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2004
Isoquinoline derivatives
R 0420
Allylic Dehydration, Retro-Pinacol, Pinacol-Like and Enamide Reactions: Synof New Isoquinolines. — Thermolysis of the anellated lactam (I) in neat PPA
49- 132 thesis
results in dehydrative/oxidative formation of dienyl lactam (II). In concentrated HCl, a
number of products is formed. Among them, (III) can be selectively obtained in HCl
under oxidative conditions. Furthermore, hypothesis of alcohol (VI) being intermediate
in the formation of (IV) and (V) is studied. — (AKUE-GEDU, R.; BOURRY, A.;
CAMUS, F.; NORBERG, B.; DURANT, F.; COUTURIER, D.; DEBACKER, M.;
RIGO*, B.; Heterocycles 63 (2004) 8, 1855-1873; Groupe Rech. Inhib. Proliferation
Cell., CNRS, Ec. Hautes Etud. Ind., F-59046 Lille, Fr.; Eng.) — Mais
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