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2004
Aldehyde derivatives
P 0190
Enantioselective Organocatalytic Aldehyde—Aldehyde Cross-Aldol Couplings.
Broad Utility of α-Thioacetal Aldehydes. — It is found that α-thioacetal alde48- 060 The
hydes are versatile partners for direct L-proline catalyzed aldol reaction. They react
successfully with a wide range of aldehyde and ketone donors with high diastereo- and
enantioselectivity. The procedure allows efficient synthesis of both β-hydroxy and
α,β-dihydroxy aldehydes and ketones. — (STORER, R. I.; MACMILLAN*, D. W. C.;
Tetrahedron 60 (2004) 35, 7705-7714; Div. Chem., Calif. Inst. Technol.,
Pasadena, CA 91125, USA; Eng.) — Jannicke
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