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2004
Structure
D 2000
49- 002
The Crystal Structures of the Dicesium Dodecahalogeno-closo-Dodecaborates
Cs2[B12X12] (X: Cl, Br, I) and Their Hydrates. — The title compounds (II), (III), and
(IV), as well as their mono- and dihydrates, isostructurally crystallize in the triclinic
space group R3 with Z = 6 (single crystal XRD). The crystal structures consist of a
cubic close packed host lattice formed by two crystallographically inequivalent quasi-icosahedral [B12X12]2- anions. The Cs + ions occupy all octahedral and one half of the
tetrahedral sites in an ordered manner. — (TIRITIRIS, I.; SCHLEID*, T.; Z. Anorg.
Allg. Chem. 630 (2004) 11, 1555-1563; Inst. Anorg. Chem., Univ. Stuttgart, D-70569
Stuttgart, Germany; Ger., Abstr. Eng.) — Schramke
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