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2004
Nitrogen
I 0014
49- 013
High-Energy-Density Materials: Synthesis and Characterization of N+5 [P(N3)6]-,
N+5 [B(N3)4]-, N+5 [HF2]-·nHF, N+5 [BF4]-, N+5 [PF6]-, and N+5 [SO3F]-. — Polynitrogen
containing compounds are promising candidates for high energy-density materials. The
title compounds are synthesized by metathetical reactions (yields given in g) and characterized by IR and Raman spectroscopy. (II) is isolated as a clear colorless liquid and
shown to be a useful precursor for the synthesis of other N+5 salts. — (HAIGES*, R.;
SCHNEIDER, S.; SCHROER, T.; CHRISTE, K. O.; Angew. Chem., Int. Ed. 43
(2004) 37, 4919-4924; Loker Hydrocarbon Res. Inst., Dep. Chem., Univ. South. Calif.,
Los Angeles, CA 90089, USA; Eng.) — W. Pewestorf
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