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2004
Antibiotics
U 1200
48- 192
Spirastrellolide A: Revised Structure, Progress Toward the Relative Configuration, and Inhibition of Protein Phosphatase 2A. — The structure of the title compound, isolated from the marine sponge Spirastrella coccinea and shown to be a potent
and fairly selective inhibitor of protein phosphatase 2A is revised to (II). Relative configurations of three major fragments of the previously proposed structure (I) are elucidated from ROESY and coupling constant data. — (WILLIAMS, D. E.; LAPAWA,
M.; FENG, X.; TARLING, T.; ROBERGE*, M.; ANDERSEN, R. J.; Org. Lett. 6
(2004) 15, 2607-2610; Dep. Chem. Biochem., Univ. British Columbia, Vancouver,
B. C. V6T 1Z1, Can.; Eng.) — Steudel
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