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2004
Molybdenum
I 5600
Three New Organically Templated Polyoxomolybdates with Capping Selenite
— Compound (III) crystallizes in the space group C2/c with Z = 8, compound
50- 020 Anions.
(IV) in the space group C2 with Z = 2, and compound (VI) in the space group P21/n
with Z = 4 (single crystal XRD). The structure of (III) features a one-dimensional
anionic double chain of [KMo4O13(SeO3)]3- units, in which four MoO6 octahedra form
a planar Mo4O13 cluster which is further capped by a SeO3 group in a bidentate fashion.
Both (IV) and (VI) contain a bicapped planar Mo5O15 cluster unit with two SeO23 - anions acting as tridentate capping groups. — (FENG, M.-L.; MAO*, J.-G.; Eur. J.
Inorg. Chem. 2004, 18, 3712-3717; State Key Lab. Struct. Chem., Fujian Inst. Res.
Struct. Matter, Chin. Acad. Sci., Fujian, Fuzhou 350002, Peop. Rep. China; Eng.) —
W. Pewestorf
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