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2004
Carboxylic acid esters
P 0360
Re(CO)5Br-Catalyzed Addition of Carboxylic Acids to Terminal Alkynes: A High
and Recoverable Homogeneous Catalyst. — 1-Alkenyl esters
50- 042 anti-Markovnikov
are obtained by the title reaction, in most cases predominantly as unusual (Z)-adducts.
If the addition reactions are performed in heptane, the catalyst can be partly recovered
from the reaction mixture without loss of activity. — (HUA*, R.; TIAN, X.; J. Org.
Chem. 69 (2004) 17, 5782-5784; Dep. Chem., Tsinghua Univ., Beijing 100084, Peop.
Rep. China; Eng.) — Klein
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