-Level Organotin Compounds. — Organotin compounds are shown to promote the palladium-catalyzed cyanation of aryl bromides. The catalyst loading is very low and the reaction
conditions are mild. KCN is used as a cyanide source in place of Cu and Zn salts with
advantages in cost and water solubility for work-up. — (YANG*, C.; WILLIAMS, J.
M.; Org. Lett. 6 (2004) 17, 2837-2840; Dep. Process Res., Merck Res. Lab.,
Merck&Co., Inc., Rahway, NJ 07065, USA; Eng.) — Steudel
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