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2004
Nucleic acids
U 0700
Novel Stereoselective Entry to 2'-β-Carbon-Substituted 2'-Deoxy-4'-thionucleofrom 4-Thiofuranoid Glycals. — A novel approach to the biologically interest48- 181 sides
ing title compounds is developed. Key step is the PhSeCl-mediated electrophilic glycosidation using 4-thiofuranoid glycals with carbon substituents at the C2-position as
a glycosyl donor. The chemical transformations of (V) and (VIII) and their derivatives
are described. — (HARAGUCHI*, K.; SHIINA, N.; YOSHIMURA, Y.; SHIMADA,
H.; HASHIMOTO, K.; TANAKA, H.; Org. Lett. 6 (2004) 16, 2645-2648; Sch.
Pharm. Sci., Showa Univ., Shinagawa, Tokyo 142, Japan; Eng.) — Steudel
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