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2004
Ketones
Q 0350
50- 053
Catalytic Cross-Coupling Reaction of Esters with Organoboron Compounds and
Decarbonylative Reduction of Esters with HCOONH4: A New Route to Acyl Transition Metal Complexes Through the Cleavage of Acyl—-Oxygen Bonds in Esters.
— Aryl ketones and dialkyl ketones are prepared in good yields and with high regioselectivities by Ru3(CO)12-catalyzed cross-coupling reactions of 2-pyridylmethyl esters
with aryl boronates or 9-alkyl-9-BBN (cf. Part 2 of the scheme) (to be continued). —
(TATAMIDANI, H.; YOKOTA, K.; KAKIUCHI, F.; CHATANI*, N.; J. Org. Chem.
69 (2004) 17, 5615-5618; Dep. Appl. Chem., Fac. Eng., Osaka Univ., Suita, Osaka
565, Japan; Eng.) — Klein
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